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121.
研究了有机磷酸羟基亚乙基二膦酸(HEDP)对生活垃圾焚烧飞灰中重金属的稳定方法.通过对不同HEDP投加量处理后的飞灰试样作危险废物浸出毒性鉴别试验,分析HEDP最佳使用剂量,并评价了稳定化飞灰的长期稳定性.结果表明,HEDP最适使用剂量为0.03 Ml/g(以商品级HEDP与飞灰的体积质量比计),处理后飞灰与原状飞灰相比,Pb、Zn和Hg的浸出浓度分别降低了98.3%、99.5%和85.0%.HEDP对飞灰中重金属稳定效果排序为:Pb>Zn>Hg>Ni>Cu>Cd>CrHAs.重金属pH相关浸出测试(pH-dependent leaching tests)表明:经0.03mL/g HEDP稳定处理的飞灰,在0.3 mol/L HNO3和0.3 mol/L NaOH的浸取条件下,其重金属浸出浓度均低于国家危险废物鉴别标准,显示具有良好的长期稳定性. 相似文献
122.
Marie-Paule?CharnayEmail author Christian?Mougin Adrien?Farrugia Enrique?Barriuso 《Environmental Chemistry Letters》2004,2(1):27-30
We studied the 14C-tagged biochemical compartments such as proteins, lipids and polysaccharides from bacterial and fungal cultures supplied with 14C-pesticides and 14C-glucose. We showed that 14C incorporation depends both on the substrate structure and on the nature of the micro-organism. Both bacterial and fungal cells incorporated glucose 14C mainly into cell wall proteins. By contrast, glyphosate 14C was mainly incorporated into cytoplasm carbohydrates by fungi. On the other hand, 2,4-dichlorophenoxyacetic acid 14C was mainly found in the carbohydrate fractions of the bacteria walls. 相似文献
123.
Six ponds of age 3 were selected 45 km north from Suzhou in the Tailake region, and research conducted on nitrogen and phosphorus cycling in P. vannanmei(Penaeus vannanme) ponds and M. nipponense(Macrobrachium nipponense) hatchery ponds under normal management. Two treatments each had three replications. The results confirmed that feed was the major path of nitrogen and phosphorus input, each accounted for 61.24%(193.81 kg ha–1) and 81.08%(45.20 kg ha–1) of the total nitrogen and phosphorus input for P. vannanme ponds; the values for M. nipponense ponds were 43.93%(86.31 kg ha–1) and 57.67%(14.61 kg ha–1), respectively. Water pumped into ponds contributed on average 83.57 kg ha–1 nitrogen and 8.48 kg ha–1 phosphorus for P. vannanmei ponds, and 87.48 kg ha–1 nitrogen and 7.00 kg ha–1 phosphorus for M. nipponense hatchery ponds. Shrimp harvest recovered 102.81 kg ha–1 nitrogen (32.94% of the total nitrogen input) and 7.94 kg ha–1phosphorus (14.23% of the total phosphorus input) for P. vannanme ponds; and 43.94 kg ha–1 nitrogen and 4.46 kg ha–1phosphorus for M. nipponense hatchery ponds. The sum of nitrogen losses through volatilization, denitrification and sedimentation was 173.62 and 122.39 kg ha–1, 54.86% and 62.29% of the total nitrogen input for P. vannanme ponds and M. nipponense hatchery ponds, respectively. Sediment accumulated 41.46 and 14.63 kg ha–1 phosphorus, 74.37% and 64.85% of the total phosphorus input for P. vannanm ponds and M. nipponense hatchery ponds. Draining and seeping caused 40.06 kg ha–1 nitrogen (12.66% of total nitrogen input) and 6.36 kg ha–1 phosphorus (11.40% of total phosphorus input) loss to the surrounding water from P. vannanme ponds in 114 days; 30.14 kg ha–1nitrogen (15.34% of the total input) and 4.45 kg ha–1 phosphorus (17.57% of the total input) to channel water from M. nipponense hatchery ponds in 87 days, respectively. Countermeasures for sustainable pond management include improving feeds and feeding, sediment treatments, machine aerating, chemicals with no pollution, and integrated fish-shrimp cultivation. Management of water resources for pond and methods to reduce nitrogen and phosphorus loading into surrounding water from drainage are elucidated. 相似文献
124.
125.
尾矿利用是矿业环境治理和经济增长的新途径 总被引:2,自引:0,他引:2
本文阐述了尾矿的合理开发利用是21世纪矿业治理环境污染和经济增长的新途径,以及尾矿综合利用研究技术路线和研究内容。 相似文献
126.
用气相色谱.电子捕获检测器(GC-ECD)测定南京市郊蔬菜中的有机氯农药残留.结果表明,12种有机氯农药在所有的供试蔬菜中均有检出,DDT和HCH在各蔬菜中的含量较高,分别占有机氯农药总残留量的49.5%~75.0%和13.9%~28.2%.Wα-HCH/Wγ-HCH和WDDE/WDDT的比值在各蔬菜体内均小于或等于1,说明这些蔬菜生长的环境中可能有新的有机氯污染物的输入.各种蔬菜对有机氯农药总量的富集因子为0.41~0.78.富集能力最大的为胡萝卜,蒜苗和菠菜.HCH类农药在各种蔬菜体内的生物富集因子(0.70~1.10)要高于DDT类(0.28~0.80).胡萝卜对HCH和DDT等有机氯农药的富集能力较强,而莴苣、蒜苗和菠菜对六氯苯、狄氏剂,异狄氏剂和硫丹有较高的生物富集能力.虽然各种蔬菜体内有机氯农药的残留量低于国家最大残留限量,但其检出率仍为100%,仍然对农产品质量安全和人类健康造成潜在的威胁.关键词:有机氯农药;蔬菜;残留量;生物富集;人类健康 相似文献
127.
128.
The size and complexity of industrial plants, along with the characteristics of the products used, require a study, analysis and control of the existing risks in every industrial process.In this paper, a methodology for risk assessment in industrial plants, based on the combination of risks identification through the Hazard and Operability (HAZOP) analysis and the risks evaluation through linguistic variables and fuzzy numbers is applied to a case study consisting on a compound feed plant located in the town of Silla (Valencia, Spain).The results from this study show that the main risk in the compound feed production process is the formation of explosive atmospheres (ATEX). Therefore, the corrective measures will focus on reducing the concentration of dust in the atmosphere and eliminating the possible sources of ignition, such as electrostatic discharges or sparks during the different phases of the process (the grinding, the transport of the raw materials, etc.) 相似文献
129.
K.M.S. Sundaram 《Journal of environmental science and health. Part. B》2013,48(4-5):409-426
Abstract Fenitrothion and aminocarb formulations were aerially sprayed over mixed coniferous forests near Fredericton and Bathurst, New Brunswick, Canada. Insecticide concentrations inside the spray blocks were measured at intervals of time by trapping the airborne toxicants in a fritted‐glass bubbler containing dimethylformamide (DMF). The residues in DMF were analysed by gas chromatography. Concentrations of the insecticides in the air sampled decreased rapidly with time from peak levels of 1997 ng/m3 (fenitrothion) and 1201 ng/m3 (aminocarb). Concentrations of the two insecticides in the air samplers were dependent upon the nature of the chemicals, type of formulation used, spray timings and other environmental factors. 相似文献
130.
Ernest Merian 《毒物与环境化学》2013,95(3-4):323-327
CARCINOGENESIS AND MUTAGENESIS, by Myron A. Mehlman, Morris F. Cranmer and Raymond E. Shapiro, from the Journal of Environmental Pathology and Toxicology (Official Organ of the American College of Toxicology), 388 pages and 135 tables and figures, 1977, linen, format 261 × 178 mm, ISBN 0–930376–02–1, printed by Pathotox Publishers, Inc., Park Forest South, Illinois 60466, $23.00 WASTE TREATMENT AND UTILIZATION (Theory and Practice of Waste Management) by Murray Moo‐Young and Grahame J. Farquhar, University of Waterloo, Ontario, Canada; 574 pages, 211 illustrations and 513 literature references, linen, format 256 × 182mm, ISBN 0–08–023831–9, printed by Pergamon Press Ltd., Oxford OX3 OBW, England 1979, US$ 70.00 or £32.00. HANDBOOK ON THE TOXICOLOGY OF METALS by Lars Friberg (S‐10401 Stockholm), Gunnar F. Nordberg (DK‐5000 Odense) and Velimir B. Vouk (WHO, CH‐1211 Geneva), and sponsored by the U.S. Environmental Protection Agency 1979, 709 pages, linen, format 246 × 173 mm, ISBN 0–444–80075–1, printed by Elsevier/North‐Holland Biomedical Press, Amsterdam NL, $117.00/Dfl. 240.00 相似文献