乙醇汽油与普通汽油非常规污染物排放特性对比研究

在一台满足国Ⅴ排放标准的双喷射(气口喷射+缸内直喷)汽油机上开展了燃用E10乙醇汽油(乙醇体积比为10%)对发动机非常规排放特性影响的试验研究.使用傅里叶变换红外分析仪(FTIR)测量了饱和烃、不饱和烃、芳香烃及醇、醛等非常规污染物排放量,对比分析了双喷射模式时各工况下E0和E10两种燃料的非常规排放水平.结果表明,双喷射模式下,加入乙醇有效降低了乙烯、1,3-丁二烯、苯和甲苯的排放量,但会导致乙醛排放升高.双喷射模式下,随着负荷增加,两种燃料下的1,3-丁二烯和甲苯排放呈现先升高后降低的趋势,乙烯、甲醛和苯排放则先降低后升高.乙醇能抑制1,3-丁二烯、乙烯生成,抑制效果为PFI模式优于双喷射模式,GDI模式抑制量最低.PFI和GDI模式下E10的甲醛排放均显著升高,但双喷射模式有效抑制了甲醛排放的增加.     

Investigation to meet China II emission legislation for marine diesel engine with diesel methanol compound combustion technology

In order to reduce the pollutant emission and alleviate the pressure of petroleum resources shortage and greenhouse gas emission at the same time, the use of clean and renewable alternative fuel for marine engines is a promising option. In this study, a marine diesel engine, which was modified to run in diesel methanol compound combustion (DMCC) mode, was investigated. After the diesel injection parameters were calibrated, and combined with a sample after-treatment device DOC (diesel oxidation catalyst), the engine could meet the requirements of China II legislation. The overall MSP (methanol substitute percent) reached 54.1%. The value of each pollutant emission was much lower than that in China II emission legislation, and there was almost no methanol and formaldehyde emissions. When methanol was injected into the inlet manifold, the intake air temperature decreased a lot, as well as the exhaust gas temperature, which were beneficial to increase engine thermal efficiency and improve engine room environment. Compared with the engine running in pure diesel mode, when the engine ran in diesel/methanol dual fuel mode, the combustion phase was advanced, and the combustion duration became shorter. Therefore, the engine thermal efficiency increased, and fuel consumption decreased significantly.     

Potential of secondary aerosol formation from Chinese gasoline engine exhaust

Light-duty gasoline vehicles have drawn public attention in China due to their significant primary emissions of particulate matter and volatile organic compounds(VOCs). However,little information on secondary aerosol formation from exhaust for Chinese vehicles and fuel conditions is available. In this study, chamber experiments were conducted to quantify the potential of secondary aerosol formation from the exhaust of a port fuel injection gasoline engine. The engine and fuel used are common in the Chinese market, and the fuel satisfies the China V gasoline fuel standard. Substantial secondary aerosol formation was observed during a 4–5 hr simulation, which was estimated to represent more than 10 days of equivalent atmospheric photo-oxidation in Beijing. As a consequence, the extreme case secondary organic aerosol(SOA) production was 426 ± 85 mg/kg-fuel, with high levels of precursors and OH exposure. The low hygroscopicity of the aerosols formed inside the chamber suggests that SOA was the dominant chemical composition. Fourteen percent of SOA measured in the chamber experiments could be explained through the oxidation of speciated single-ring aromatics. Unspeciated precursors, such as intermediate-volatility organic compounds and semi-volatile organic compounds, might be significant for SOA formation from gasoline VOCs. We concluded that reductions of emissions of aerosol precursor gases from vehicles are essential to mediate pollution in China.     

柴油机尾气中PAH_s的分析

本文概述了柴油机尾气中ＰＡＨｓ的分析方法，着重论述了采样及预处理方法，特别对预处理方法进行了深入的探讨。另外，通过对柴油机两种不同工况下产生的尾气进行分析后发现，柴油机转速越高，其排放尾气中ＰＡＨｓ的含量就越低。     

Multipoint source method in air pollution modelling of cold start emission

The paper presents a new method of air pollution modelling on a micro scale. For estimation of concentration of car exhaust pollutants, each car is treated as an instantaneous moving emission source. This approach enables us to model time and spatial changes of emission, especially during cold and cool start of an engine. These stages of engine work are a source of significant pollution concentration in urban areas. In this work, two models are proposed: one for the estimation of emission after cold start of the engine and another for the prediction of pollutant concentration. The first model (defined for individual exhaust gas pollutants) enables us to calculate the emission as a function of time after the cold or cool start, ambient temperature and average speed of motion. This model uses the HBEFA database. The second mathematical model is developed in order to calculate the pollutant dispersion and concentrations. The finite volume method is applied to discretise the set of partial differential equations describing wind flow and pollutant dispersion in the domain considered. Models presented in this paper can be called short-term models on a small spatial scale. The results of numerical simulation of pollutant emission and dispersion are also presented.     

废旧塑料回收利用技术

从我国废塑料回收利用的现状出发 ,分析了今后我国废塑料回收利用技术的发展趋势和应采取的措施 ,指出了废塑料回收利用的重要性。     

A comparison of hydrocarbons emission from engine running 85# gasoline and M-100 methanol fuel

Increasing global interest in methanoi fuel has led us to investigate the exhaust emissionsof its engine. Analysis of its inorganic and organic emissions. such as CO. NO_x and hydrocarbons(total HC) have been widely reported. This paper presents an analysis of more than 20 kinds ofhydrocarbons in the emissions obtained from a spark-ignition Shanghai car running 85^# gasoline anda comparison with emission from a Santana test car running M-100 methanol fuel. A set ofenrichment method has also been described. Test results show that at the current stage of methanolengine development the concentration of individual hydrocarbon including some poisonous substancesis lower than those of normal gasoline engine.     

含铅,无铅汽油车尾气排出物遗传毒性比较

利用台架试验模拟汽车行驶工况，收集了发动机使用无铅汽油，含铅汽油燃烧后的尾气颗粒物，对其中吸附的有机物进行了提取，并以Ａｍｅｓ试验，中国仓鼠肺细胞体外微核实验等方法，从基因，染色体水平检测了两种颗粒提取的遗传毒性。     

船舶柴油机NOx后处理技术的进展

根据国内外的降低NOx排放方面最新的成果和科研动态，主要介绍了当前正在研究或者已经应用于实际的有效降低柴油机NOx排放的技术措施，并分析了各种技术方法的特点和在实际应用过程中面临的问题。     

电喷汽油机进气系统沉积物模拟评价方法

设计和制作了一种电喷发动机进气系统沉积物模拟评价装置，提出了评价进气系统沉积物生成的方法－外观等级法，并用实验验证了该方法的可靠性。通过实验验证：电喷式汽油机进气系统沉积物模拟评价方法具有较好的分辨性、重复性，可以作为以后油品和添加剂评价的方法。