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91.
基于两种样品前处理方法对比研究小冬克玛底冰川雪坑中痕量元素 总被引:1,自引:0,他引:1
通过对唐古拉山小冬克玛底冰川雪坑中非季风季节沉积的雪样分别进行酸化处理和消解处理后,利用高分辨扇形磁场等离子体质谱仪(ICP-SFMS)测试了样品中19种痕量元素(Ba、U、Sr、Rb、Tl、Mo、Cs、Pb、Sb、V、Cr、Mn、Fe、Co、Al、Cu、Ti、Li、As)的酸化浓度和总浓度.研究结果表明,痕量元素浓度的变化范围较大,元素Al的最大/最小浓度比为326(酸化浓度)和465(总浓度),元素Pb相应比值为27和48.雪冰中痕量元素的总浓度一般大于该元素的酸化浓度,其中,元素Pb、Fe、Sb、Ba、Al、Ti的酸化浓度占总浓度的平均比值分别为91%、76%、60%、52%、33%和21%.一般地,样品中不溶微粒含量越大,酸化浓度占总浓度的比值越小;不溶微粒含量越小,则相反.对痕量元素的富集系数(EF)分析表明,各元素总浓度EF均值小于酸化浓度EF均值,揭示了用酸化浓度计算EF存在对痕量元素人为来源影响的高估.人类排放是小冬克玛底冰川中痕量元素的来源之一,对于元素Mo和Sb,人类排放估计是主要来源.利用后向轨迹模型模拟出小冬克玛底冰川雪冰中痕量元素在非季风季节主要来源于青藏高原西部及中亚中东地区. 相似文献
92.
Rapant S Cvecková V Dietzová Z Khun M Letkovicová M 《Environmental geochemistry and health》2009,31(1):11-25
This study presents an assessment of the potential impact of geological contamination of the environment on the health of
the population in Spišsko-Gemerské rudohorie Mts. (SGR Mts.). The concentration levels of potentially toxic elements (mainly
As, Cd, Cu, Hg, Pb, Sb, and Zn) were determined in soils, groundwater, surface water, and stream sediments as well as in the
food chain (locally grown vegetables). A medical study included some 30 health indicators for all 98 municipalities of the
study area. The As and Sb contents in human fluids and tissues were analyzed in one municipality identified to be at the highest
risk. Based on element content, environmental and health risks were calculated for respective municipalities. Out of 98 municipalities
14 were characterized with extremely high environmental risk and 10 were characterized with very high carcinogenic risk from
arsenic (groundwater). Extensive statistical analysis of geochemical data (element contents in soils, groundwater, surface
water, and stream sediments) and health indicators was performed. Significant correlations between element contents in the
geological environment and health indicators, mainly cancer and cardiovascular diseases, were identified. Biological monitoring
has confirmed the transfer of elements from the geological environment to human fluids and tissues as well as to the local
food chain. 相似文献
93.
A human health risk assessment of rare earth elements in soil and vegetables from a mining area in Fujian Province,Southeast China 总被引:1,自引:0,他引:1
Contaminated food through dietary intake has become the main potential risk impacts on human health. This study investigated concentrations of rare earth elements (REEs) in soil, vegetables, human hair and blood, and assessed human health risk through vegetables consumption in the vicinity of a large-scale mining area located in Hetian Town of Changting County, Fujian Province, Southeast China. The results of the study included the following mean concentrations for total and bio-available REEs of 242.92 ± 68.98 (135.85–327.56) μg g−1 and 118.59 ± 38.49 (57.89–158.96) μg g−1 dry weight (dw) in agricultural soil, respectively, and total REEs of 3.58 ± 5.28 (0.07–64.42) μg g−1 dw in vegetable samples. Concentrations of total REEs in blood and hair collected from the local residents ranged from 424.76 to 1274.80 μg L−1 with an average of 689.74 ± 254.25 μg L−1 and from 0.06 to 1.59 μg g−1 with an average of 0.48 ± 0.59 μg g−1 of the study, respectively. In addition, a significant correlation was observed between REEs in blood and corresponding soil samples (R2 = 0.6556, p < 0.05), however there was no correlation between REEs in hair and corresponding soils (p > 0.05). Mean concentrations of REEs of 2.85 (0.59–10.24) μg L−1 in well water from the local households was 53-fold than that in the drinking water of Fuzhou city (0.054 μg L−1). The health risk assessment indicated that vegetable consumption would not result in exceeding the safe values of estimate daily intake (EDI) REEs (100−110 μg kg−1 d−1) for adults and children, but attention should be paid to monitoring human beings health in such rare earth mining areas due to long-term exposure to high dose REEs from food consumptions. 相似文献
94.
Reconnaissance soil geochemical survey of Gibraltar 总被引:2,自引:0,他引:2
The extreme density of population of Gibraltar, situated at the southern tip of Spain, exerts considerable pressure on land use and thus future planning is of utmost importance. An initial reconnaissance soil geochemical survey of Gibraltar was based on 120 surface samples (0–15 cm) taken from a wide range of exposed, either bare soil or vegetated sites, to provide the optimum geographical distribution. The total elemental concentrations of 26 elements (Li, Na, K, Be, Mg, Ca, Sr, Ba, Al, La, Ti, V, Cr, Mo, Mn, Fe, Co, Ni, Cu, Ag, Zn, Cd, Pb, P, S, As) were determined by nitric/percholric acid digestion followed by inductively coupled plasma-atomic emission spectrometry (ICP-AES) analysis. The reconnaissance data shows that the spatial distribution of various elements depended on previous and present land use. Most elements (Ca, Cr, Mg and Mn excluded) exhibited relatively high concentrations in civilian and natural soils. Trends have been established for many elements, and concentrations exceeding guideline values have been found in certain areas of Gibraltar. This reconnaissance of Gibraltar is at present being followed by a more detailed baseline geochemical survey, which will establish the extent and magnitude of the variations in major and trace elements in soils and dusts, assess the impact of industrial, commercial and urban development on the geochemical landscape and to make recommendations concerning sustainable development. 相似文献
95.
96.
初论元素富集成矿的地球化学机理—以岩浆热液矿床的形成为例 总被引:2,自引:0,他引:2
元素富集成矿的过程实质上是元素在地球不同圈层和不同相以及不同集合体之间分配的结果。元素的富集起始于地球形成的初期。对于大多数金属成矿元素 ,地壳特别是上地壳是大多数矿石和矿胎的储库 ,地壳丰度是元素富集成矿的物质基础。元素在地质体系演化共存相间的分配是元素富集成矿的关键过程。对于以侵入体为中心的热液矿床的形成 ,岩浆部分熔融、结晶分异、液态分离、挥发分分离以及气液相不混溶等过程能够导致金属元素最终达到矿石级的富集。挥发分则是元素富集成矿的重要制约因素 相似文献
97.
Asante KA Agusa T Mochizuki H Ramu K Inoue S Kubodera T Takahashi S Subramanian A Tanabe S 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):862-873
Trace elements (22) and stable isotope ratios (δ15N and δ13C) were analyzed in marine organisms from shallow (SW) and deep-water (DW) of the East China Sea to understand biomagnification and prey source of trace elements. In the benthic marine organisms from DW, δ15N values were negatively correlated with Ba, Cu, Ag, Mo, Sr, As, and Co concentrations. This may be due to the specific accumulation in lower trophic animals and/or the biodilution through the food web in DW. Relationships between δ15N and concentrations of Co, Cr, Bi, and Tl in fish and Ag, Bi, V, Hg, and Tl in crustaceans showed positive correlations, suggesting that trophic position was affecting the concentrations of those elements in phyla, with higher trophic animals retaining higher concentrations than the lower trophic animals. Positive correlations between δ13C and Rb were observed in marine organisms. Therefore, Rb may be a possible substitute of δ13C as tracer of prey source in the East China Sea although further investigation is required. 相似文献
98.
Removal of trace elements in three horizontal sub-surface flow constructed wetlands in the Czech Republic 总被引:1,自引:0,他引:1
Lenka Kröpfelová Jaroslav Švehla 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1186-1194
Between March 2006 and June 2008 removal of 34 trace elements was measured on a monthly basis at three horizontal-flow constructed wetlands in the Czech Republic designed to treat municipal wastewater. In general, the results indicated a very wide range of removal efficiencies among studied elements. The highest degree of removal (average of 90%) was found for aluminum. High average removal was also recorded for zinc (78%). Elements removed in the range of 50-75% were uranium, antimony, copper, lead, molybdenum, chromium, barium, iron and gallium. Removal of cadmium, tin, mercury, silver, selenium and nickel varied between 25 and 50%. Low retention (0-25%) was observed for vanadium, lithium, boron, cobalt and strontium. There were two elements (manganese and arsenic) for which average outflow concentrations were higher compared to inflow concentrations. Reduced manganese compounds are very soluble and therefore they are washed out under anaerobic conditions. 相似文献
99.
100.