天津地区冬季总悬浮颗粒物中PAHs污染特征

采集并分析了天津不同区县13个样点冬季总悬浮颗粒物(TSP)中16种优控多环芳烃(PAHs)含量.结果表明不同样品间PAHs含量差异明显,东部开发区和中北部区县含量明显高于其它地区,大港油田的颗粒物中PAHs含量很低,市区、南部区县和北部山区居中.根据毒性等效因子计算了等效浓度,不同样品PAHs总等效浓度差异不大,占总浓度50%的高环PAHs毒性贡献达90%.     

Isomer‐specific determination and toxic evaluation of potentially hazardous coplanar PCBs,dibenzofurans and dioxins in the tissues of “Yusho” PCB poisoning victim and in the causal oil

In the light of new discoveries on the extremely toxic non‐ortho coplanar 3,3’,4,4'‐tetra‐ (T₄CB), 3,3’,4,4’,5‐penta‐(P₅CB) and 3,3'4,4’,5,5'‐hexachlorobiphenyl (H₆CB) and their mono‐ and di‐ortho analogs, tissue samples of a Yusho poisoning victim and Yusho causal oils were subjected to a thorough congener/isomer‐specific investigation for polychlorinated biphenyls (PCBs), polychlorinated dibenzofurans (PCDFs), polychlorinated dibenzo‐p‐dioxins (PCDDs). Among the many PCB congeners detected in Yusho oil, non‐ortho coplanar T₄CB constituted 3.1%, P₅CB‐0.17% and H₆CB‐0.0072% in total PCBs. Their concentrations in liver and adipose tissue were 130–700 (T₄CB), 54–720 (P₅CB) and 50–380 (H₆CB) pg/g on wet weight basis. The observed concentrations in adipose tissue were two to four fold higher than that detected in unexposed individuals. Among the PCDFs identified, toxic 2,3,7,8‐substituted isomers including 2,3,4,7,8‐P₅CDF were the dominant ones. Tetra‐ through hepta‐CDDs were detected in the oil, whereas octa‐CDD was the dominant isomer in the patient. A comparison with KC‐400 revealed enrichment of coplanar PCBs in Yusho oil along with toxic PCDFs. Enrichment was highest for 3,3'4,4'5,5'‐H₆CB followed by 3,3’,4,4'5‐P₅CB. A comparative toxic evaluation of these chemical groups in Yusho patient's adipose tissue based on “2,3,7,8‐T₄CDD Toxic Equivalent Analysis” revealed accountable toxic contribution from coplanar PCBs. This analysis also confirmed that 2,3,4,7,8‐P₅CDF was the principal causative agent in Yusho poisoning.     

汽车炸弹爆炸下装配式防爆墙弹塑性动力计算与数值分析

根据汽车炸弹恐怖爆炸的特点,计算了汽车炸弹近地爆炸空气冲击波参数,提出了防爆墙结构等效静载的弹塑性动力计算方法。按该方法设计了一种钢板混凝土装配式防爆墙组合结构,并与有限元数值分析结果进行了比较。结果表明,按该方法设计的防爆墙结构,其设计荷载只有其峰值压力的五分之一,能很好地发挥防爆墙结构塑性变形的特点,具有较大的经济价值。     

熔融硝盐高温分解爆炸事故后果严重度评价

为评价热处理用硝盐槽熔融硝盐高温分解爆炸事故机理和后果严重度,结合某企业铝合金件硝盐固溶热处理工艺进行研究。 利用压缩气体容器爆炸能量计算模型、超压准则和TNT当量法估算热处理用硝盐槽内熔融硝盐高温分解爆炸事故后果,得出35 000 kg熔融硝盐在高温分解转化率为50%时爆炸的TNT当量为1 257.6 kg,爆炸会造成半径53.97 m范围内的人员轻伤,该结果和利用政府推荐的危险指数法得出的外部防护距离为50 m较为接近。 以上分析计算表明:超温爆炸过程中,熔融硝盐在硝盐槽中超温分解快速产生大量气体,在硝盐槽上盖及上部硝盐的阻挡下不能及时排出,致使硝盐槽内气体压力瞬间升高,形成类似于压力容器的空间,发生物理爆炸并引发高温硝盐喷溅。     

基础隔震结构抗震可靠度简化分析方法

选用胡聿贤平稳地震地面运动模型作为基础隔震结构的随机地震动输入,采用Bouc-Wen模型描述隔震结构的层间滞变位移,将滞变体系动力特性矩阵随机等效线性化,并建立等价线性状态方程.引入左右特征向量系,对振动微分方程进行解耦,推导了基础隔震结构随机地震响应的统计矩解析解.采用变形失效准则,定义了上部结构和隔震层的功能状态极...     

半城市化地区家庭生活垃圾特征及低碳对策：以厦门市集美区为例

半城市化地区已成为城市化研究的热点,但其生活垃圾管理问题常被忽视.以典型半城市化地区——厦门市集美区为例,通过问卷调查与实地采样两种方法,分析不同住区家庭生活垃圾产生的特征,并通过生命周期分析法,对比混合填埋、混合堆肥、混合焚烧以及分类处理4种垃圾处理方案的温室气体排放,提出相应的垃圾管理对策.结果表明：半城市化地区可...     

关于环境保护税法(草案)几个问题的探讨

《环境保护税法(草案)》已经初次审议并公布草案全文征求意见,本文对草案中有关问题进行了探讨,期望这些建议能为修改法律草案条文提供参考。关于水污染物环境保护税的纳税人,建议按照直接向环境排放污水的企业事业单位和其他生产经营者、城镇污水集中处理设施、园区污水集中处理设施等三类区分;关于大气污染物、水污染物的征税范围与方法,建议近期将大气污染物中的重金属项目也纳入应税污染物,与水污染物征税范围保持一致,远期考虑与排放标准脱钩,重新审视、确定应税污染物的范围、筛选原则与当量值;关于综合利用固体废物征收环境保护税问题,建议对综合利用过程在满足环保标准要求条件下,免征环境保护税,而综合利用形成的原材料或产品则不适用本法。另外本文还提出了未来环境保护税应覆盖产品全生命周期的生产、使用、废弃等环节的观点。     

宁波地区当量加速环境谱的编制

首先利用宁波地区接近十年的环境资料数据编制了该地区的环境谱,其次基于电化学腐蚀原理和腐蚀电量相等的原理,建立了自然腐蚀环境向实验室加速环境折算的当量关系,并从力学性能和腐蚀深度进行验证,最后给出了可供实验室加速试验用的宁波地区加速环境谱。     

Ricin as a weapon of mass terror — Separating fact from fiction

In recent years there has been an increased concern regarding the potential use of chemical and biological weapons for mass urban terror. In particular, there are concerns that ricin could be employed as such an agent. This has been reinforced by recent high profile cases involving ricin, and its use during the cold war to assassinate a high profile communist dissident. Nevertheless, despite these events, does it deserve such a reputation? Ricin is clearly toxic, though its level of risk depends on the route of entry. By ingestion, the pathology of ricin is largely restricted to the gastrointestinal tract where it may cause mucosal injuries; with appropriate treatment, most patients will make a full recovery. As an agent of terror, it could be used to contaminate an urban water supply, with the intent of causing lethality in a large urban population. However, a substantial mass of pure ricin powder would be required. Such an exercise would be impossible to achieve covertly and would not guarantee success due to variables such as reticulation management, chlorination, mixing, bacterial degradation and ultra-violet light. By injection, ricin is lethal; however, while parenteral delivery is an ideal route for assassination, it is not realistic for an urban population. Dermal absorption of ricin has not been demonstrated. Ricin is also lethal by inhalation. Low doses can lead to progressive and diffuse pulmonary oedema with associated inflammation and necrosis of the alveolar pneumocytes. However, the risk of toxicity is dependent on the aerodynamic equivalent diameter (AED) of the ricin particles. The AED, which is an indicator of the aerodynamic behaviour of a particle, must be of sufficiently low micron size as to target the human alveoli and thereby cause major toxic effects. To target a large population would also necessitate a quantity of powder in excess of several metric tons. The technical and logistical skills required to formulate such a mass of powder to the required size is beyond the ability of terrorists who typically operate out of a kitchen in a small urban dwelling or in a small ill-equipped laboratory. Ricin as a toxin is deadly but as an agent of bioterror it is unsuitable and therefore does not deserve the press attention and subsequent public alarm that has been created.     

铁路噪声预测模式的监测验证与误差分析

为了验证列车通过的等效声级、等效时间及预测模式的正确性,选择了一个开阔的场所,在距离铁路外轨中心线30 m处采用两种不同的方式记录列车通过时的源强及持续时间,然后利用监测值预测60 m处的1h等效连续A声级,并与60 m处的1h等效连续A声级监测值进行对比.结果表明,列车经过身边到离开时的持续时间作为等效时间,经过身边时的最大噪声级作为源强,所得到的预测值与监测值的误差范围在-0.3～0.9 dB(A),方差为0.229,离散度较小,预测值与监测值较吻合,可用于指导设计与规划工作.同时,在分析误差产生原因的基础上,提出了提高预测准确性的建议.