温度对氨法脱硫率影响的实验研究

对使用氨（NH3）脱除烟气中气态污染物的技术进行了分析和总结，认为氨洗涤法洗涤净化烟气是一种很有前景的方法，并就温度对SO2脱除率的影响进行了实验研究。实验研究结果显示，当温度超过54℃时，NH3对SO2仍有很高的脱除率。并根据实验结果建议，在实际氨法脱硫工程中，脱硫过程温度宜控制在60℃以下或在80℃以上。     

Characteristics and source apportionment of PM2.5 under the dual influence of the Spring Festival and the COVID-19 pandemic in Yuncheng city

Based on the online and membrane sampling data of Yuncheng from January 1st to February 12th, 2020, the formation mechanism of haze under the dual influence of Spring Festival and COVID-19 (Corona Virus Disease) was analyzed. Atmospheric capacity, chemical composition, secondary transformation, source apportionment, backward trajectory, pollution space and enterprise distribution were studied. Low wind speed, high humidity and small atmospheric capacity inhibited the diffusion of air pollutants. Four severe pollution processes occurred during the period, and the pollution degree was the highest around the Spring Festival. In light, medium and heavy pollution periods, the proportion of SNA (SO₄²⁻, NO₃⁻ and NH₄⁺) was 59.6%, 56.0% and 54.9%, respectively, which was the largest components of PM_2.5; the [NO₃⁻]/[SO₄²⁻] ratio was 2.1, 1.5 and 1.7, respectively, indicating that coal source had a great influence; the changes of NOR (nitrogen oxidation ratio, 0.44, 0.45, 0.61) and SOR (sulphur oxidation ratio, 0.40, 0.49, 0.65) indicated the accumulation of secondary aerosols with increasing pollution. The coal combustion, motor vehicle, secondary inorganic sources and industrial sources contributed 36.8%, 26.59%, 11.84% and 8.02% to PM_2.5 masses, respectively. Backward trajectory showed that the influence from the east was greater during the Spring Festival, and the pollutants from the eastern air mass were higher, which would aggravate the pollution. Meteorological and Spring Festival had a great impact on heavy pollution weather. Although some work could not operate due to the impact of the COVID-19 epidemic, the emission of pollutants did not reduce much.     

Dynamic fate modeling of γ-hexachlorocyclohexane in the lower reaches of the Liao River

A QWASI model dependent on temperature is parameterized to describe the long-term fate of persistent organic pollutants (POPs) in the Liao River. The model parameters, namely fugacity capacity, degradation rate, and transfer coefficient, are profoundly affected by temperature. This model is used to simulate the fate of γ-hexachlorocyclohexane (γ-HCH) in the lower reaches of the Liao River from 1998 to 2008. Modeling results show that γ-HCH fugacity capacities in air, water, and sediment increase as temperature decreases, and the transfer and transformation rate coefficients increase as temperature increases. The variations of transfer and transformation parameter D values depend on fugacity capacities, and transfer and transformation coefficients simultaneously. The performance of the model is evaluated by comparing the predicted and observed concentrations in the water and sediment of the Liao River. The predicted values agree well with the observed value in the order of magnitude, in most cases within the factor of 3. It is believed that the model is appropriate for simulating the long term fate of POPs in the Liao River. Translated from Environmental Science, 2006, 27(1): 121–125 [译自: 环境科学]     

战略环境评价及其应用初探

概述了战略环境价的概念、产生原因、研究现状及其工作程序，结合川南矿肥工程项目对它进行了应用初探，提出了计划、规划层次ＳＥＡ的方法和指标，并对我国环评工作提出了建议。     

沉淀物和生物中U,Th和226Ra的联合测定

用放射化学法对U,Th,~(226)Ra等核素进行联合测定,国外已有不少报道,只是所用的分离方法和所测的介质不同而已。我国学者也做过一些这方面的工作。本工作建立了用三正辛胺-二甲苯萃取分离法对沉积物和生物样中U,Th和~(226)Ra的联合测定方法。 二、主要仪器与试剂     

泉州湾滩涂沉积物对Cu（Ⅱ）的吸附实验

研究了Cu(Ⅱ)在泉州湾滩涂沉积物上的吸附行为。探讨了pH和温度对吸附作用的影响，测定了其吸附等温线。实验结果表明，常温下Cu(Ⅱ)在泉州湾滩涂沉积物上的吸附平衡时间约需3．5小时；吸附量随pH的升高先增大而后减少，pH=6．0左右时达最大；吸附量随温度的升高而增大；其吸附行为可以很好地用Langmuir型吸附等温线来描述。并在此基础上初步探讨了Cu(Ⅱ)在泉州湾滩涂沉积物上的吸附机理。     

利用多次回归拟合水的饱和蒸气压与温度的关系表达式

在使用于湿球测定锅炉烟气含湿量的过程中,需要查找水的饱和蒸气压,非常不方便.利用D-196和<化工原理>上册中取得部分数据,用多次线性回归的方法,拟合出水在0～200℃范围内的饱和蒸气压与温度的关系表达式;并对该表达式的误差进行了分析,误差均值为0.2‰,最大值也只有0.8‰,完全可以满足环境监测中数据处理的精度要求.     

On-line optical determination of floc size of Fe(Ⅲ) coagulants

This study investigated the floc aggregation, average floc size, floc size variance and floc growth velocity when ferric chloride （FeCl3） and polyferric chloride （PFC） were used to treat the simulated water samples. The factors including coagulant dose, ionic strength and solution pH, which affect the floc aggregation, were studied. Experiments were carried out in a bench-scale reactor using photometric dispersion analyzer （ PDA）. Results showed that there were great differences between the floc aggregation of PFC and FeCl3. The average floc size and fioc growth velocity of PFC were much larger than those of FeCl3. Compared with FeCl3, PFC gave a better coagulation performance in wider range of pH, dosage and ionic strength. It was also found that the coagulation efficiency of PFC did not depend on average floc size but on floc growth velocity.     

戴明循环理论在规划环评工作程序中的应用初探

通过分析现阶段我国规划环评的现状和存在的问题,结合国内外规划环评及其工作程序的研究成果,提出使用戴明循环理论对现阶段的规划环评工作程序进行改进,使程序层次化、工作细分化,增强整个规划环评工作的可操作性,使规划环评工作落实到单位和人,明确责任,减少部门间冲突.戴明循环理论的引入,提高规划环评的评价效果和效率,为规划环评提供了一个有效科学的评价方法,有助于规划环评的顺利开展,使环境问题从源头上得到控制,适应建设和谐社会的需要.     

采用钙钛矿型催化剂(La0.8K0.2Cu0.05Mn0.95O3)同时催化去除NOx和碳烟的研究

将钙钛矿型催化剂与碳烟均匀混合后置于固定床连续流动反应体系中,利用程序升温反应技术,在模拟柴油机尾气的情况下对同时催化去除氮氧化物(NOx)和碳烟的反应进行了实验研究.通过改变含Cu原料的用量,得到不同Cu取代量的催化剂La0.8K0.2CuxMn1-xO3,性能评价结果表明,La0.8K0.2Cu0.05Mn0.95O3催化剂的综合性能较好,碳烟的起燃温度及NO向N2的最大转化率分别为280℃和58.0%.采用该催化剂,进一步考察了进气中NO浓度、O2浓度、进气总流量及催化剂与碳烟的接触状况对反应的影响.研究结果表明,进气中NO浓度、O2浓度、气体总流量和催化剂与碳烟之间的接触状况对NO的去除率的影响比较明显,而对碳烟起燃温度的影响较小.O2浓度从5%变为7.5%时,碳烟的起燃温度及最大NO转化率分别从280℃和53.8%变为270℃和96.7%.碳烟与催化剂松散接触时,碳烟的起燃温度及最大NO转化率分别为290℃和48.4%,紧密接触时分别为275℃和70.4%.而进气中NO浓度、气体总流量的变化对碳烟的燃烧基本上没有影响,虽然NO的转化率有明显变化,但生成的N2总量基本不变.