农药内分泌干扰效应研究进展

农药作为农业生产过程中的一类重要生产资料,主要用作杀虫剂、杀菌剂和除草剂等。由于农药的大量使用,目前在各类农产品及各种环境介质中都能被检测到,对饮食健康和环境安全带来潜在危害。研究发现,许多农药为内分泌干扰物,其能够干扰人类和其他生物体的内分泌系统正常功能。本文在总结国内外相关研究的基础上,对农药内分泌干扰效应的作用机理及筛选模型进行总结,对有机氯、有机磷和拟除虫菊酯等各类农药的内分泌干扰效应研究进展进行综述,并提出深入探究农药致毒作用机制和低剂量下多种农药联合毒性是本领域的重要研究方向。     

碳纳米材料的水环境行为及对水生生物毒理学研究进展

随着纳米科技的迅猛发展,人工碳纳米材料的生产和使用逐年递增,越来越多的碳纳米材料进入水环境中,对水生生物产生毒性效应。本文在介绍了碳纳米球、石墨烯、碳纳米管3种碳纳米材料的基础上,分析了碳纳米材料的水环境行为,重点综述了碳纳米材料对水生生物毒性效应研究现状,以及可能的致毒机制,并指出今后碳纳米材料对水生生物毒理学亟待加强的研究领域。     

全氟辛酸(PFOA)对菲律宾蛤仔体内酶活性的影响

采用半静态毒性实验方法,将菲律宾蛤仔(Ruditapes philippinarum)分别暴露于0.2、2、20μg·L-1的全氟辛酸(perfluorooctanoic acid,PFOA)中,在处理后第1、3、6、10、15、21天分别取样,测定整体组织中超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、过氧化物酶(POD)、谷胱甘肽-S-转移酶(GST)、7-乙氧基异吩噁唑酮脱乙基酶(EROD)活性和过氧化脂质(LPO)含量。酶活性分析结果显示:PFOA对菲律宾蛤仔组织SOD、CAT和POD活性均呈现先促进后抑制的作用;低浓度组SOD活性在暴露第1天达到最高,显著高于对照组(P<0.01);中高浓度组SOD活性在暴露第6天达到最低;暴露1~15 d,低浓度组CAT活性均显著高于对照组(P<0.05);高浓度组CAT活性在暴露第6天得到显著诱导,其余时间基本处于抑制状态;中浓度组POD活性在暴露第3天即达到最高,高浓度组POD活性基本一直处于抑制状态;随着PFOA暴露时间的延长,菲律宾蛤仔组织LPO含量呈现了先降低后升高的趋势;各浓度组中EROD的活力都显著被诱导(P<0.01),与处理浓度呈正相关;中高浓度组的GST活性在胁迫期间变化比较显著,呈现诱导-抑制的变化规律。研究表明,PFOA暴露能够引起菲律宾蛤仔组织抗氧化酶和生物转化酶的变化,可以与其他敏感性指标一起作为指示早期海洋PFOA污染的生物标志物。     

氯代阻燃剂得克隆对纤细裸藻的生态毒性效应

得克隆(Dechlorane Plus,DP)作为全球广泛使用的氯代阻燃剂,具有POPs特性和环境毒性,但其生物毒性数据非常有限。本文选择水生初级生产者纤细裸藻(Euglena gracilis)作为研究对象,通过检测藻细胞生长状况、光合色素水平、抗氧化酶活性、谷胱甘肽(GSH)和丙二醛(MDA)含量变化,研究了不同浓度DP对其生态毒性效应的影响。结果显示,低浓度DP对纤细裸藻生长具有一定促进作用,但差异不显著;DP浓度较低时(0.1和0.5 mg·L-1DP)类胡萝卜素含量受到轻微抑制;较高浓度DP暴露导致超氧化物歧化酶(SOD)、过氧化物酶(POD)和谷胱甘肽(GSH)水平显著增加,同时高浓度DP(8 mg·L-1)下MDA含量显著上升,提示膜结构受到损伤;表明较高实验浓度范围内,DP对纤细裸藻的生长及抗氧化系统均产生一定影响,结果将为DP的环境生态风险评价提供科学依据。     

Back-pedaling or continuing quietly? Assessing the impact of ICLEI membership termination on cities’ sustainability actions

Over the past decade, cities have emerged as leaders in sustainability and climate protection in the United States. ICLEI, a voluntary network of local governments, played an important role driving this trend. After years of steady growth, ICLEI became a target of political opposition and its membership dropped significantly from 2010 to 2012. This begs the question of whether cities’ termination of their ICLEI affiliation diminishes their implementation of sustainability actions. Two surveys administered in 2010 and 2014 provide data on cities’ implementation of an array of sustainability actions. Using a difference-in-differences (DiD) method, the impact of ICLEI termination on local governments’ administrative and policy commitments to sustainability is assessed. The results suggest that ending ICLEI membership does not significantly impact local sustainability actions, and also indicate that the durability of policy actions may be only loosely linked to the policies that justify them.     

Media Use and Public Perceptions of Global Warming in India

Media plays a vital role in informing the public about environmental threats. Although climate change is a global problem, developing countries such as India are often more vulnerable to the impacts due to poverty, illiteracy, and low public awareness. Using data from a nationally representative survey in India, this paper explores the relationships between media use, issue attention, and trust in informational sources on one hand and science-based climate change beliefs, risk perceptions, and policy support on the other. Results suggest that the Indian media, through consistent and accurate coverage of global warming using trusted sources, can play a positive role in increasing public engagement among a largely unaware population. Implications for climate change communication in India are discussed.     

Does Engagement in Advocacy Hurt the Credibility of Scientists? Results from a Randomized National Survey Experiment

It is often assumed that issue advocacy will compromise the credibility of scientists. We conducted a randomized controlled experiment to test public reactions to six different advocacy statements made by a scientist—ranging from a purely informational statement to an endorsement of specific policies. We found that perceived credibility of the communicating scientist was uniformly high in five of the six message conditions, suffering only when he advocated for a specific policy—building more nuclear power plants (although credibility did not suffer when advocating for a different specific policy—carbon dioxide limits at power plants). We also found no significant differences in trust in the broader climate science community between the six message conditions. Our results suggest that climate scientists who wish to engage in certain forms of advocacy have considerable latitude to do so without risking harm to their credibility, or the credibility of the scientific community.     

Sorption and desorption of glyphosate,MCPA and tetracycline and their mixtures in soil as influenced by phosphate

Phosphate fertilizers and herbicides such as glyphosate and MCPA are commonly applied to agricultural land, and antibiotics such as tetracycline have been detected in soils following the application of livestock manures and biosolids to agricultural land. Utilizing a range of batch equilibrium experiments, this research examined the competitive sorption interactions of these chemicals in soil. Soil samples (0-15 cm) collected from long-term experimental plots contained Olsen P concentrations in the typical (13 to 20 mg kg^?1) and elevated (81 to 99 mg kg^?1) range of build-up phosphate in agricultural soils. The elevated Olsen P concentrations in field soils significantly reduced glyphosate sorption up to 50%, but had no significant impact on MCPA and tetracycline sorption. Fresh phosphate additions in the laboratory, introduced to soil prior to, or at the same time with the other chemical applications, had a greater impact on reducing glyphosate sorption (up to 45%) than on reducing tetracycline (up to 13%) and MCPA (up to 8%) sorption. The impact of fresh phosphate additions on the desorption of these three chemicals was also statistically significant, but numerically very small namely < 1% for glyphosate and tetracycline and 3% for MCPA. The presence of MCPA significantly reduced sorption and increased desorption of glyphosate, but only when MCPA was present at concentrations much greater than environmentally relevant and there was no phosphate added to the MCPA solution. Tetracycline addition had no significant effect on glyphosate sorption and desorption in soil. For the four chemicals studied, we conclude that when mixtures of phosphate, herbicides and antibiotics are present in soil, the greatest influence of their competitive interactions is phosphate decreasing glyphosate sorption and the presence of phosphate in solution lessens the potential impact of MCPA on glyphosate sorption. The presence of chemical mixtures in soil solution has an overall greater impact on the sorption than desorption of individual organic chemicals in soil.     

城市绿化屋顶的微气候调节与径流削减效应研究

快速城市化与气候变化双重作用下,热岛效应与城市内涝成为最为突出的城市环境问题。绿化屋顶因能有效利用闲置屋面添緑、帮助城市缓解热岛和暴雨径流而受到关注。以往研究较多探讨单种气象条件下、单个小面积实验型绿化屋面的气候水文调节功能,本研究基于夏秋两季的微气候水文观测数据,定量分析不同气象条件下5种典型绿化屋顶的降温和径流削减效应。首先选择晴朗、多云、降雨3种典型夏日天气条件,分析草坪、裸土、菜地、小面积花园、大面积花园5种类型绿化屋顶与对照光屋顶之间的温度差日变化规律,探讨绿化屋顶热效应强度及时空特征;其次,选择暴雨、大雨、中雨及小雨4次典型降雨,分析大面积草坪与花园型绿化屋顶上的降雨-滞蓄过程及径流削减率。研究结果表明:绿化屋顶降温与升温效应并存,晴朗无风天气条件下,距离屋面10 cm和150 cm两个高度上,绿化屋顶最高可降低气温5.3℃和2.5℃,多云及降雨天气条件下降温强度下降,升温时段延长;白天草坪与裸土上的大气温度高于对照光屋顶,其它绿化屋顶的温度低于对照屋顶;夜间5个绿化屋顶的大气温度均低于对照屋顶,且降温效应按照大面积花园、草坪、小面积花园、裸土、菜地的顺序递减。绿化屋顶径流削减效益与绿化类型及降雨强度密切相关,花园型绿化对一次典型暴雨、大雨、中雨、小雨的径流削减率分别为50.8%、78%、100%、100%,简易型绿化的4次径流削减率分别为24.3%,58.6%,98.2%和100%。研究结果可为同气候区其他城市绿化屋顶环境设计及管理提供一定参考价值。     

山区县乡公路建设对沿线景观格局的影响研究——以昆明市东川区蒋家沟小流域为例

公路建设对区域的各种生态过程、灾害活动等影响引起广大学者的关注,目前对小尺度区域公路沿线景观格局的影响效应研究较少。利用3S技术对云南省昆明市东川区蒋家沟小流域内县乡级公路沿线三期影像的景观进行分类和制图,运用Fragstats3.3软件和景观指数计算方法,从斑块和景观两个层次上研究公路建设前后景观格局的变化。结果表明:(1)不同时期建设公路及全部公路沿线均出现坡耕地显著减少、梯田显著增加的趋势;在不同距离梯度上,针叶林、灌丛、坡耕地景观百分比不断降低,梯田、草地面积增加。(2)公路沿线景观格局动态变化则表现为:在斑块层次上,1973年前建设公路沿线景观形态更复杂,破碎化程度高,1973年后建设公路沿线阔叶林、针叶林斑块数量增加,破碎化趋势明显;在景观层次上,公路沿线景观多样性增加,景观内部连通性降低,整体景观格局破碎化加剧,但1973年前建设公路沿线空间连接性有所提升,1973年后建设公路沿线则表现出空间连接性下降的趋势,公路全线两侧150 m范围对景观水平指数的影响最大。