巯基改性高岭土负载CeO2-CdS光催化降解结晶紫

为获得高效催化活性的光催化材料,实现偶氮类染料的高效降解,试验以巯基乙酸钠作为硫源和高岭土改性剂合成了巯基高岭土/CeO₂-CdS催化剂,并以降解结晶紫为模板反应,优化确定了巯基高岭土/CeO₂-CdS催化剂的制备条件.采用XRD（X射线衍射）、SEM（扫描电子显微镜）、TEM（透射电子显微镜）、FTIR（傅里叶红外光谱）和UV-Vis（紫外-可见光漫反射光谱）对催化剂进行了表征.结果表明:①催化剂是由巯基高岭土、立方相结构的CdS和萤石结构的CeO₂组成;②CdS和CeO₂的负载破坏了巯基高岭土的层状结构;③最优催化剂和巯基高岭土/CeO₂的可见光的响应范围分别为550和450 nm;④当CeO₂:CdS（摩尔比,下同）为4:6,巯基高岭土:CeO₂-CdS（质量比,下同）为1:3时,催化剂具有最优的光催化活性;⑤在50 mL结晶紫浓度为10 mg/L的溶液中,添加0.1 g最优催化剂后,采用350 W氙灯对其光照150 min时,结晶紫的降解率为95.1%;⑥最优催化剂具有良好的重复使用性能,重复使用5次时,对结晶紫的降解率为90.4%.研究显示,结晶紫降解的最终产物为CO₂和H₂O,催化剂对结晶紫的降解机理是以羟基自由基氧化为主和超氧基氧化为辅的共存氧化机理.      

红绒盖牛肝菌菌丝对Cu(Ⅱ)和Cd(Ⅱ)生物吸附的影响因子

在离体条件下,研究了外生菌根真菌红绒盖牛肝菌(Xerocomus chrysenteron)菌丝对 Cu(Ⅱ)和 Cd(Ⅱ)生物吸附的影响因子,考察了X. chrysenteron菌丝对 Cu(Ⅱ)和 Cd(Ⅱ)的吸附能力、去除率和平衡吸附量在不同初始质量浓度和不同温度下所受影响,并采用Freundlich和Langmuir线性化吸附等温线模型拟合X. chrysenteron菌丝的生物吸附热力学特性. 结果表明:当菌丝的质量浓度为10g/L, 30 ℃时,X. chrysenteron非活性菌丝对 Cu(Ⅱ)和 Cd(Ⅱ)的最佳吸附量分别为47.11和11.72mg/g(以菌丝干质量计);X. chrysenteron非活性菌丝对 Cu(Ⅱ)和 Cd(Ⅱ)的吸附能力、去除率、平衡吸附量均优于活性菌丝;X. chrysenteron菌丝对 Cu(Ⅱ)和 Cd(Ⅱ)的吸附能力随其初始质量浓度的增加而增大,去除率随其初始质量浓度的增大而分别呈指数下降和线性下降;30 ℃时X. chrysenteron菌丝对 Cu(Ⅱ)和 Cd(Ⅱ)的吸附能力、去除率、平衡吸附量均比 25 ℃时大.     

交联壳聚糖-CdS颗粒可见光催化脱色甲基橙研究

利用壳聚糖对金属离子的配位络合作用和吸附性能,模拟生物矿化仿生制备交联壳聚糖/CdS复合粒子。以甲基橙为处理对象,氙灯模拟可见光,研究了该复合材料对甲基橙的降解脱色性能。用Langmuir-Hinshelwood方程从动力学的角度,考察了不同催化剂浓度、甲基橙的初始浓度、反应体系的pH值、外加无机阴离子等对甲基橙降解脱色的影响。结果表明,该复合材料的吸附性能和光催化活性产生的协同作用能较有效促进甲基橙染料的脱色,在低质量浓度条件下可见光催化过程为假一级反应。光催化剂的最佳用量为1.5g/L,甲基橙降解的最佳pH为4.0。Cl-和Br-均对MO的光催化脱色起抑制作用,而NO3-的添加明显促进MO的光催化速率。     

Cd在无瓣海桑模拟湿地系统中的分布迁移及净化效应

在温室中建立红树林植物无瓣海桑模拟湿地系统,分别用正常、5倍和10倍浓度3种人工配制的生活污水定时定量对模拟系统污灌4个月,研究重金属Cd的分布、迁移以及湿地系统对Cd污染的净化效应。结果表明,污水中的Cd主要存留在土壤子系统中(约90%),只有很少部分迁移到植物体和凋落物中;无瓣海桑各器官中Cd含量在根部最高;模拟系统对污水中Cd的净化效果显著,在植物-土壤-水系统中,正常、5倍和10倍浓度组的净化率分别为96.04%、85.19%和92.24%,在无植物系统中,对应组分别为81.18%、85.46%和80.96%。     

Variation of grain Cd and Zn concentrations of 110 hybrid rice cultivars grown in a low-Cd paddy soil

Enhanced Cd uptake and Zn depletion in rice grains and high potential for food Cd exposure by the high-yielding hybrid cultivars of China had been addressed. A field experiment was conducted in 2006 to determine the di erence in grain Cd and Zn between cultivars. Total 110 cultivars including super rice and common hybrid rice cultivars were grown on a single paddy soil (Entic Haplaquept) with a neutral reaction and low total Cd content. Grain Cd and Zn concentrations were determined with graphite atomic adsorption spectrophotometer (GFAAS) and flame atomic adsorption spectrophotometer (AAS) respectively.Wide variation of Cd content in grain was found in a range of 0.004–0.057 mg/kg, while the Zn content in a range of 10.25–30.06 mg/kg among the cultivars. Higher Cd but lower Zn concentration in grains of super rice cultivars was observed compared to the common hybrid ones. A highly significant positive linear correlation of grain Cd/Zn with grain Cd was found for super rice and common hybrid cultivars, meanwhile much higher slope for these hybrid cultivars than the reported non-hybrid cultivars was also observed. Using the limit value of the Chinese chemical guidelines for foods (MOHC and SSC, 2005), calculated potential risk of food Cd exposure with “Zn hungry” through diet intake was prominent with all the studied 110 hybrid rice cultivars, possessing high potential health problems for rice production in South China using the super rice cultivars. Breeding of genotypes of rice cultivars with low grain Cd and low Cd/Zn ratio is needed for rice production in acidic red soils where Cd bioavailability is prevalently high.     

Photocatalytic degradation of methyl orange over ITO/CdS/ZnO interface composite films

ITO/CdS/ZnO interface composite films were successfully prepared by subsequent electrodeposition of CdS and ZnO onto indium tin oxide (ITO) glass substrates. The obtained ITO/CdS/ZnO composite films were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), and UV-Vis spectroscopy. The photocatalytic activity of ITO/CdS/ZnO composite films were investigated using methyl orange (MO) as a model organic compound under UV light irradiation. The influence of operating parameters on MO degradation including initial concentration of MO, pH value of solution, and inorganic anion species over the composite films were examined. A blue shift of absorption threshold was observed for the ITO/CdS/ZnO film in comparison with ITO/ZnO film. ITO/CdS/ZnO composite films prepared under specific conditions showed a higher photocatalytic activity than that of ITO/ZnO films. It was also found that the photocatalytic degradation of MO on the composite filing followed pseudo-first order kinetics.     

Bioaccumulation of cadmium bound to humic acid by the bivalve Meretrix meretirx Linnaeus from solute and particulate pathways

Humic acid is an important pool of heavy metals in sediments.Generally,the presence of refractory humic matter in aquatic systems would decrease the bioavailability of Cd and hence control the bioaccumulation of Cd in benthic animals.In the present work,we applied a suspending system to determine the relative importance of particulate and dissolved fractions of humic acid as Cd sources for the bivalve Meretrix meretrix and to investigate the difference of bioaccumulation characteristics of Cd adsorbed on di...     

镉、铅在沉水植物龙须眼子菜叶片中的分布

采用室内浸提、扫描电镜附加能谱分析、差数离心和凝胶层析等手段,研究了镉、铅在龙须眼子菜(Potamogeton pectinatus)叶片中的分布.结果表明,龙须眼子菜对镉、铅具有很强的吸收能力,对溶液中镉、铅的平均去除效率分别为84%、91%.当镉、铅处理液浓度分别为6.67,83.00μmol/L时,龙须眼子菜对镉、铅的生物积累量分别为496,10800mg/kg,其中可溶态镉、铅的浓度分别为55.0,14.1mg/kg,说明龙须眼子菜叶片中的镉、铅大部分都是以结合态存在的.铅在龙须眼子菜叶细胞上的分布重量百分比及原子百分比均高于镉.15%的镉和25%的铅分布在龙须眼子菜的细胞壁中;56%的镉和25%的铅分布在液泡和胞基质中.龙须眼子菜叶片中除了有小分子蛋白与镉结合外,还有其他小分子有机物也能与镉结合,而铅则主要与小分子蛋白结合.     

镉诱导长江华溪蟹肝胰腺细胞凋亡研究

应用显微与亚显微技术和琼脂糖凝胶电泳方法,研究了不同浓度Cd2+(0、7.25、14.50、29.00、58.00和116.00mg·L-1)处理不同时间(24、48、72和96h)对长江华溪蟹(Sinopotamon yangtsekiense)肝胰腺细胞凋亡的影响.结果显示,29.00mg·L-1Cd2+处理48h,光镜下肝胰腺细胞凋亡主要表现为染色质不规则凝聚、固缩和边集;58.00mg·L-1Cd2+处理72h,细胞核碎裂,形成凋亡小体;116mg·L-1Cd2+处理96h,出现坏死细胞;电镜下48h和72h处理组肝胰腺细胞呈现典型的细胞凋亡特征,与光镜检测结果一致,具体表现为核边集、核膜折叠、核裂解形成凋亡小体.琼脂糖凝胶电泳图谱中48和72h处理组出现凋亡细胞所特有的DNA梯状条带,58.00mg·L-1Cd2+处理72h后条带尤为清晰.随着Cd2+浓度的增加和处理时间的延长,肝胰腺中凋亡细胞所占比例呈现先升后降的趋势,凋亡指数的变化表现出显著的剂量和时间效应关系.研究表明,镉能够诱导长江华溪蟹肝胰腺出现细胞凋亡.细胞凋亡的检测及凋亡指数的变化能够灵敏地反映出镉对水生动物的胁迫程度及毒性大小,可作为水生态环境镉污染的生物评估指标.     

Ecotoxicological effects of polycyclic musks and cadmium on seed germination and seedling growth of wheat (Triticum aestivum)

Single and joint toxic e ects of polycyclic musks including 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[g]-2- benzopyran (HHCB) and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronapthalene (AHTN) and cadmium (Cd) on seed germination and seedling growth of wheat (Triticum aestivum) were investigated. The results showed that the toxicity sequence of HHCB toxic to wheat seed germination and seedling growth was similar to that of AHTN, that is, germination rate > shoot elongation > root elongation, while the toxicity of Cd was in the sequence of root elongation > shoot elongation > germination rate, according to the LC50 and EC50 values. It is suggested that polycyclic musks and Cd had di erent toxicological mechanisms. Root and shoot elongation of wheat might be good bioindicators for the contamination of polycyclic musks and Cd in soil. The mixture of polycyclic musks and Cd had synergistic e ects on T. aestivum according to the equi-toxic mixture approach when root elongation was selected as the toxicological endpoint. Thus, the joint toxicity of HHCB and Cd was significantly higher than the single toxicity of HHCB or Cd, which was also confirmed by the EC50 mix value of the mixture (EC50 mix = 0.530 TUmix). The EC50 mix value of the mixture of AHTN and Cd was 0.614 TUmix, which indicated that the mixture toxicity was strengthened when AHTN coexisted with Cd.