In situ phytoremediation of arsenic- and metal-polluted pyrite waste with field crops: effects of soil management

Sunflower, alfalfa, fodder radish and Italian ryegrass were cultivated in severely As-Cd-Co-Cu-Pb-Zn-contaminated pyrite waste discharged in the past and capped with 0.15 m of unpolluted soil at Torviscosa (Italy). Plant growth and trace element uptake were compared under ploughing and subsoiling tillages (0.3 m depth), the former yielding higher contamination (∼30%) in top soil.Tillage choice was not critical for phytoextraction, but subsoiling enhanced above-ground productivity, whereas ploughing increased trace element concentrations in plants. Fodder radish and sunflower had the greatest aerial biomass, and fodder radish the best trace element uptake, perhaps due to its lower root sensitivity to pollution. Above-ground removals were generally poor (maximum of 33 mg m⁻² of various trace elements), with Zn (62%) and Cu (18%) as main harvested contaminants. The most significant finding was of fine roots proliferation in shallow layers that represented a huge sink for trace element phytostabilisation.It is concluded that phytoextraction is generally far from being an efficient management option in pyrite waste. Sustainable remediation requires significant improvements of the vegetation cover to stabilise the site mechanically and chemically, and provide precise quantification of root turnover.     

Sexual difference in mercury concentrations of lake trout (Salvelinus namaycush) from Lake Ontario

We determined total mercury (Hg) concentrations in 50 female lake trout (Salvelinus namaycush) and 69 male lake trout from Lake Ontario (Ontario, Canada and New York, United States). Results showed that, on average, males were 8% higher in Hg concentration than females in Lake Ontario. We also used bioenergetics modeling to determine whether a sexual difference in gross growth efficiency (GGE) could explain the observed sexual difference in Hg concentrations. According to the bioenergetics modeling results, male GGE was about 3% higher than female GGE, on average. Although the bioenergetics modeling could not explain the higher Hg concentrations exhibited by the males, a sexual difference in GGE remained a plausible explanation for the sexual difference in Hg concentrations of the lake trout. In an earlier study, male lake trout from Lake Ontario were found to be 22% higher in polychlorinated biphenyl (PCB) concentration than females from Lake Ontario. Thus, although males were higher in both Hg and PCB concentrations, the degree of the sexual difference in concentration varied between the two contaminants. Further research on sexual differences in Hg excretion rates and Hg direct uptake rates may be needed to resolve the disparity in results between the two contaminants.     

红斑顠体虫在活性污泥中的生长特性研究

以活性污泥为研究对象,研究了污泥中红斑顠体虫的生长情况以及红斑顠体虫对污泥减量的影响.结果表明:(1)红斑顠体虫的培养温度应该保持在20℃以上.在低污泥负荷(F/M) (＜0.4 mg/(mg·d))下,红斑顠体虫均能大量出现.(2)当温度大于20℃、红斑顠体虫处于生长期的活性污泥浓度(MLSS)＞3.0 g/L时,红...     

基于改进熵值法的城市“精明增长”综合测度——以长江三角洲16市为例

“精明增长”是资源环境约束下中国城市可持续增长的必然选择,该理论的中国化与适应性研究至关重要。将理论内涵与中国城市增长实际需求相结合,构建包含城市规模、城市福利、城市空间和城市消耗四增长维度的城市“精明增长”综合测评模型,并运用改进熵值算法,对1999~2008年长江三角洲地区从时序变动与截面比较进行实证研究。结果表明：长三角16市在考察期内增长逐年更为精明;上海、南京、杭州城市增长更为精明,其余城市熵值评分考察期内波动较大,且空间分布有两极分化的趋势;四增长维度影响综合评价的权重由高至低分别为福利维度、规模维度、消耗维度与空间维度,城市福利和规模增长是影响城市增长精明程度的主要方面,两维度中反映城市环境、产业结构、就业结构、城市化水平的指标贡献较大;城市消耗和空间维度权重较低,其中反映土地与生活能源消耗的指标作用明显,需要加大城市消耗的控制和内涵空间增长的拓展     

中国区域污染与经济增长实证:基于面板数据联立方程

考虑区域污染与区域经济增长的双向作用机制,构建联立方程模型,利用我国1998-2008年30个地区的面板数据,实证研究了6类区域污染物指标与区域经济增长的内在关系,对环境库兹涅茨曲线假说进行验证,探讨区域污染的主要影响因素。研究结果表明:①仅工业粉尘、工业SO2与GDP存在倒U型曲线关系,符合环境库兹涅茨曲线假说;工业废水、工业固废与GDP存在正的线性关系,工业废水中污染物化学需氧量、工业烟尘与GDP存在负的线性关系,不支持环境库兹涅茨曲线假说。指出并非经济发展到一定水平,区域污染问题就会得到全面解决。②人口规模对区域污染排放影响不显著;科技水平和能源利用率的提高能有效降低区域污染排放;政府环保管制未能有效控制区域污染排放;加大贸易开放程度对污染排放影响有正有负;产业结构不合理会加剧区域污染排放。③工业烟尘、工业SO2污染对区域经济增长有反作用。现阶段,我国区域污染对区域经济增长的反馈机制较弱,给我们敲醒了环保警钟。指出转变经济增长方式,走经济增长与环境保护协调发展的路子是我国今后的必然选择。     

高盐废水盐度对中度嗜盐菌生长动力学的影响

高盐废水盐度变化是影响微生物生长的重要因素之一。研究以中度嗜盐菌Halomonassp．STSY．3为例,测定其在不同盐度下生长对数期末OD600,并以葡萄糖为限制性基质,利用Monod方程,对菌株进行生长动力学拟合。结果表明,Halomonassp．STSY-3的最适生长盐度为7％（以NaCl计）,此盐度下其OD600 为2．56,而0%和34％盐度下OD600分别为0．47和0．06;Halomonassp．STSY-3的生长动力学模型与实验数据能较好地拟合,在最适生长盐度下动力学模型参数μmax 为2．257h-1,Ks为0．0082g／L。比较不同盐度下STSY-3生长动力学参数,得出中度嗜盐菌STSY-3的生长存在3个明显分区：最适盐度区（盐度2％～9％）、嗜盐过渡区（盐度9％～20％和0．68％～1．76％）及生长抑制区（盐度≤2％或≥20％）。其中嗜盐过渡区0．68％～1．76％由于范围较小,实际意义小,忽略不计。     

青萍生长特征及其对受污染河水的修复效果

以浮萍优势品种青萍（Lemna minor）为研究对象,开展受污染河水修复。分析了青萍在不同营养盐浓度条件下的生长特征,探讨了青萍对受污染河水的修复效果。在表面积为0.0095 m2的限制空间条件下,青萍在1、2和5 mg总氮（TN）/L营养液中的生长特征都能较好地服从Logistic生长模型,受制约的临界鲜重（FW）分别为1.20、1.36和1.36 g;青萍对受污染河水中氮磷污染物具有较好的去除效果,氨氮（NH＋4-N）的平均去除率、平均去除量和平均去除速率分别为56.87%、1.22 mg/d和0.0466 mg/（g FW·h）,正磷酸盐（PO3-4-P）的平均去除率、平均去除量和平均去除速率分别为66.95%、0.25 mg/d和0.0088 mg/（g FW·h）。根据相关性分析,进水NH＋4-N和PO3-4-P浓度与其对应去除量之间极显著相关;青萍FW与NH＋4-N去除速率之间显著负相关,但与PO3-4-P去除速率之间不存在显著相关性;NH＋4-N进水浓度与去除速率相关性不显著,但PO3-4-P进水浓度与去除速率显著正相关。     

Rapid determination of polar pesticides and plant growth regulators in fruits and vegetables by liquid chromatography/tandem mass spectrometry

ABSTRACT

A simple high-throughput liquid chromatography/tandem mass spectrometry (LC-MS/MS) multiresidue analysis method was developed for the simultaneous determination of polar pesticides, plant growth regulators and other polar compounds. These included amitrole, chlormequat, mepiquat, cyromazine, ETU, PTU, perchlorate, and daminozide using a mixed-mode column. A 10 g test portion was shaken with acidified methanol for 10 min. After centrifugation, the sample extract was injected and analyzed within 11 min by LC-MS-MS. This column eliminated the need for derivatization or the use of ion paring reagent. Two MS-MS transitions were monitored in the method for each target compound to achieve true positive identification. Eight isotopically-labeled internal standards corresponding to each analyte were used to correct for matrix suppression effect and/or instrument signal drift. The average recovery for all analytes at 20, 40, and 250 ng/g (n = 6) ranged from 73–136%, with a relative standard deviation of ≤ 20%.     

2株油烟降解优势菌株的筛选及性能研究

通过以油烟冷凝液为惟一碳源的选择培养基初筛,从长期受到油烟严重污染的土壤中筛选出具有降解油烟污染物能力的优势菌株XJ01、XJ03。研究了其最佳生长条件及降解性能,并对其进行了生理生化特征及分子生物学鉴定。研究表明,XJ01、XJ03最佳生长温度分别为35℃、30℃,最佳生长pH均为7,摇床转速均为120r／min,最佳降解时间分别为48h和36h;在最佳降解条件下,xJ01、XJ03总降解量分别达4．47113g／L和4．18ing／L,降解过程中,降解液pH值持续下降,生物量先增加后下降。经分子生物学鉴定,菌株XJ01、XJ03分别与铜绿假单胞菌群（Pseudomonasaeruginosagroup）和克雷伯氏菌属（Klebsiellasp．）同源性最高均达到100％。     

Interactions between energy consumption,international trade,and real income in Canada: An empirical investigation from a new version of the Solow growth model

This study investigates the empirical relationship between energy consumption, international trade, and real income in Canada which has an important role in global energy and trade. It employs bound tests to level relationships and conditional error correction models through ARDL specification to a new version of the Solow Growth model. Using annual data of the 1960–2010 period, results reveal a long-term relationship between energy consumption, international trade, and real income in Canada. It is also found that energy exporting activity is the determinant (driver) of energy consumption through the channel of real income and energy consumption is the determinant (driver) of exports through the channel of real income in the long term of the Canadian economy. Exports and energy use are the determinants (drivers) of real income in the long term of the Canadian economy; therefore, as conditional Granger causality tests suggest there is feedback relationship between energy consumption, international trade, and real income in the long term of the Canadian economy. The present study suggests that any energy conservation policies are likely to have negative influence on output and international trade in Canada.