阻燃高抗冲聚苯乙烯/有机改性蒙脱土纳米复合材料阻燃效应的研究(Ⅰ)--传统阻燃剂与改性蒙脱土的阻燃协效性

运用"一步熔融共混法"制备了包含十溴联苯醚(DBDPO)-氧化锑(Sb2O3)和蒙脱土(MMT)-十六烷基三甲基溴化铵(C16BrN)阻燃体系的高抗冲聚苯乙烯(HIPS)复合材料,并通过X射线衍射(XRD)、透射电镜(TEM)、UL 94垂直燃烧测试和锥形量热计等测试手段对其结构形貌和燃烧性能进行了表征.结果表明,在传统阻燃剂DBDPO存在前提下,仍然获取了具有插层结构的高抗冲聚苯乙烯/蒙脱土(HIPS/MMT)纳米复合材料.燃烧特性实验发现两种阻燃体系在HIPS基体中具有良好协效性,复合材料热释放速率大幅下降.这种效应为减少溴系阻燃剂用量以降低生产成本和减轻不良环境效应提供了依据,对于发展绿色环保型高性能聚合物阻燃复合材料非常有意义.     

城市混凝土桥梁薄弱处分析

随着城市化进程的不断发展,包括高架桥、立交桥在内的大量混凝土桥梁在城市交通网络中扮演者极其重要的角色。但受环境侵蚀、交通量日益增加的影响,城市混凝土桥梁不可避免地出现一定损伤,严重甚至会导致桥梁倒塌等重大灾难事故。在分析城市混凝土桥梁的各种损伤及损伤演化过程的基础上提出运营桥梁薄弱处的概念。该薄弱处是指受环境侵蚀、材料老化、荷载变化等因素的影响,混凝土桥梁结构中最先发生破坏的构件或构件中的某一位置。对运营桥梁薄弱处的分析宜采用分析结构中各处的承载力下降及相应的荷载效应增加二者相结合的方法,通过比较获得桥梁中各处抗力与荷载效应最为接近的地方,即结构薄弱处。最后,总结了城市混凝土桥梁薄弱处分析研究的发展方向及亟待解决的关键技术。     

地震序列下桥梁连梁装置的防落梁效果分析

在各类地震序列中,主-余震所占比例最大。主震震级越高其余震的震级亦越高,对结构的破坏越大。桥梁结构作为重要交通枢纽工程,其在整个地震序列发生时应确保通行,起到生命线工程的作用。选用集集地震序列对桥梁结构进行非线性时程分析,发现结构在主震作用下梁墩相对位移过大、主梁发生落座,余震作用下结构有发生落梁的可能。对结构设置防落梁装置,并进行非线性时程分析,结果显示连梁装置可有效抑制桥梁上、下部结构相对位移,提高结构抗推能力与整体性,保证了结构在整个地震序列中不发生落梁震害。在抗震分析中,应考虑到强余震对结构带来的影响,保证损伤结构在地震序列中的安全。     

Evaluation of the impact of matrix effects in LC/MS measurement on the accurate quantification of neonicotinoid pesticides in food by isotope-dilution mass spectrometry

The use of isotope-labeled internal standards is the most widely accepted approach to overcome the matrix effects on quantification of pesticides in food by LC/MS. We evaluated the impact of the matrix effects on quantification of six neonicotinoid pesticides, acetamiprid, clothianidin, dinotefuran, imidacloprid, thiacloprid, and thiamethoxam, in food by using deuterated internal standards. The calibration curves for each pesticide were obtained by using matrix-free and matrix-matched calibration solutions with blank brown rice, carrot, and green onion extracts. For brown rice and carrot, the matrix effects were not observed. In contrast, the slopes of calibration curves for each pesticide were influenced by presence of green onion extracts in calibration solutions (variability of the slopes was 4–9%), because the ratios of peak area for native pesticide to those for internal standards were influenced by matrix. The spike-and-recovery test with green onion was also performed. The analytical values obtained by using matrix-free calibration solution were biased from the spiked concentration, whereas those obtained by using matrix-matched calibration solution were comparable to the spiked concentration. These results indicate that matrix-matched calibration solution should be used for accurate quantification of neonicotinoid pesticides in food by LC/MS using deuterated internal standards.     

外秦淮河底泥释放对上覆水水质的影响

通过静态模拟实验，分析了外秦淮河底泥中释放出的与黑臭有关的DO、COD、NH3-N对上覆水水质的影响。上覆水中COD质量浓度是前4d呈下降趋势，至第11d基本稳定；NH3-N质量浓度是前4d呈上升趋势，至第11d趋于稳定；DO质量浓度是从开始实验时的7mg/L左右，很快下降至第11d的1mg/L以下才基本稳定。结果表明，外秦淮河底泥释放对上覆水水质有一定影响，并且这种释放有明显的梯度效应。     

转盘式光催化燃料电池处理染料废水

采用阳极氧化法制备转盘式TiO_2阳极,设计并开发了转盘式光催化燃料电池(PFC),探讨了圆盘转速对PFC中染料降解效果的影响。实验结果表明:随着圆盘转速的提高,污染物和光电界面反应产物的传质作用得以强化,罗丹明B降解率提高;在圆盘转速为1 600 r/min、反应时间为60 min的条件下,罗丹明B降解率达90.8%,是圆盘转速为0 r/min时的8.5倍;光电流也随着圆盘转速的提高而提高,但提高幅度远小于罗丹明B降解率的提高幅度;同时,加强传质作用后再外加电压对PFC催化降解性能的提高作用有限。     

西宁市非采暖季和采暖季PM2.5中14种金属元素特征

于2012年11月采暖季和2013年9月非采暖季,在青藏高原典型城市西宁市4个采样点采集细颗粒物(PM_(2.5))样品,共获得40个有效样品。用微波消解-ICP-MS法、原子荧光法分析了样品中14种重点防控金属。结果表明:14种重点防控金属中Ag、Tl平均质量浓度为0.10~0.50 ng/m~3,Co、Sb、Hg平均质量浓度为0.50~4.00 ng/m~3,V、Cd、Cr、Ni、Cu、As平均质量浓度为4.00~50.0 ng/m~3,Mn、Pb、Zn平均质量浓度为50.0~2 000 ng/m~3。采样期间,采暖季相比非采暖季,PM_(2.5)质量浓度有下降趋势,不同采样区金属元素浓度有增有减。富集因子分析结果表明,重点防控金属元素在非采暖季主要来源于土壤风沙扬尘、机动车尾气和工业排放,采暖季主要来源于土壤风沙扬尘、燃煤、燃油、机动车尾气和工业排放。非采暖季Zn、Ag、Cd、Hg、Tl和Pb富集因子较高,采暖季Zn、As、Ag、Cd、Sb、Hg、Tl、Pb富集因子较高,更容易受到人为源的影响。     

A meta‐analysis of the antecedents of work–family enrichment

This study meta‐analytically examined theoretically derived antecedents of both directions of work–family enrichment (sometimes labeled facilitation or positive spillover), namely, work–family enrichment and family–work enrichment. Contextual and personal characteristics specific to each domain were examined. Resource‐providing (e.g., social support and work autonomy) and resource‐depleting (e.g., role overload) contextual characteristics were considered. Domain‐specific personal characteristics included the individuals' psychological involvement in each domain, the centrality of each domain, and work engagement. Results based on 767 correlations from 171 independent studies published between 1990 and 2016 indicate that several contextual and personal characteristics have significant relationships with enrichment. Although those associated with work tend to have stronger relationships with work–family enrichment and those associated with family tend to have stronger relationships with family–work enrichment, several antecedent variables have significant relationships with both directions of enrichment. Resource‐providing contextual characteristics tend to have stronger relationships with enrichment than do resource‐depleting characteristics. There was very little evidence of gender being a moderator of relationships between contextual characteristics and enrichment. Lastly, meta‐analytic structural equation modeling provided evidence that a theoretical path model wherein work engagement mediates between several contextual characteristics and enrichment is largely generalizable across populations.     

Evaluating the usability of a commercial cooling vest in the Hong Kong industries

Objective. The provision of appropriate personal cooling vests is recognized as an effective measure to combat heat stress. However, personal cooling vests are not widely implemented in the Hong Kong industries. The current study aims to evaluate the usability of a hybrid cooling vest that is associated with the success of its application in industrial settings. Methods. A self-administrated questionnaire focusing on 10 subjective attributes of cooling effect, ergonomic design and usability of a hybrid cooling vest was administered with 232 occupational workers in the construction, horticultural and cleaning, airport apron services and kitchen and catering industries. Results. A structural equation model estimated by analysis of moment structures was constructed to evaluate the usability of the cooling vest, as influenced by cooling effect and ergonomic design. Results showed that cooling effect (path coefficient?=?0.69, p?p?Conclusions. The structural equation model is feasible to examine the complex nature of the structural relationships among the subjective perceptions of personal cooling vests. The empirical findings furnish sound evidence for further optimization of the hybrid cooling vest in terms of cooling effect and ergonomic design for occupational workers.     

流动人口居留意愿的梯度变动与影响机制

随着城乡利益格局的变化,新生代流动人口的居留意愿呈现出新的特征,其变动与城市类型密切相关。利用调查数据进行分析,发现新生代流动人口的居留意愿表现出随流入地的城市类型而梯度变动的特征,即呈现出在大城市的居留意愿强,中小城市的流动性强和特大城市的返乡意愿强的特征,大城市是新生代流动人口实现留城理想与个人发展最佳的平台。但是总的来说,新生代流动人口的流动行为与第一代流动人口同中存异,没有出现根本性的改变。利用多层模型,对新生代流动人口居留意愿的影响机制进行了实证分析,发现城市类型、经济收入、社会融入与身份认同、家庭迁居、户籍可获得性是影响居留意愿的重要因素。此外,户籍可获得性与新生代流动人口身份认同交互作用显著的影响了新生代流动人口的居留意愿,并进一步增强了居留意愿在不同城市类型的差异。这体现出户籍制度对流动者的影响逐步由早期的福利隔绝向心理隔绝转变。对不同城市类型新生代流动人口居留意愿的差异进行量化分析发现,特大城市和大城市流动者的居留意愿呈现刚性,而超大城市和中小城市流动者居留意愿具有弹性。根据上述分析提出政策建议:将大城市作为吸纳流动人口的主导区域构建城市发展规划策略,发挥特大城市和大城市的集聚效应,促进区域的产业发展;在城市社区建设和城市文明建设方面,为流动人口与城市居民的相互融合提供政策支持;依托政府、社会组织与学校,提升新生代流动人口的人力资本。