The paper briefly describes an electro-optical system for counting of dust particles, which is based on the scattering phenomena.Utilizing the scattering of light by various size particles present in the environment, various particle counting techniques have been developed in order to measure the scattered intensity of light. Light scatters in all directions but much more in the so-called near forward direction 17∘ off axis, at 163∘ from the light source in the visible range.On the basis of two techniques, the right angle and forward angle scattering, opto-mechanical systems have been developed which measure scattered intensity and particulate matter. The forward scattering Nephelometer is more sensitive and therefore is more suitable for pollution monitoring than the right angle scattering Nephelometer. Whereas the right angle scattering Nephelometer has the utility in extremely low concentration in ppb level owing to the excellent light trap efficiency in comparison to forward scattering Nephelometer. In this paper measurement techniques and measurement results associated with design and development of a real time particle analyser are also discussed. 相似文献
Typical tasks of a river monitoring network design include the selection of the water quality parameters, selection of sampling and measurement methods for these parameters, identification of the locations of sampling stations and determination of the sampling frequencies. These primary design considerations may require a variety of objectives, constraints and solutions. In this study we focus on the optimal river water quality monitoring network design aspect of the overall monitoring program and propose a novel methodology for the analysis of this problem. In the proposed analysis, the locations of sampling sites are determined such that the contaminant detection time is minimized for the river network while achieving maximum reliability for the monitoring system performance. Altamaha river system in the State of Georgia, USA is chosen as an example to demonstrate the proposed methodology. The results show that the proposed model can be effectively used for the optimal design of monitoring networks in river systems. 相似文献
An approach is developed to simulate leaching of a dissolved chemical constituent in the vadose zone of an aquifer. Specifically,
nitrate loading at the water table for different water table depths, for a range of aquifer permeability values, and for different
cases of heterogeneity of the aquifer, are considered. Models from the literature are first used to derive soil–water characteristic
curves (water retention and hydraulic conductivity) from a grain size distribution curve for unsaturated conditions. Given
infiltration from the surface, the initial conditions for the chemical concentration, and the water content profile, leaching
of the chemical in the vadose zone is simulated as a function of both time and depth. The methodology is illustrated for a
permeable aquifer. Simulations are undertaken using a finite element code for saturated and unsaturated flow. Different scenarios
are simulated depending on the heterogeneity of the aquifer and the depth of the water table. Modeling results show that in
the example case studied, nitrate concentration loading at the water table does not depend strongly on the position of the
water table, but rather on the material properties of the aquifer. The contribution of this endeavor resides in the methodology
which allows a prediction of nitrate leaching using only the grain size property of the aquifer. It allows practitioners to
obtain a first assessment of leaching with limited data. 相似文献
13C CP-MAS NMR spectroscopy is a technique that has proved to be useful in studying soil organic matter (SOM). Nevertheless, NMR spectra exhibit a weak signal and have very low resolution due to: the low natural abundance of 13C (1.1 % of C) in SOM, the generally low SOM content of soils, and the presence of paramagnetic impurities. This paper studies the effects of soil chemical pre-treatments on 13CP-MAS NMR spectra quality and spectra representativity i.e. soil C mass balance.
After chemical pre-treatment to increase total organic carbon (TOC) content and C/Fe ratio, eight soils characterized by different levels of organic carbon content and C/Fe ratios were studied using 13CP-MAS NMR. Moreover, where chemical treatments were not applicable due to high carbon losses, the number of 13CP-MAS NMR scans was increased in order to obtain satisfactory spectra.
Results show that chemical pre-treatment of soils with C/Fe > 1 caused high C losses. Bulk soils were therefore studied by increasing the number of 13CP-MAS NMR scans. Acceptable spectra were obtained from 8K scans (1K = 1024 transient). On the other hand, even when a large number of scan (32K) are used, soil with C/Fe < 1 cannot be studied. As these soils are characterized by low C losses after HCl treatments (range of 2.9–25.4%), a pre-treatment of at least 1.39 mol l−1 HCl removes excess Fe and at the same time increases C/Fe ratio resulting in 32K scans providing good spectra. 相似文献