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221.
KFR-2特种饰面型防火涂料的热解动力学分析 总被引:1,自引:0,他引:1
利用梅特勒TA4000,25-TC15型热分析仪对KFR-2特种饰面型防火涂料和普通乳胶漆涂料进行了TG和DSC分析,研究了KFR-2特种饰面型防火涂料和普通乳胶漆涂料的降解过程.在分析动力学理论模型基础上,分析数据,确定了KFR-2特种饰面型防火涂料和普通乳胶漆涂料的热力学参数,活化能.通过分析比较得出,与普通乳胶漆相比,KFR-2特种饰面型防火涂料由于添加了阻燃成分,使活化能显著提高,热稳定性明显加强,体系耐热性能好,阻燃效果明显. 相似文献
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中、低纬度地区山地冰川有机酸记录的研究是目前国际冰芯地球化学研究的前沿之一。中国天山乌鲁木齐河源一号冰川为一中纬度山地冰川。对其冰芯的草酸根含量的分析显示,其冰芯所记录的过去43 年草酸根变化的总体特征是在一个背景值基础上存在着含量的突变峰值。草酸根的背景值含量在1 ng/g左右,在部分冰芯段,其含量甚至低于测试分析的检测限;而大多数草酸根峰值的含量都达到或超过了10 ng/g。草酸根的平均含量为3.6 ±9.2 ng/g ( x±1σ, N=534),其中70%以上由峰值构成。50年代后期是草酸根的一个低值期,平均含量略高于本底值;至60-70年代达到最高值,平均含量为5.0ng/g;80年代草酸根平均含量又下降到接近50 年代后期的水平;至90年代回落到本底值附近。草酸根的主要来源是人类活动对大气所造成的污染。其过去43 年平均含量的变化大致与中国西部工业和环境保护事业的发展历程相一致,是西部区域大气污染变化的一种反应。 相似文献
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长光路FTIR研究OH发生体系中的OH浓度 总被引:2,自引:0,他引:2
利用长光路FTIR测定早苯、三本等芳香烃化合物在烟雾箱中光化学反应衰减,确字了NOx-H2O、Air、HONO-H2O-Air和CH3ONO-NO-Air3种体系在我灯自夸下的OH浓度,结果表明三者OH浓度范围分别为:~10^5~10^6、~10^7、~10^7~10^8molecules.cm^-3,并进一步讨论了反应前体物对生成OH浓度的影响。 相似文献
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R. G. Clawson B. G. Lockaby R. B. Rummer 《Journal of the American Water Resources Association》1999,35(5):1081-1088
ABSTRACT: Floodplain forests directly influence water quality by serving as sinks, sources, or transformers of nutrients. Increases in the demand for timber raise the question of how silvicultural disturbance may affect this function. The objective of this research was to compare biogeochemical relationships between undisturbed vs. disturbed conditions in a floodplain forest. A randomized complete block design consisting of three blocks and two treatments (partial harvest and undisturbed) was installed on the Flint River floodplain, Georgia. The partial cut was conducted during September-October 1993. Automated water samplers were situated to sample during flood events as sheet flow entered and exited treatment plots during the 1994, 1995 and 1996 flood seasons. Prevs. post-contact comparisons indicated that the undisturbed floodplain has minimal influence on water chemistry at this scale of measurement. Although the partial harvest on an 8-ha scale had minimal effect upon sheetfiow water chemistry for three years following harvest, the data suggest that harvests may stimulate a minor increase in Ca and K sink activity. 相似文献
229.
Brent Finley Paul K. Scott Meghan E. Glynn Dennis Paustenbach Kerry A. Thuett 《毒物与环境化学》2017,99(1):48-64
The objective of this study was to determine the valence state of chromium (Cr) in the blood of individuals with Cr-containing metal hip implants. Serum and red blood cell (RBC) Cr concentrations from 52 patients with Cr-containing total hip arthroplasties were measured preoperatively and at 3, 12, and 24 months postoperatively. Geometric mean and median pre-surgery serum Cr concentrations were consistently below 0.2 µg/L, while geometric mean and median pre-op RBC Cr concentrations were typically about four- to six-fold higher than the serum values. A significant 5- to 13-fold increase was found in the mean and median serum Cr concentrations three months post-surgery, with an 8- to 18-fold rise at 12 and 24 months, respectively. Steady-state serum concentrations were reached between 3 and 12 months. In contrast, there were no marked differences in mean and median RBC Cr concentrations pre- and post-surgery. Slope regression analysis for our data was similar to those reported for Cr(III) in spiked blood samples. The analysis showed that Cr released from hip implants preferentially distributed into serum and not RBC, indicating that the form of Cr present in blood of hip implant patients was in the form of non-toxic Cr(III). Our findings indicate that blood Cr concentrations Cr(III) associated with metal implants do not pose an adverse health risk to patients, which is in agreement with findings published by most investigators. 相似文献
230.
J.-C. Aznar M. Richer-Laflche H. Paucar-Muoz M. Bordeleau Y. Bgin 《Chemosphere》2009,76(10):1366-1371
In the context of intense emissions causing atmospheric pollution, tree growth reductions could be related to soil chemistry modifications or direct foliar injuries. To verify these hypotheses, mineral soils were sampled in an area (Murdochville, Canada) where previous studies had demonstrated that tree growth was impacted by smelter emissions and that forest floor lead concentrations could be used as a proxy for atmospheric pollutant depositions. Samples were analysed for Al, Pb (concentrations and isotope ratios), basic cations (Ca, K, P, and Mg) and Zr. Mass balance calculations were performed on soil profiles to assess vertical migration of elements. Pb concentrations in litter diminished gradually with distance from the smelter. The Pb isotope ratios in these organic soil layers were close to those measured in the Murdochville ores. These patterns were not encountered in mineral soil layers. Pb isotope ratios in these layers were close to those measured in uncontaminated geological materials, and Pb concentrations and basic cation depletions were not related to the proximity of the smelter. Growth reduction was closely associated with litter Pb concentrations, which were used as a proxy for atmospheric deposition, but was not correlated with any elemental concentration or cation depletion measured in mineral soil layers. Our overall results suggest that trees responded mainly to direct atmospheric emissions, which caused foliar damage, rather than to soil chemistry modifications. 相似文献