Study on the hydrolysis/precipitation behavior of Keggin Al13 and Al30 polymers in polyaluminum solutions

The hydrolysis/precipitation behaviors of Al³⁺, Al₁₃ and Al₃₀ under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl₃, PAC_Al13 and PAC_Al30 were 6.5–7.5, 8.5–9.5, and 7.5–9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl₃ ? PAC_Al30 > PAC_Al13. The precipitates' size increased when the dosage increased from 50 μM to 200 μM, but it decreased when the dosage increased to 800 μM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The iso-electric points of the freshly formed precipitates for AlCl₃, PAC_Al13 and PAC_Al30 were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl₃ hydrolysis precipitates were lower than those of PAC_Al13 and PAC_Al30 when pH > 5.0. The Zeta potential of PAC_Al30 hydrolysis precipitates was higher than that of PAC_Al13 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al–Ferron research indicated that the hydrolysis precipitates of AlCl₃ were composed of amorphous Al(OH)₃ precipitates, but those of PAC_Al13 and PAC_Al30 were composed of aggregates of Al₁₃ and Al₃₀, respectively. Al³⁺ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al₁₃ and Al₃₀ species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al–Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al–Ferron method. The chemical composition of Al_a, Al_b and Al_c depended on coagulant and solution pH. The Al_b measured in the current case was different from Keggin Al₁₃, and the high Al_b content in the AlCl₃ hydrolysis precipitates could not used as testimony that most of the Al³⁺ was converted to highly charged Al₁₃ species during AlCl₃ coagulation.     

生态旅游环境教育功能的实现途径研究

生态旅游是一项具有保护自然生态与文化多样性,提高旅游者环境意识及维护当地居民生活双重责任的旅游活动,具有较强的环境教育功能。但其功能的发挥不是旅游活动的自然结果,而有赖于人的自觉和切实有效的环境教育。本研究基于对生态旅游环境教育功能及其影响因素正确认识基础上,构建生态旅游环境教育功能实现的基本框架,并系统阐述环境解说、产品设计、舆论监督、宣传教育、环境管理等途径。本研究对促进生态旅游健康发展和国民环境教育具有重要意义。     

联合生物法处理炼油厂含油污泥的研究

大港石化公司采用联合生物法处理含油污泥,对使用好氧、厌氧工艺处理含油污泥的结果进行了探讨。实验结果表明:先进行好氧处理然后脱水再进行厌氧堆肥工艺处理含油污泥,除油率达到97.6%,除磷、钾的指标低于《城镇垃圾农用控制标准》(GB8172-87)的要求外,其他指标均符合该标准要求,且避免了二次污染。     

基于ASEB栅格分析法的旅游产品开发研究——以福建省湄洲岛为例

基于旅游体验理论为指导,在福建省湄洲岛旅游资源评价的基础上,运用ASEB栅格分析法对湄洲岛旅游产品开发进行了深度分析,提出产品谱系研究、创新旅游活动、联动开发文化旅游产品以及重点开发湄洲岛中部爱情旅游产品等对策.     

Agricultural Structure in Western China by Comparing with before and after CFFG Based on Shift-share Method

Based on shift-share method, this article employs re- gional share, structural shift and competitive shift to analyze the structural benefit and competitive position of agricultural structure in western China by comparing with agriculture, foresting, stockbreeding and fishing before and after Conversion of Farmland to Forest and Grassland （CFFG）. Then authors draw following conclusion： while CFFG program has been put in practice, the agricultural structure in western China has some typical characteristics, such as growth faster, structural predominance obvious and more competitive. But the contributiveness from the competition is not too much yet, and the structural benefit of forest estate and stockbreeding are restrained.     

环境库兹涅茨曲线假说在中国的经验研究

改革开放以来,中国年均98%的经济持续增长举世瞩目,然而对经济增长所付出的环境代价却存在着诸多争议。环境库兹涅茨曲线（EKC）假说是对环境 收入关系研究的经典表述,可以直观地展现环境与收入变化的关系。在前人研究EKC时运用单一或多个单一指标测量污染程度存在缺陷的基础上,基于 1982～2006年中国6类环境污染物,用改进的熵值法计算出代表我国整体环境污染状况的环境污染指数,利用协整检验来研究中国环境库兹涅茨曲线的存在性及其“本土化”特征,发现与一般发达国家和新兴发展中国家的“倒U”型环境库兹涅茨曲线不同,中国综合环境污染模型呈“正U”型,以21世纪初为分界点,之前环境污染水平不断下降,之后环境污染又开始有所恶化;利用脉冲响应函数来考察环境污染和经济增长的互动关系,发现经济增长在追溯期内对环境污染均为正向影响,而环境污染仅在短期对经济增长有促进作用。这一研究旨在为制定符合中国国情的环境、经济政策,实现经济与环境协调发展提供理论依据.     

The effects of scale and spatial heterogeneities on diffusion in volcanic breccias and basalts: Amchitka Island, Alaska

Knowledge of the factors that influence the diffusion of contaminants, such as the diffusivity and the connected porosity, is crucial to modeling the long-term fate and transport of contaminants in subsurface systems with small or negligible advective flow, such as in fractured crystalline rock. Fractured rock is naturally heterogeneous, and hence, understanding the diffusivity of a molecule through this material (or the formation factor of the medium) becomes a complex problem, with critical concerns about the scale of laboratory measurements and about the spatial variability of these measurements relative to the scale needed for fate and transport modeling. This study employed both electrical and tracer-based laboratory methods to investigate the effects of scale and pore system connectivity on the diffusivity for volcanic matrix rock derived from the study site, a former underground nuclear test site at Amchitka Island, Alaska. The results of these investigations indicate a relatively well-connected pore system with scale effects generally limited to approximately 6 cm lengths and well-correlated to observed heterogeneous features. An important conclusion resulting from this study, however, is that there is a potential for the estimated diffusivity to be misrepresented by an order of magnitude if multiple samples or longer sample lengths are not used. Given the relatively large number of measurements resulting from these investigations, an analysis of the probability density function (PDF) of the diffusivity was possible. The PDF of the diffusivity was shown to generally follow a normal distribution for individual geologic layers. However, when all of the geologic layers are considered together, the distribution of the subsurface as a whole was shown to follow a lognormal distribution due to the order of magnitude differences amongst the layers. An understanding of these distributions is essential for future stochastic modeling efforts.     

规划环境影响评价中的生物多样性评价方法探析

通过对国内外生物多样性评价现状、以GIS为基础的生态模型应用和生物多样性评价层次选择的分析,提出了将景观生态学和GIS为基础的生态模型综合以用于规划环评生物多样性评价的新思路     

烟气脱硫系统调试方法

介绍了风洞式烟气脱硫系统的工艺流程及原理,重点对烟气脱硫系统调试过程进行了阐述,为相关工程测试人员提供参考。     

Preferred modes of travel among older adults: What factors affect the choice to walk instead of drive?

Introduction

There are many factors that influence older adults' travel choices. This paper explores the associations between mode of travel choice for a short trip and older adults' personal characteristics.

Methods

This study included 406 drivers over the age of 64 who were enrolled in a large integrated health plan in the United States between 1991 and 2001. Bivariate analyses and generalized linear modeling were used to examine associations between choosing to walk or drive and respondents' self-reported general health, physical and functional abilities, and confidence in walking and driving.

Results

Having more confidence in their ability to walk versus drive increased an older adult's likelihood of walking to make a short trip by about 20% (PR = 1.22; 95% CI: 1.06-1.40), and walking for exercise increased the likelihood by about 50% (PR = 1.53; 95% CI = 1.22-1.91). Reporting fair or poor health decreased the likelihood of walking, as did cutting down on the amount of driving due to a physical problem.

Discussion

Factors affecting a person's decision to walk for exercise may not be the same as those that influence their decision to walk as a mode of travel. It is important to understand the barriers to walking for exercise and walking for travel to develop strategies to help older adults meet both their exercise and mobility needs. Impact on Industry: Increasing walking over driving among older adults may require programs that increase confidence in walking and encourage walking for exercise.