电感耦合等离子体发射光谱在分析废液晶显示器面板主要元素中的应用

采用电感耦合等离子体发射光谱(ICP-AES)法对废液晶显示器(TFT-LCD)面板主要元素含量进行了测定。结果表明:(1)在酸体系下回收废TFT-LCD面板中In时,尽管不同酸体系下各元素浓度变化较大,但是主要伴随元素以Al、Fe为主。(2)绝大多数元素测定结果的相对标准偏差低于3%。(3)不同元素加标回收率基本在86%～110%。ICP-AES法具有灵敏度高、检出限较低、多元素同时测定等优点,能满足元素测定误差要求,可有效应用于废TFT-LCD面板中主要元素的测定。     

晶硅光伏组件出口对中国碳排放的影响

基于文献资料,估算了2004-2009年中国晶硅光伏组件制造过程中的能源消耗和CO2排放强度。研究发现,2004-2009年,晶硅光伏组件制造过程中的能耗强度和CO2排放强度均逐年下降。2009年,单晶、多晶光伏组件制造过程中的能耗强度分别为2 629 kWh/kWp和2 242 kWh/kWp,碳排放强度分别为1 829 gCO2/Wp和1 559 gCO2/Wp。由于晶硅光伏组件的大量出口,中国不仅出口了大量的隐含碳,还损失了数量可观的、潜在的CO2减排能力。2004-2010年,中国的隐含碳净出口量由3万tCO2增加到852万tCO2;如果出口的晶硅电池全部用于国内,在其生命周期内累计可减排CO23.4亿t。除2004年和2010年外,国内安装的晶硅光伏组件在其生命周期内所能减少的CO2排放不足以抵消晶硅光伏行业的CO2排放,晶硅光伏行业对中国CO2减排的贡献为负。在多晶硅全部国产的情况下,中国若维持晶硅电池应用中的CO2减排量与全行业CO2排放量的平衡,至少应将晶硅组件制造的7.2%安装在国内使用。若多晶硅进口比例仍保持在50%左右,则至少应将晶硅组件制造的4.9%安装在国内使用。     

二氧化硫排放测算方法与控制对策探讨

二氧化硫作为衡量企业减排成绩和环境效益的重要指标,其计算方法的选取尤为重要。通过对几种常用二氧化硫排放测算方法的研究及比较,选取了物料衡算法作为长庆油田公司第一采气厂天然气净化厂环境统计分析的基本计算依据,确定了二氧化硫排放问题的关键影响因素,同时从环境统计学角度给出了二氧化硫达标排放的控制指标及建议,为有效开展二氧化硫及其他污染物的排放问题研究,提供技术指导及方法依据。     

Lead-210 and Beryllium-7 fallout rates on the southeastern coast of Brazil

Total ²¹⁰Pb and ⁷Be fallout rates were measured on the coastal region of Niteroi, Brazil. The monthly depositional flux of ²¹⁰Pb and ⁷Be varied by a factor of 26, from 1.7 to 43.3 mBq cm⁻² year⁻¹ and ∼27, from 7.5 to 203.5 mBq cm⁻² year⁻¹, respectively. The relatively large oscillations in the depositional flux of ²¹⁰Pb at this study site were likely due to variations in air mass sources, while the ⁷Be fluctuations may be driven by a combination of weather conditions. Local geology could support the periodic high fluxes of ²¹⁰Pb from continental air masses, as shifting oceanic wind sources were affirmed by the uncorrelated ²¹⁰Pb and ⁷Be fallout activities and ⁷Be/²¹⁰Pb ratios. The ²¹⁰Pb atmospheric deposition was found to be in agreement with local sediment inventories, an important consideration in geochemical studies that estimate sedimentation processes.     

基于纳污红线的河流排污权优化分配模型

实行水功能区限制纳污红线的水资源管理制度,在理论和实践中必须要建立河流污染物总量控制管理制度,而实行污染物总量控制,首先要确定河流排污权的初始分配方案。结合我国现行流域水功能区划成果,以水功能区作为排污权初始分配主体开展排污权分配研究,提出由河流环境保护部门确定河流总体排污权,首先通过纵向配置将排污权分配给水功能区,然后通过横向配置将初始排污权分配给排污者的一种纵向加横向分配模式。以资源分配的公平性和效率为管理目标,并以污染物总量控制、浓度控制、企业生产连续性等为约束条件,建立了河流排污权多目标分配优化模型。最后利用多目标演化算法对算例进行了求解,验证了方法的可行性,且此分配方式所获得的环境节余容量最大     

Developing spatially stratified N(2)O emission factors for Europe

We investigate the possibility to replace the – so-called – Tier 1 IPCC approach to estimate soil N₂O emissions with stratified emissions factors that take into account both N-input and the spatial variability of the environmental conditions within the countries of the European Union, using the DNDC-Europe model. Spatial variability in model simulations is high and corresponds to the variability reported in literature for field data. Our results indicate that (a) much of the observed variability in N₂O fluxes reflects the response of soils to external conditions, (b) it is likely that national inventories tend to overestimate the uncertainties in their estimated direct N₂O emissions from arable soils; (c) on average over Europe, the fertilizer-induced emissions (FIE) coincide with the IPCC factors, but they display large spatial variations. Therefore, at scales of individual countries or smaller, a stratified approach considering fertilizer type, soil characteristics and climatic parameters is preferable.     

An overview of experimental results and dispersion modelling of nanoparticles in the wake of moving vehicles

Understanding the transformation of nanoparticles emitted from vehicles is essential for developing appropriate methods for treating fine scale particle dynamics in dispersion models. This article provides an overview of significant research work relevant to modelling the dispersion of pollutants, especially nanoparticles, in the wake of vehicles. Literature on vehicle wakes and nanoparticle dispersion is reviewed, taking into account field measurements, wind tunnel experiments and mathematical approaches.Field measurements and modelling studies highlighted the very short time scales associated with nanoparticle transformations in the first stages after the emission. These transformations strongly interact with the flow and turbulence fields immediately behind the vehicle, hence the need of characterising in detail the mixing processes in the vehicle wake. Very few studies have analysed this interaction and more research is needed to build a basis for model development. A possible approach is proposed and areas of further investigation identified.     

Vertical emission profiles for Europe based on plume rise calculations

The vertical allocation of emissions has a major impact on results of Chemistry Transport Models. However, in Europe it is still common to use fixed vertical profiles based on rough estimates to determine the emission height of point sources. This publication introduces a set of new vertical profiles for the use in chemistry transport modeling that were created from hourly gridded emissions calculated by the SMOKE for Europe emission model. SMOKE uses plume rise calculations to determine effective emission heights. Out of more than 40 000 different vertical emission profiles 73 have been chosen by means of hierarchical cluster analysis. These profiles show large differences to those currently used in many emission models. Emissions from combustion processes are released in much lower altitudes while those from production processes are allocated to higher altitudes. The profiles have a high temporal and spatial variability which is not represented by currently used profiles.     

基于弹性系数的大兴区环境-经济预警研究

在环境-经济系统中,选择弹性系数对区域节能减排做预警研究,构建基于弹性系数的区域环境-经济预警系统。将该预警系统应用于实际案例中,计算了符合北京市大兴区节能减排目标要求的弹性系数区间,对区域未来的环境-经济状况进行预测和预警。在惯性发展情景下,大兴区2010年和2020年环境-经济系统处于临界状态,节能减排达标尚存在一定困难,其中SO2、COD排放是区域环境-经济安全的最大影响因素。     

基于社会经济核算矩阵的江西省氮磷减排调控方案研究

通过编制江西省2002年包含环境账户的社会经济核算矩阵(ESAM)研究了江西省征收排污费与分类实施氮磷营养盐减排补贴对18个产业生产收益的影响。研究结果表明:不同氮磷减排调控方案对各产业产值的边际影响存在差异。总体上看,除部分服务业,调整氮磷排污费的征收标准对各部门生产收益的整体影响并不大,氮磷排放越少的产业受调控影响的产值变化较大;而调整氮（或磷）营养盐的减排补贴对各产业生产收益的边际影响较为显著,氮（或磷）排放越多的产业生产收益增加幅度越大,污染治理部门及其他氮（或磷）排放不太相关的产业生产收益变化甚微。综合比较3种减排调控方案,实施氮磷营养盐减排补贴对江西省产业发展影响最为显著