Synthesis and biodegradation of poly(γ-butyrolactone-co-l-lactide)

Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.¹H and¹³C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×10⁴. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT _m andT _g values of the copolymers showed a gradual depression with an increase in BL content. NoT _m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers.     

黄山风景区物质容量研究

系统地分析了旅游区物质容量与其子容量之间的关系,根据黄山区风景区客流空间负荷特点,认为北海游览区是黄山风景区物质容量的“瓶照”最低水桶板原则,合理计算了黄山风景区物质容量;详细探讨了扩大黄山风景区物质容量的若干途径。     

伊犁地区矿泉水中无机成分分析

通过对伊犁地区部分矿泉水水质分析,展示了该地区矿泉水中微量元素含量及其分布的特点,为今后开发和利用水地区的矿泉资源提供了一定的科学依据.     

Enzymatic degradation of poly([R,S] β-hydroxybutyrate)

The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity.     

污染环境的刑事责任问题探讨

根据一些发达国家的法律实践和我国环境保护工作的实际需要,探讨了对环境造成严重恶果的行为,应设立“污染环境罪”来调整人们行为的最后法律手段的必要性,并就污染环境罪的基本特征及与其它法律责任的区别作了分析和阐述,提出在我国刑法中应专条补充设立“污染环境罪”规定的建议。     

乡镇环境保护的“角直模式”

本文分析了江苏省角直镇乡镇经济腾飞与环境保护协调同步的发展过程,总结出了“统一规划、合理布局、集中控制、全面管理、环境保护与经济建设协调发展”的“角直模式”,并就模式的优缺点作了一定程度的探讨.     

在监测样本信息的基础上确定水环境系统权重的分配方法

权重确定是水环境质量评价中很重要的一个方面，本文在监测样本信息的基础上，利用正交旋转变换方法，提出了一种权重确定方法，并结合实际进行了计算。     

从生态环境角度论鄱阳湖区农业可持续发展

鄱阳湖区农业资源十分丰富，具有发展大农业的优越条件。本文通过对湖区农业生态环境的脆弱性分析，指出湖区农业的非良性循环特性，提出防洪、抗旱、治涝、血吸虫病治理等对策措施，为湖区农业可持续发展提供决策参考。     

宜宾市水资源保护与可持续发展问题的探讨

本文从近几年来宜宾市工业及生活废水等排放情况及水环境质量的监测资料，阐述了我市流域水污染状况与可持续发展面临的主要问题，提出了水资源保护对策，以促进社会经济可持续发展。     

磷肥厂烘干磨高压静电除尘技术及应用

本文根据高压静电除尘的原理,磷肥厂烘干磨粉尘的特性分析,以及作者本人的工作实践,探讨了高压静电除尘技术在磷肥厂烘干磨粉尘治理中应用的可行性。