常压非平衡等离子体条件下CO2的转化

研究常温常压下,脉冲电晕等离子体对温室气体ＣＯ２的活经与轮,分别考究了纯ＣＯ２气体,ＣＯ２－Ｈ２,ＣＯ２－ＣＨ４体系中ＣＯ２的轮。纯ＣＯ２气体放电,ＣＯ２主要分解为ＣＯ和Ｏ２,ＣＯ的选择性在７０％以上,随着脉冲电压峰值的增加,ＣＯ２转化率,ＣＯ２产率有所提高。     

Atmospheric Change and Biodiversity

Strategies to conserve biodiversity need to include the monitoring, modelling, adaptation and regulation of the composition of the atmosphere. Atmospheric issues include climate variability and extremes; climate change; stratospheric ozone depletion; acid deposition; photochemical pollution; suspended particulate matter; and hazardous air pollutants. Coarse filter and fine filter approaches have been used to understand the complexity of the interactions between the atmosphere and biodiversity. In the first approach, climate-based models, using GIS technology, helped create future biodiversity scenarios under a 2 × CO₂ atmosphere. In the second approach, the SI/MAB forest biodiversity monitoring protocols helped calibrate the climate-forest biodiversity baseline and, as global diagnostics, helped identify where the biodiversity was in equilibrium with the present climate. Forest climate monitoring, an enhancing protocol, was used in a co-location approach to define the thermal buffering capacity of forest ecosystems and their ability to reduce and ameliorate global climate variability, extremes and change.     

The relevance of James Lovelock’s research and philosophy to environmental science and academia

James E. Lovelock, famed for his Gaia hypothesis, which views the Earth as a living integrated and interconnected self-regulating system whose equilibrium comes about from complex energy-based interactions and feedback loops, ultimately sustaining life, passed away at the end of July, 2022 at the age of 103. Not only are the adaptive mechanisms of Gaia central to the conversation of environmental homeostasis, they lie at the heart of climate change and global warming. Lovelock is also remembered as the co-inventor of the electron capture detector that eventually allowed for the sensitive detection of chlorofluorocarbons and pesticides. Finally, Lovelock’s free-spirited nature and research independence allow academia to rethink current research’s modus operandi.     

中国安全生产政策变迁及其内在逻辑——基于间断均衡模型的实证分析*

为全面发挥安全生产政策对推进安全生产治理体系与治理能力现代化的保障作用,基于间断均衡模型审视改革开放以来我国安全生产政策变迁过程,并提出将其划分为3个均衡期和2个间断期。研究结果表明:在政策目标的转换下,我国安全生产政策变迁先后历经“生产安全”、“安全发展”与“总体安全”3个阶段的深刻调整。决策主体注意力分配、焦点事件持续冲击与地方政府创新供给利用改变政策场域而影响安全生产政策变迁,分别呈现“原动力”、“驱动力”与“拉动力”的作用机制,具有典型的中国情境。研究结果可为廓清中国安全生产政策变迁机制提供理论思考。     

Thermodynamic method for the prediction of solid CO2 formation from multicomponent mixtures

The increase in GHG concentration has a direct effect on global climate conditions. Among the possible technologies to mitigate GHG emissions, CCS is being accepted to gain emission reduction. Such technology also involves cryogenic CO₂ capture processes based on CO₂ freeze-out or where the formation of solid CO₂ must be avoided. Captured CO₂ is usually transported in pipelines for the reinjection.The risk associated to the release of CO₂ is due to the changing temperatures and pressures the system may experience, which can lead to the deposition of solid CO₂ where it must be avoided. Prolonged exposure to dry ice can cause severe skin damage and its resublimation could pose a danger of hypercapnia. It is, thus, necessary to build up a tool able to predict the conditions in which CO₂ can freeze-out.A thermodynamic methodology based on cubic EoSs has been developed which is able to predict solid–liquid–vapor equilibrium of CO₂ mixtures with n-alkanes or H₂S which are usually found in equipment for acidic gas, mainly natural gas, treatment.The focus is a detailed analysis of the method performances when more than two components are present since, for such a case, literature does not provide significant modeling results.     

土壤污染对地下水影响的2种评估方法的应用与比较

以某含1,2-二氯乙烷等10种有机物污染土壤回填项目为例,介绍了2种方法(三相平衡耦合地下水稀释模型和Sesoil耦合地下水稀释模型)在评估土壤污染对地下水影响中的具体应用并进行了比较. 结果表明,采用US EPA(美国国家环境保护局)推荐的三相平衡耦合地下水稀释模型预测的地下水中目标污染物浓度高于新泽西州推荐的Sesoil耦合地下水稀释模型的3~10倍,污染物亨利常数及碳水分配系数越高,二者的差异越明显,达到1个数量级. 对于多环芳烃类的强疏水性有机污染物,2种方法的评估结论无本质差异. 出于保守性及调查成本的考虑,在制订国家或区域范围基于保护地下水的土壤通用筛选值时,建议采用所需参数相对较少的三相平衡耦合地下水稀释模型的方法,以节约调查成本. 对于具体评估项目,当污染物浓度超过通用筛选值时,建议进一步对场地水文地质条件进行调查,采用Sesoil耦合地下水稀释模型重新评估并计算该特定场地的筛选值,以节约修复成本.      

Thermodynamic investigation of the effect of oxygen and hydrogen chloride potential upon generation and decomposition behavior of dioxins

The thermodynamic equilibrium of the C‐H‐O‐Cl system has been calculated to elucidate the generation and decomposition behavior of dioxins, and is discussed from the viewpoint of the oxygen and hydrogen chloride potential. The dioxins behavior is greatly dependent on the oxygen potential, i.e. higher temperature and oxygen potential lead to the complete decomposition of dioxins, while low hydrogen chloride potential under insufficient oxygen condition leads to an increase of multi‐chlorine displacement of dioxins.     

水体沉积物质量基准研究现状

沉积物质量基准是对水质基准的补充,对水质管理具有重要意义。目前国际上沉积物质量基准计算方法有十几种。对各种方法的理论基础、数据需求、适用范围等方面进行了概述之后,综合分析了各种方法的理论基础。研究结果认为,应将建立沉积物质量基准的方法分为以生物效应数据为基础的生物效应数据库法和以相平衡分配原理为依据的相平衡分配法。而根据统计方法不同,生物效应数据库法又分为单值基准、双值基准和三轴图法。同时还对美国、加拿大、荷兰、英国、澳大利亚和新西兰的沉积物质量基准研究发展和应用概况进行了分析。结合我国实际情况认为,依赖于大量生物效应数据的生物效应数据库法,目前在我国的适用范围有限,只能用于推导少数几种污染物的基准值。相平衡分配法具有可靠的理论基础而且不需要大量的生物效应数据,具有很大的发展潜力。因此,对于目前沉积物质量基准研究处于初级阶段的我国,更适合使用相平衡分配法计算污染物沉积物质量基准。     

重金属污染沉积物质量评价研究—以太湖为例

以太湖的表层沉积物为研究对象,运用相平衡分配法(EqP)探讨了沉积物中4种重金属(Cu, Pb, Zn, Cd)的沉积物质量基准(CSQC)值;根据美国国家环境保护局(US EPA)基于水生生物对重金属的最终慢性毒理水平的淡水水质基准,制定了太湖4种重金属(Cu, Pb, Zn,和Cd)的沉积物质量基准值分别为145.2,308.72,293.01,0.46mg/kg.以此CSQC为参比值,参考潜在生态危害指数法对各元素赋予不同的权重值,运用综合污染指数法对太湖沉积物重金属的环境质量进行评价,结果显示,2010年8~9月太湖沉积物质量基本为良.这一结果与沉积物重金属总量分析结果一致.     

软弱基底排土场变形破坏治理措施研究

针对软弱基底露天矿排土场普遍存在的变形破坏问题,结合胜利东二露天矿南排土场南帮边坡的工程实际,基于极限平衡理论,给出了通过探槽及滑坡变形反分析综合确定基底赋存条件及抗剪强度指标的方法;提出了对软弱基底排土场的变形治理措施;根据已有监测数据,对南帮边坡治理效果进行了评价。结果表明:在实施削坡减载措施后,各地表监测点的累计位移趋于平缓,边坡治理措施效果明显,解决了胜利东二露天矿迫切的安全问题,为同样具有软弱基底的其他露天矿排土场变形及破坏治理提供了指导。