加速溶剂萃取-在线净化-液相色谱串联质谱法检测污泥堆肥样品中三氯生和三氯卡班

污泥堆肥样品基质复杂,其中三氯生（TCS）和三氯卡班（TCC）的提取和净化过程操作烦琐、回收率低。通过对净化条件进行优化,建立了加速溶剂萃取-在线净化-液相色谱串联质谱法检测污泥堆肥样品中TCS和TCC的分析方法,并对上海某污水厂实际污泥堆肥样品中的TCS和TCC进行定量分析。结果表明,TCS和TCC的检出限分别为0.003和0.0002μg/g,加标回收率为90.3%~99.8%,相对标准偏差（RSD）为1.2%~8.5%（n=6）。该方法样品前处理时间短、回收率高、试剂使用量少,能够满足实际污泥堆肥样品中TCS和TCC的检测要求。     

应急预案编制基本操作程序及方法

应急预案编制涉及行业领域专业技术、应急管理知识、工作进度和质量管控等多方面内容,是一项专业性、系统性很强的工作。为向公众普及有关工作程序和方法,笔者结合实际工作经验提炼出应急预案编制工作的核心思想,引入项目管理的思路,提出一种面向对象、以实践应用为导向的工作模式。本文有详细的步骤展示,提供相应的文本样式,并对常见工作方法、技巧和失误进行归纳分析。研究结果提供一种可行的思路参考,对于应急预案编制设计、评审等人员具有一定参考和科普传播价值。     

鱼体甲基汞的萃取富集和测定

研究了苯萃取和半胱氨酸滤纸富集再用苯洗脱的方法,使鱼肉中甲基汞得到富集和提取。建立了气相色谱测定甲基汞的方法并对所建立的方法进行评价。结果表明:加标回收率为87.10%～105.69%;变异系数为2.93%。符合要求,大量样品实验表明,该方法适用于痕量甲基汞的提取和分析。     

Measuring implicit psychological constructs in organizational behavior: An example using psychological capital

Implicit psychological constructs are effective predictors of behavioral outcomes but are rarely used in organizational settings because of real or imagined problems with measurement validity and administration. To address these concerns, we present a means of assessing implicit constructs quickly and easily by using psychological capital as an example. Copyright © 2012 John Wiley & Sons, Ltd.     

呼吸器标准中的泄漏率与实验室呼吸防护水平

结合国内外呼吸器最新标准中有关泄漏率与实验室呼吸防护水平的测试条件和方法,从基本概念和评价方法入手对比剖析了不同标准之间内容的差异.文中涉及的国内外标准主要有美国职业安全与健康研究所指定的系列化生放核呼吸器标准、欧洲EN 13274 - 1:2001、日本JIST8159:2006、中国GB 2626 - 2006和GB 2890 - 2009以及ISO/DIN 16900-1.2草案.通过对比分析不同标准之间在评价方法中采用的气溶胶种类、受试者人数、模拟动作种类及持续时间、采样方法、测试结果评价方法等具体内容,指出了我国呼吸器标准中泄漏率测试方法及相关标准发展中应注意的问题.     

油污染土壤气体抽排去污模型及影响因素

为了开展适合我国实际情况的有机污染土壤气体抽排净化技术研究,在对油污染土壤的通风去污过程机理进行分析的基础上,建立了一个简化机理模拟模型.以华北地区典型土壤为实验土样,油污染物为例,通过一维土柱实验,研究了抽排气体流速、土壤含水率和土质对去污过程的影响.实验表明抽排气体流速存在最佳值,土壤含水率对不同土质土壤净化时间影响不同,对粉砂土,含水率升高,净化效率增强;而对粘质土壤,结果正好相反.对模型预测结果进行实验验证表明,本文建立的模拟模型在实验限定条件范围内是准确和适用的.     

Fieldwork after conflict: contextualising the challenges of access and data quality

Despite sustained scholarly interest in post‐conflict states, there has not been a thorough review and analysis of associated methodology and the challenges of conducting research in these contexts. Addressing this gap, this paper directs attention to the particular effects of these settings on access and data quality and their ramifications for the resulting scholarship. It assesses the intrinsic challenges of performing fieldwork in these environments, drawing on both relevant social science literature and the authors’ experiences of carrying out research in Afghanistan and Timor‐Leste. The study demonstrates that the post‐conflict environment moulds research design and, consequently, influences how questions are answered as well as the questions asked. Moreover, it highlights ways to mitigate these issues. This work is of relevance to scholars planning to engage in field research and to researchers reflecting upon their work, as well as to policymakers who are considering undertaking programmes or commissioning research in post‐conflict areas.     

Electro-remediation of tailings from a multi-metal sulphide mine: comparing removal efficiencies of Pb,Zn, Cu and Cd

Sulphidic mine tailings characterised by high concentrations of heavy metals (Pb 3532?±?97?mg/kg, Zn 8450?±?154?mg/kg, Cu 239?±?18?mg/kg and Cd 14.1?±?0.3?mg/kg) and abundant carbonate (17%) were subjected to eight lab-scale electrodialytic remediation (EDR) experiments to investigate the influence of current density, treatment time and particle size on removal efficiency. Pb and Cu removal improved when increasing current density, while Zn and Cd removal did not. In contrast Zn and Cd removal improved by grinding the tailings, while Pb and Cu removal did not. At the highest current density (1.2?mA/cm²), 94%, 75%, 71% and 67% removal of Pb, Zn, Cu and Cd could be achieved, respectively, on grinded tailings in 28 days. Sequential chemical extraction made before and after EDR revealed larger oxidisable fractions of Zn, Cu and Cd, representing large fractions of sulphides, which was likely to be the main barrier to be removed as efficiently as Pb. This was in accordance with acid/base extraction tests in which Pb showed high solubility at both high and low pH (up to 65% and 86% of extraction, respectively), while considerable extraction of Zn (55%) happened only at low pH; and very limited extraction (<20%) of Cu and Cd occurred at any pH.     

Key considerations and challenges in the application of social-network research for environmental decision making

Attempts to better understand the social context in which conservation and environmental decisions are made has led to increased interest in human social networks. To improve the use of social-network analysis in conservation, we reviewed recent studies in the literature in which such methods were applied. In our review, we looked for problems in research design and analysis that limit the utility of network analysis. Nineteen of 55 articles published from January 2016 to June 2019 exhibited at least 1 of the following problems: application of analytical methods inadequate or sensitive to incomplete network data; application of statistical approaches that ignore dependency in the network; or lack of connection between the theoretical base, research question, and choice of analytical techniques. By drawing attention to these specific areas of concern and highlighting research frontiers and challenges, including causality, network dynamics, and new approaches, we responded to calls for increasing the rigorous application of social science in conservation.     

城市安全生产风险评估调研和信息处理方法研究

为城市安全生产风险评估调研工作的合理有序开展,本文结合实际案例归纳了城市安全生产风险评估调研的目的、范围、内容和流程,具体介绍了走访座谈法、常专结合法、函件调研法等信息采集方法,总结了综合归纳法和逻辑处理法等信息处理方法。结果表明,在调研的不同阶段运用不同的调研方法可有效获取城市安全生产风险源信息及安全生产基本信息,为城市安全生产风险评估工作奠定坚实的信息数据资料支撑。