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91.
将活性污泥培养及驯化后接种于生物滴滤塔中,挂膜启动后处理模拟氯苯废气(简称氯苯废气),考察了生物滴滤塔在挂膜启动阶段及稳定运行阶段的性能。实验结果表明:接种41 d后生物滴滤塔成功挂膜,此时氯苯去除率稳定在90%以上;生物滴滤塔稳定运行阶段,随着进气中氯苯质量浓度由303.82 mg/m3逐渐增至1 489.05 mg/m3,氯苯去除率从85.1%降至70.1%。处理氯苯废气适宜的工艺条件为:空塔停留时间超过45 s,喷淋液流量31.8 mL/min,氯苯负荷23.97~128.01 g/(m3·h)。生物滴滤塔对喷淋液的酸性环境有较好的适应性,喷淋液pH的变化对氯苯去除率无显著影响。 相似文献
92.
在火灾条件下,约束钢柱轴力由于升温而增加,会导致在较低的温度下发生屈曲;但屈曲后,钢柱的轴向温度膨胀得到释放,轴力下降,因此屈曲后钢柱仍能继续承栽。本文通过计算长度系数将转动约束钢柱转换为铰支钢柱,给出了一种轴向约束钢柱在火灾升温条件下的临界温度的简化计算方法——轴力放大系数设计方法。此法通过轴力放大系数将轴向约束钢柱转化为无约束钢柱,再按无约束钢柱计算得到钢柱的临界温度。用验证过的有限元模型对简化计算方法进行了验证,计算结果表明简化方法吻合较好。 相似文献
93.
为了研究高强度约束钢柱在火灾下的反应,根据高强度结构钢Q460在高温下的力学性能参数,建立了约束高强度钢柱受火分析模型,得到了高强度约束钢柱在火灾下的轴向位移、跨中挠度、最大应力以及临界温度。采用有限元分析对理论结果进行了验证,两者吻合很好。利用验证过的该文计算方法计算了2种荷栽比、长细比和约束刚度比条件下的高强钢柱的抗火性能;采用CECS200:2006的力学性能参数计算了约束普通钢柱的抗火性能。通过对高强钢和普通钢的抗火性能分析发现,轴向约束明显降低钢柱的临界温度,长细比、荷载比越大,临界温度越低;高强钢的抗火性能要优于普通钢。 相似文献
94.
A study has been made of the effect a reactive barrier made of pine (softwood) or oak (hardwood) wood intercalated in a sandy soil column has on the retention of linuron, alachlor and metalaxyl (pesticides with contrasting physicochemical characteristics). The leaching of pesticides has been carried out under a saturated flow regime and breakthrough curves (BTCs) have been obtained at flow rates of 1 mL min−1 (all pesticides) and 3 mL min−1 (linuron). The cumulative curves in the unmodified soil indicate a leaching of pesticides >80% of the total amount of compound added. After barrier intercalation, linuron leaching decreases significantly and a modification of the leaching kinetics of alachlor and metalaxyl has been observed. The theoretical R factors increased ∼2.6-3.3, 1.2-1.6-fold, and 1.4-1.7-fold and the concentration of the maximum peak decreased ∼6-12-fold, 2-4-fold and 1.2-2-fold for linuron, alachlor and metalaxyl, respectively. When considering the three pesticides, significant correlations have been found between the theoretical retardation factor (R) and the pore volume corresponding to the maximum peaks of the BTCs (r = 0.77; p < 0.05) or the total volume leached (r = −0.78; p < 0.05). The results reveal the efficacy of reactive wood barriers to decrease the leaching of pesticides from point sources of pollution depends on the type of wood, the hydrophobicity of the pesticide and the adopted water flow rate. Pine was more effective than oak in decreasing the leaching of hydrophobic pesticide linuron or in decreasing the maximum peak concentration of the less hydrophobic pesticides in soils. Efficacy of these wood barriers was limited for the least hydrophobic pesticide metalaxyl. 相似文献
95.
Column experiments were conducted to validate a screening model predicting the influence of pentachlorophenol (PCP) pole-treating oil on the vertical migration of its impurities, chlorinated dioxins and furans (PCDD/Fs). PCP pole-treating oil (15 mL d−1) and water (20 mL d−1) were added daily to the top of sand and organic soil columns during 35 d. Column soil samples were analyzed to determine concentrations of hydrocarbons and PCDD/Fs at several depths in the columns (0-30 cm) and their evolution in time (7, 14, 21 and 35 d).The model predicted a significant vertical migration of PCDD/Fs due to the presence of oil as a free phase and PCDD/Fs were found in the different column layers at concentrations consistent with model predictions (same order of magnitude). Measured PCDD/Fs concentrations are in total disagreement with literature data and with model prediction in the absence of oil free phase, which implies PCDD/F properties alone cannot be used to predict their fate in the current context: the influence of PCP pole-treating oil must be accounted for to properly explain their migration. 相似文献
96.
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98.
在常温条件下,采用生物滴滤塔处理模拟甲硫醚废气,考察了气体空床停留时间(EBRT)、容积负荷、喷淋密度及营养液pH对生物滴滤塔性能的影响。实验结果表明:当EBRT为90 s、进气甲硫醚质量浓度为150 mg/m~3、喷淋密度为0.65 m~3/(m~2·h),营养液pH为6.8时,甲硫醚去除率为90%;容积负荷高于15 g/(m~3·h)时,对生物滴滤塔的性能产生抑制作用;EBRT为90 s及60 s时,最佳喷淋密度分别为0.56~0.65 m~3/(m~2·h)及0.65~0.75 m~3/(m~2·h);降解甲硫醚的微生物对pH的变化较敏感,最适营养液pH为6~7。 相似文献
99.
Yuan-Na Xing Ying Guo Mei Xie Ru-Lang Shen 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1382-1387
A solid-phase microextration-based sampling method was employed to determine the concentrations of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and its metabolites, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethane (DDD), 1,1-dichloro-2,2-bis(p-chlorophenyl)ethene (DDE) and 1-chloro-2,2-bis(p-chlorophenyl)ethene (DDMU), in two estuarine bays, Daya Bay and Hailing Bay, of South China. Six DDT components including p,p′-DDT, o,p′-DDD, p,p′-DDD, o,p′-DDE, p,p′-DDE, and p,p′-DDMU were detected in Hailing Bay, while only p,p′-DDD was found in Daya Bay. p,p′-DDD was the most abundant DDT component in both bays, sharply different from the previous finding in the water column of the Palos Verdes Shelf, California, USA that p,p′-DDE was prevalent. In addition, the occurrence of p,p′-DDMU (with a range of 0.047-0.21 ng/L in Hailing Bay) has not been reported around the globe, and its presence in our study region appeared to stem from dehydrochlorination of p,p′-DDD, favored under aerobic conditions, but further investigations are clearly needed to confirm the mechanism for generation of DDMU in estuarine environments. 相似文献
100.
根据废弃印刷线路板中材料密度不同,采用水介质流化床对印刷线路板粉末中的金属进行回收,对0.25~0.177、0.177~0.104、0.104~0.074和-0.074 mm 4个粒级范围内的物料进行分选试验。试验结果表明,在上述4个粒级范围内,随介质流速的增大,金属回收率降低;金属回收率η与实际操作速度(ua)和颗粒终端沉降速度(ut)的比值φ(ua/ut)存在一定线性关系,分析模拟了η与φ之间的相关性方程,外推试验的结果证明了相关性方程的可靠性;在合适的操作条件下,各粒级范围内金属的回收率分别为95.02%、90.07%、87.5%和92.68%。 相似文献