污染源减排时刻和减排比例对北京市PM_(2.5)浓度的影响

利用Model-3/CMAQ及京津冀地区高分辨率排放源清单,选取文献[19]中污染峰值当天启动50%污染源削减方案的同时,进一步设置了3种污染源控制方案(峰值当天启动75%源削减;峰值日前1d、2d开始启动25%源削减),比较了峰值日前启动适量减排与峰值日当天启动大幅度减排的效果差异.结果表明:污染峰值当天启动50%、75%减排时,北京市PM2.5浓度下降率分布不均匀,高值区集中于PM2.5浓度高值区,减排后PM2.5浓度分布较减排前均匀.提前1~2d启动25%源削减时,峰值日北京市PM2.5浓度整体下降.城、郊PM2.5下降率均表现为当天减排50%小于提前1d开始减排25%;当天启动减排提高到75%时,城区PM2.5下降率大于提前2d启动25%减排,郊区表现为峰值前2d启动25%削减优于当天减排75%.将峰值前1d、2d启动25%减排分别与当天启动50%、75%减排时北京市峰值日PM2.5浓度下降率相减,北京市绝大部分区域下降率差值为正;峰值前1d、2d启动25%减排分别比峰值日启动50%、75%减排时北京市平均PM2.5多下降4.7μg/m3(6%)、2.9μg/m3(4%).综上所述,在污染峰值来临之前采取适量减排较污染当天才启动大幅度减排更有利于北京市整体空气质量达标.     

水解酸化处理黄麻生物脱胶废水试验

针对黄麻生物脱胶废水浓度高、处理难度大的问题,采用水解酸化与膜生物反应器组合工艺对黄麻生物脱胶废水进行了处理试验。考察水解酸化池对COD、氨氮、木质素等的去除效果;并通过调节试验条件,考察水力停留时间、pH值、温度等因素对水解酸化效果的影响,得出处理黄麻生物脱胶废水的最佳实验条件。结果表明,水解酸化预处理工艺提高了废水的可生化性,对COD、氨氮均有较高的去处效率,对于降低纤维素的聚合度、促成纤维素的水解起到了关键的作用,为后续的好氧处理创造了有利条件。试验在水力停留时间10 h下,COD与氨氮去处率最高分别达35%,40%;影响水解酸化的因素主要为pH值和水力停留时间。     

时间压力视角下人格特征与VDT视觉搜索绩效的关系及形成机理*

为合理选拔和培训特定情境下的视觉搜索安检人员,从时间压力视角分析大五人格特征与视觉显示终端（visual display terminal,VDT）的视觉搜索绩效的关系。通过变量分析和设计,提出VDT视觉搜索绩效影响因素理论模型;运用Visual Studio设计实验模拟视觉搜索安检任务,采集绩效及眼动数据;最后进行有中介的调节模型检验。研究结果表明:不同人格特征的VDT视觉搜索绩效存在差异;所有人格特征的搜索策略随机指数随时间压力的增加而降低,但调整强度在不同人格特征之间存在差异,严谨性人格调整幅度最大;时间压力通过搜索策略的中介作用（部分）间接调节人格特征与VDT视觉搜索绩效的关系;较高和较低时间压力下,严谨性人格通过有效的搜索策略调整,绩效最好;中等时间压力下,开放性人格的绩效最好。研究结果可为视觉搜索作业人员的选拔和培训提供理论依据。     

Advanced process control system with MPC as a new approach for layer of protection analysis

Layer of protection analysis (LOPA) is a widely used method to support process safety in the chemical industries. In the LOPA, the process is classified into many layers, one of such layers considers the basic process control system (BPCS) which commonly uses PID controllers. This kind of controllers cannot deal with constraints. For this reason, the main purpose of this work is to provide a framework to enhance the control layer in the LOPA, which consists of a model predictive control (MPC) with safety features. These features include: sublayers in the controller system (such as real time optimization, target calculation, and MPC), safety constraints, and guarantee of stability by adopting an Infinite Horizon MPC (IHMPC). Here, we propose an approach for control-inspired view to process safety, replacing the BPCS by an Advanced Process Control System (APCS). Moving forward with these concepts, first, a literature review emphasizes the content, showing two perspectives for the APCS. The APCS is designed for two varieties of controllers, a basic IHMPC and IHMPC with zone control to compare the performance. In this framework, the first sublayer consists of a real time optimization (RTO) structure, that calculates the optimal operating condition for the process controller, which computes the control action. Besides, RTO has an additional constraint called the safety index, based on the protection of process operational. RTO and basic IHMPC communicate directly, while for IHMPC with zone control there is an inner sublayer called Target Calculation, it computes a feasible target to the controller, working as another safety strategy in APCS. After that, we demonstrate both structures applied to a CSTR reactor. From the case study, we compared both controllers, and evaluated the effect that the safety index constraint causes in the setpoints, outputs, and control actions. The use of safety constraint in RTO proved to be a safe strategy for the control layer, as well as IHMPC with zone control presented a safer profile than basic IHMPC. Furthermore, the results show that safety constraint affect the economic goal, decreasing its value.     

人工湿地水力停留时间分布模拟

将人工湿地视为在纵向分散活塞流反应器（PFD）的主流道上并联一个n级串联完全混合反应器（CSTRs）所组成的系统.在这一物理概念的基础上,推导了模拟人工湿地水力停留时间分布（RTD）的CSTRs＋PFD并联模型.模型所包含的4个参数（串联CSTRs个数n,串联CSTRs容积占系统总容积的百分数z,进入串联CSTRs的流量占总流量百分数f,PFD的分散数D）对RTD的峰值时间、峰值高度、平均停留时间、停留时间分布方差具有良好的调节作用.与传统模型相比,该模型能更准确地反映不同人工湿地的特征水流规律.模型采用基于流量的无量纲时间变量,可应用于非稳态变流量下人工湿地RTD的模拟.用前期示踪剂试验所获得的5条水平潜流人工湿地的RTDs对该模型进行验证,当这4个参数取值为z=0.41、f=0.57、n=3、D=0.667时,该模型计算所得RTD与实测RTDs拟合程度良好,较传统PFD或CSTRs模型能更好地反映该人工湿地RTD早期高峰、峰值集中、尾部倾斜拖长的流态特征.     

MBBR-A2O/MBR处理农村生活污水动力学研究

采用MBBR-A2O/MBR(又称BCO-MBR)工艺,对水质特征呈现低碳源高氮磷、水质波动大和日变化系数大等特点的农村生活污水进行研究。对比MBBR-A2O/MBR工艺在5种不同水力停留时间下的(0.42 d、0.50 d、0.75 d、1.25 d、1.50 d)运行状况,挑选出最佳的水力停留时间,并利用Lawrence-McCarty模型构建该工艺的污染物降解动力学方程。结果表明,随着水力停留时间(HRT)的延长,MBBR-A2O/MBR工艺对污染物的去除效果逐渐提升。当HRT为1.25d,CODCr、NH3H、TN、TP平均进水质量浓度分别280.67mg/L、36.88 mg/L、50.59 mg/L、2.51 mg/L时,平均出水质量浓度分别为34.33 mg/L、3.19 mg/L、5.13 mg/L、0.63 mg/L,平均去除率分别可达87.86%、89.92%、89.85%、74.95%。CODCr、NH3H、TN出水质量浓度在城镇污水排放标准一级A限值以下,TP出水质量浓度达到一级B标准,因此确定最佳的HRT为1.25 d。污染物降解动力学计算所得模拟值与实际出水质量浓度测量值拟合度良好,其中CODCr模拟值与平均测量值一致性最高,相对误差在0.02~0.14,NH3H与TN的相对误差分别在0.19~0.60和0.1~0.33。这表明污染物降解动力学方程可以较好地模拟工艺出水的污染物质量浓度。CODCr降解动力学方程常数为Vmax=0.19 d-1,KS=82.97 mg/L;NH3H降解动力学方程常数为Vmax=0.02d-1,KS=8.49 mg/L;TN降解动力学方程常数为Vmax=0.024 d-1,KS=8.10 mg/L。研究的动力学常数与传统活性污泥法动力学常数相比,KS较高,而Vmax较低,导致Vmax较低的主要原因可能是测定的污泥质量浓度高于实际有效的质量浓度。研究对利用MBBR-A2O/MBR工艺处理农村生活污水和传统活性污泥工艺提标改造具有一定的应用参考价值。     

瓶级聚酯切片静电起电特性试验研究*

为了分析瓶级聚酯切片（PET）生产过程中分析筛处理量对其静电带电特性的影响,基于颗粒振动摩擦带电模拟试验,研究单颗粒PET振动摩擦带电饱和量以及多颗粒PET振动带电荷质比数据。结果表明:瓶级PET产品静电半衰期超过80 ks;PET单颗粒与金属分析筛碰撞摩擦时带电量随振动时间增加趋于饱和,且单粒子荷质比大小可超过16 nC·g-1;随着分析筛内PET总质量增加,PET颗粒间碰撞几率增加,但PET的荷质比值迅速降低。利用工业振动筛处理PET时,应尽量提高总颗粒处理量以控制颗粒带电,抑制静电对粉尘吸附作用,有利于脱除切片中携带的粉尘。     

随机过程“各态历经”理论应用于环境噪声监测优化布点

本文尝试应用随机过程“各态历经”理论，在大、中、小多个样本中研究城市环境噪声监测的时—空相关性，找出“定点测量法”与“网格测量法”的内在联系，探讨以“定点测量法”取代“网格测量法”进行城市区域环境噪声普查的可行性，从而实现环境噪声监测优化布点及为实现城市环境噪声自动监测布点提供技术依据     

喀什市2022年环境空气质量特征分析

为摸清喀什市环境空气质量变化特征,为管理部门进行污染精准管控提供科学参考,基于喀什市2022年环境空气自动监测数据开展分析研究。结果表明:2022年喀什市二氧化硫、二氧化氮、臭氧、一氧化碳年均质量浓度均优于国家二级标准。超标污染物主要为可吸入颗粒物和细颗粒物。喀什市细颗粒物、可吸入颗粒物浓度呈春、秋、冬季高,夏季低的季节特征。     

The effects of daylight saving time on vehicle crashes in Minnesota

Introduction: Daylight saving time (DST), implemented as an energy saving policy, impacts many other aspects of life; one is road safety. Based on vehicle crash data in Minnesota from 2001 to 2007, this paper evaluates long- and short-term effects of DST on daily vehicle crashes. Method: To provide evidence to explain the causes of more/fewer crashes in DST, we examine the impact of DST on crashes in four periods of a day: 3 a.m.-9 a.m., 9 a.m.-3 p.m., 3 p.m.-9 p.m., 9 p.m.-midnight. The effects of risk and exposure to traffic are also separated. Our statistical models not only include weather conditions and dummy variables for days in DST as independent variables, but also consider traffic volumes on major roads in different periods of a day. Our major finding is that the short-term effect of DST on crashes on the morning of the first DST is not statistically significant. Moreover, it is interesting to notice that while DST per se is associated with fewer crashes during dusk, this is in part offset because it is also associated with more traffic on roads (and hence more crashes). Our path analysis shows that overall DST reduces crashes. Impact on industry: Daylight saving time can lead to fewer crashes on roads by providing better visibility for drivers.