Review of Pesticide Retention Processes Occurring in Buffer Strips Receiving Agricultural Runoff1

Arora, Kapil, Steven K. Mickelson, Matthew J. Helmers, and James L. Baker, 2010. Review of Pesticide Retention Processes Occurring in Buffer Strips Receiving Agricultural Runoff. Journal of the American Water Resources Association (JAWRA) 46(3):618-647. DOI: 10.1111/j.1752-1688.2010.00438.x Abstract: Review of the published results shows that the retention of the two pesticide carrier phases (runoff volume and sediment mass) influences pesticide mass transport through buffer strips. Data averaged across different studies showed that the buffer strips retained 45% of runoff volume (ranging between 0 and 100%) and 76% of sediment mass (ranging between 2 and 100%). Sorption (soil sorption coefficient, K_oc) is one key pesticide property affecting its transport with the two carrier phases through buffer strips. Data from different studies for pesticide mass retention for weakly (K_oc < 100), moderately (100 < K_oc < 1,000), and strongly sorbed pesticides (K_oc > 1,000) averaged (with ranges) 61 (0-100), 63 (0-100), and 76 (53-100) %, respectively. Because there are more data for runoff volume and sediment mass retention, the average retentions of both carrier phases were used to calculate that the buffer strips would retain 45% of weakly to moderately sorbed and 70% of strongly sorbed pesticides on an average basis. As pesticide mass retention presented is only an average across several studies with different experimental setups, the application of these results to actual field conditions should be carefully examined.     

Enhancing consultation practices on Air Quality Management in local authorities

Schedule 11 of the Environment Act 1995 underpins the requirement for consultation on air quality issues. The ongoing air quality review and assessment process represents one of the largest locally based science policy and communication initiatives ever undertaken in the UK. This paper outlines the practice of consultation and communication for Air Quality Management (AQM) and reviews the interaction between Environmental Health professionals, as the leading actor in the AQM process and other stakeholders involved in air quality consultation, including the public. Results are presented from a widespread questionnaire survey of English local authorities. Data indicate that the majority of air quality consultation has been carried out with statutory consultees (by sending the review and assessment reports) and the public (via websites and leaflets) in the form of information dissemination.     

Comparing Costs of Onsite Best Management Practices to Nutrient Credits for Stormwater Management: A Case Study in Virginia

Best management practices (BMPs) are widely used to mitigate impacts of increased impervious surfaces on stormwater runoff. However, there is limited detailed and up‐to‐date information available on the cost of designing, constructing, and maintaining BMPs over their lifetime. The objective of this study is to analyze BMPs recently constructed by the Virginia Department of Transportation (VDOT) to quantify their total cost per pound of phosphorus removed annually. A motivating factor for the study is recent changes to regulatory guidelines in Virginia which allow for full or partial substitution of purchased nutrient credits in lieu of constructing onsite BMPs to achieve compliance with stormwater quality regulations. Results of the analysis of nine BMPs found their cost ranged from $20,100 to $74,900, in 2014 dollars, per pound ($44,313‐$165,126 per kg) of phosphorus removed. Based on these results and assuming current credit prices procured by VDOT, purchasing nutrient credits is a cost‐effective option for the agency, especially when factoring in the cost of additional right of way for the BMP. Based on this finding, we expect compliance with stormwater quality regulations through credit purchases to become more widely used in Virginia. Moving forward, we suggest more direct tracking of BMP costs to support comparisons between BMP costs across a range of types and conditions to credit purchases for meeting stormwater regulations.     

Accretion of Nutrients and Sediment by a Constructed Stormwater Treatment Wetland in the Lake Tahoe Basin

This unique study evaluates the cumulative 16‐year lifetime performance of a wetland retention basin designed to treat stormwater runoff. Sediment cores were extracted prior to basin excavation and restoration to evaluate accretion rates and the origin of materials, retention characteristics of fine particulate matter, and overall pollutant removal efficiency. The sediment and organic layers together accreted 3.2 cm of depth per year, and 7.0 kg/m²/yr of inorganic material. Average annual accretion rates in g/m²/yr were as follows: C, 280; N, 17.7; P, 3.74; S, 3.80; Fe, 194; Mn, 2.68; Ca, 30.8; Mg, 30.7; K, 12.2; Na, 2.54; Zn, 0.858; Cu, 0.203; and B, 0.03. The accretion of C, N, P and sediment was comparable to nonwastewater treatment wetlands, overall, and relatively efficient for stormwater treatment wetlands. Comparison of particle size distribution between sediment cores and suspended solids in stormwater runoff indicated the wetland was effective at removing fine particles, with sediment cores containing 25% clay and 56% silt. A majority of the accretion of most metals and P could be attributed to efficient trapping of allochthonous material, while over half the accretion of C and N could be attributed to accumulation of autochthonous organic matter. Stormwater treatment was shown to be effective when physical properties of a retention basin are combined with the biological processes of a wetland, although sediment accretion can be relatively rapid.     

Detention Outlet Retrofit Improves the Functionality of Existing Detention Basins by Reducing Erosive Flows in Receiving Channels

By discharging excess stormwater at rates that more frequently exceed the critical flow for stream erosion, conventional detention basins often contribute to increased channel instability in urban and suburban systems that can be detrimental to aquatic habitat and water quality, as well as adjacent property and infrastructure. However, these ubiquitous assets, valued at approximately $600,000 per km² in a representative suburban watershed, are ideal candidates to aid in reversing such cycles of channel degradation because improving their functionality would not necessarily require property acquisition or heavy construction. The objective of this research was to develop a simple, cost‐effective device that could be installed in detention basin outlets to reduce the erosive power of the relatively frequent storm events (~ < two‐year recurrence) and provide a passive bypass to maintain flood control performance during infrequent storms (such as the 100‐year recurrence). Results from a pilot installation show that the Detain H₂O device reduced the cumulative sediment transport capacity of the preretrofit condition by greater than 40%, and contributed to reduced flashiness and prolonged baseflows in receiving streams. When scaling the strategy across a watershed, these results suggest that potential gains in water quality and stream channel stability could be achieved at costs that are orders of magnitude less than comparable benefits from newly constructed stormwater control measures.     

Field Trial Assessment of Biological,Chemical, and Physical Responses of Soil to Tillage Intensity,Fertilization, and Grazing

Soil microbial populations can fluctuate in response to environmental changes and, therefore, are often used as biological indicators of soil quality. Soil chemical and physical parameters can also be used as indicators because they can vary in response to different management strategies. A long-term field trial was conducted to study the effects of different tillage systems (NT: no tillage, DH: disc harrow, and MP: moldboard plough), P fertilization (diammonium phosphate), and cattle grazing (in terms of crop residue consumption) in maize (Zea mays L.), sunflower (Heliantus annuus L.), and soybean (Glycine max L.) on soil biological, chemical, and physical parameters. The field trial was conducted for four crop years (2000/2001, 2001/2002, 2002/2003, and 2003/2004). Soil populations of Actinomycetes, Trichoderma spp., and Gliocladium spp. were 49% higher under conservation tillage systems, in soil amended with diammonium phosphate (DAP) and not previously grazed. Management practices also influenced soil chemical parameters, especially organic matter content and total N, which were 10% and 55% higher under NT than under MP. Aggregate stability was 61% higher in NT than in MP, 15% higher in P-fertilized soil, and also 9% higher in not grazed strips, bulk density being 12% lower in NT systems compared with MP. DAP application and the absence of grazing also reduced bulk density (3%). Using conservation tillage systems, fertilizing crops with DAP, and avoiding grazing contribute to soil health preservation and enhanced crop production.     

施肥与秸秆还田对太湖稻-油复种系统春季杂草群落特征的影响

掌握不同管理模式下稻田杂草群落特征,可以为杂草综合防治及农田生物多样性的保持提供理论依据和技术途径。借助稻-油复种系统长期定位施肥试验（江苏吴江,始于1987年）,于2007年春季监测长期不同施肥和秸秆还田对农田杂草群落的影响。施肥与秸秆还田对春季稻田杂草群落结构特征存在显著作用。长期有机无机肥配合施用下（化肥+猪粪+秸秆）杂草生物多样性和生物量均下降;长期不施氮肥下杂草总密度显著增高,达1 810 ind./m2;长期不施肥时,田间野老鹳草成为优势种群,其相对密度达879%;全年秸秆还田（化肥+油菜秸秆+水稻秸秆）下,田间优势杂草种群为禾本科的看麦娘,其相对密度达697%;秋熟水稻秸秆还田下杂草生物量下降,而生物多样性显著提高。上述结果表明,通过合理施肥和秸秆还田措施,可以对稻油复种模式中春季杂草群落进行有效调控。     

A Multilevel Model of the Impact of Farm‐Level Best Management Practices on Phosphorus Runoff1

Abstract: Multilevel or hierarchical models have been applied for a number of years in the social sciences but only relatively recently in the environmental sciences. These models can be developed in either a frequentist or Bayesian context and have similarities to other methods such as empirical Bayes analysis and random coefficients regression. In essence, multilevel models take advantage of the hierarchical structure that exists in many multivariate datasets; for example, water quality measurements may be taken from individual lakes, lakes are located in various climatic zones, lakes may be natural or man‐made, and so on. The groups, or levels, may effectively yield different responses or behaviors (e.g., nutrient load response in lakes) that often make retaining group membership more effective when developing a predictive model than when working with either all of the data together or working separately with the individuals. Here, we develop a multilevel model of the impact of farm level best management practices (BMPs) on phosphorus runoff. The result of this research is a model with parameters which vary with key practice categories and thus may be used to evaluate the effectiveness of these practices on phosphorus runoff. For example, it was found that the effect of fertilizer application rate on farm‐scale phosphorus loss is a function of the application method, the hydrologic soil group, and the land use (crop type). Further, results indicate that the most effective method for controlling fertilizer loss is through soil injection. In summary, the resultant multilevel model can be used to estimate phosphorus loss from farms and hence serve as a useful tool for BMP selection.     

Pesticide residue removal in classic domestic processing of tomato and its effects on product quality

This study was undertaken to evaluate the effectiveness of several household practices (washing with water or acidic, alkaline, and oxidizing solutions, and peeling) in minimizing pesticide residue contamination of tomatoes, as well as the impact on the quality of the treated fruit. Tests were performed using two systemic fungicides (azoxystrobin and difenoconazole) and one contact fungicide (chlorothalonil). Solid-liquid extraction with low temperature partition (SLE/LTP) and liquid-liquid extraction with low temperature partition (LLE/LTP) were used to prepare the samples for pesticides determination by gas chromatography. Washing the tomatoes with water removed approximately 44% of chlorothalonil, 26% of difenoconazole, and 17% of azoxystrobin. Sodium bicarbonate (5%) and acetic acid (5%) solutions were more efficient, removing between 32 and 83% of the residues, while peeling removed from 68 to 88% of the pesticides. The washing solutions altered some fruit quality parameters, including acidity and chroma, and also caused weight loss. Acetic acid (0.15 and 5%) and hypochlorite (1%) solutions had the greatest effect on these parameters.     

Manure placement depth impacts on crop yields and N retained in soil

The objective of this study was to determine the impact of manure placement depth on crop yield and N retention in soil. Experimental treatments were deep manure injection (45 cm), shallow manure injection (15 cm), and conventional fertilizer-based management with at least three replications per site. Water infiltration, and changes in soil N and P amounts were measured for up to 30 months and crop yield monitored for three seasons following initial treatment. Deep and shallow manure injections differed in soil inorganic N distributions. For example, in the manure slot the spring following application, NO₃-N in the surface 60 cm was higher (p < .01) when injected 15 cm (21.4 μ g/g) into the soil than 45 cm (11.7 μ g/g), whereas NH₄-N had opposite results with shallow injection having less (p = 0.045) NH₄-N (102 μ g/g) than deep (133 μ g/g) injection. In the fall one year after the manure was applied, NO₃-N and NH₄-N were lower (p = 0.001) in the shallow injection than the deep injection. The net impact of manure placement on total N was that deep injection had 31, 59, and 44 more kg N ha^{? 1} than the shallow injection treatment 12, 18, and 30 months after application, respectively. Deep manure injection did not impact soybean (Glycine max L.) yield, however corn (Zea mays L.) yield increased if N was limiting. The higher corn yield in the deep injected treatment was attributed to increased N use efficiency. Higher inorganic N amounts in the deep injection treatment were attributed to reduced N losses through ammonia volatilization, leaching, or denitrification. Results suggest that deep manure placement in glacial till soil may be considered a technique to increase energy, N use efficiency, and maintain surface and ground water quality. However, this technique may not work in glacial outwash soils due to the inability to inject into a rocky subsurface.