Experimental investigation of ash deposits on convection heating surfaces of a circulating fluidized bed municipal solid waste incinerator

Incineration of municipal solid waste(MSW) is a waste treatment method which can be sustainable in terms of waste volume reduction, as well as a source of renewable energy.During MSW combustion, increased formation of deposits on convection heating exchanger surfaces can pose severe operational problems, such as fouling, slagging and corrosion.These problems can cause lower heat transfer efficiency from the hot flue gas to the working fluid inside the tubes. A study was performed where experiments were carried out to examine the ash deposition characteristics in a full-scale MSW circulating fluidized bed(CFB) incinerator, using a newly designed deposit probe that was fitted with six thermocouples and four removable half rings. The influence of probe exposure time and probe surface temperature(500, 560, and 700℃) on ash deposit formation rate was investigated. The results indicate that the deposition mass and collection efficiency achieve a minimum at the probe surface temperature of 560℃. Ash particles are deposited on both the windward and leeward sides of the probe by impacting and thermophoretic/condensation behavior. The major inorganic elements present in the ash deposits are Ca,Al and Si. Compared to ash deposits formed on the leeward side of the probe,windward-side ash deposits contain relatively higher Ca and S concentrations, but lower levels of Al and Si. Among all cases at different surface temperatures, the differences in elemental composition of the ash deposits from the leeward side are insignificant.However, as the surface temperature increases, the concentrations of Al, Si, K and Na in the windward-side ash deposits increase, but the Ca concentration is reduced. Finally,governing mechanisms are proposed on the basis of the experimental data, such as deposit morphology, elemental composition and thermodynamic calculations.     

Water softening by induced crystallization in fluidized bed

Fluidized bed and induced crystallization technology were combined to design a new type of induced crystallization fluidized bed reactor. The added particulate matter served as crystal nucleus to induce crystallization so that the insoluble material, which was in a saturated state, could precipitate on its surface. In this study, by filling the fluidized bed with quartz sand and by adjusting water p H, precipitation of calcium carbonate was induced on the surface of quartz sand, and the removal of water hardness was achieved.With a reactor influent flow of 60 L/hr, a fixed-bed height of 0.5 m, pH value of 9.5, quartz sand nuclear diameter of 0.2–0.4 mm, and a reflux ratio of 60%, the effluent concentration of calcium hardness was reduced to 60 mg/L and 86.6% removal efficiency was achieved. The resulting effluent reached the quality standard set for circulating cooling water. Majority of the material on the surface of quartz sand was calculated to be calcium carbonate based on energy spectrum analysis and moisture content was around 15.994%. With the low moisture content, dewatering treatment is no longer required and this results to cost savings on total water treatment process.     

山西省低热值燃煤电厂煤粉炉SO2和NOx超低排放工艺技术路线探讨

燃煤电厂污染物排放实施超低排放是中国燃煤电站绿色火电的大方向,煤电进入超低排放阶段,实施超低排放标准对电厂的污染物治理提出了更为苛刻的要求。为了在环境影响评价中落实超低排放可行措施,使SO2和NOx 达到超低排放标准,本文根据山西省低热值燃煤电厂实际环境影响评价过程中遇到超低排放工艺技术路线的问题,针对煤粉锅炉燃用高灰分、高硫分、热值低的煤质情况,介绍了大气污染物脱硫和脱硝的超净排放工艺方案,指出采用“石灰石-石膏湿法”脱硫双循环技术;锅炉低氮燃烧技术+SCR脱硝工艺技术(3+1层),可以满足山西省超低排放限值要求。     

旋滤组合移动式颗粒床除尘器优化设计建模

以旋滤组合移动式颗粒床除尘器的性能-结构关系为基础,建立移动式颗粒床除尘器优化设计的数学模型。该模型以除尘效率最大为优化目标,以结构参数与运行参数间的关系为约束条件,对特定的粉尘和含尘气体以及一定的运行参数而言,优化设计变量为移动式颗粒床除尘器的结构参数(主要有进气口尺寸,旋风体直径,过滤床直径、厚度及有效过滤高度),从而确定移动式颗粒床除尘器的最佳结构尺寸。通过设计实例检验,证明了该模型具有较好的实际应用价值。     

疏浚底泥生态毒理性风险分析方法的研究进展

疏浚底泥土地利用应该尽可能避免对施用土壤、周围地表水及地下水的污染,通过生物聚积试验和急性、亚急性毒性试验考查底泥对水及土壤中生物、植物发芽生长的影响,通过渗滤试验评价其对地下水层的污染。疏浚底泥土地利用前,其生态毒理性风险分析的方法包括风险简化评价和风险详细评价。通常简化评价方法用于估计底泥土地利用对生态系统影响程度;详细评价法进一步通过生物毒性试验和柱状渗滤试验来确定其生态毒理性影响,界定其风险特性。     

阳极溶出伏安法连续测定底泥中的总镉和总铅

样品经盐酸-硝酸-氢氟酸-高氯酸消解后，用1＋1盐酸溶解残渣，以高氯酸做支持电解质，采用阳极溶出伏安法的标准加入法，测定样品中的总镉和总铅，取得满意结果。     

DDNP废水处理新方法研究

DDNP是一种重要的起爆药，其生产废水成份复杂，用传统工艺处理难度较大且不经济。鉴于此，经研究总结得出DDNP废水处理新工艺：先用锅炉废烟气蒸发浓缩，再焚烧的方法，即处理了废水，又降低了锅炉烟尘。是一种低成本、低能耗以废治废的经济实用方法。     

循环流化床锅炉局部磨损问题及控制

对循环流化床锅炉(以下简称CFBB)局部磨损的机理进行了分析，总结了几种控制防磨措施，为CFBB正常维护提出了几点建议。     

卧式锅炉烟管拼接问题探讨

通过对锅炉烟管破坏强度的理论分析，提出了卧式锅炉烟管在制造、维修过程中不宜采用拼接形式的建议。     

锅炉除尘水微孔管式过滤技术

通过对锅炉除尘水处理方法的选择，介绍了微孔过滤技术，总结了微孔过滤技术在实际中的运用。