除草定在土壤中的降解和移动特性研究

除草定是一种新型嘧啶类除草剂,其在环境中的归趋备受关注。采用室内模拟试验方法,研究了除草定在不同土壤中的降解性、吸附性和移动特性。结果表明,除草定在江西红壤、太湖水稻土和东北黑土中的降解半衰期分别为693.1、173.3、138.6 d,该药在土壤中降解较慢,影响其在土壤中降解速率的主要因素为土壤有机质。除草定在江西红壤、太湖水稻土与东北黑土中的吸附较好地符合Freundlich方程,Kd值分别为0.34、1.86和2.94;3种土壤对除草定的吸附过程为自发的物理吸附。薄层层析试验显示,当溶剂展开至11.5 cm处,除草定在江西红壤、太湖水稻土和东北黑土中最远移至8~10 cm处。影响除草定在土壤中吸附性和移动性的主要因素为土壤有机质含量。除草定存在对地下水污染的潜在风险性,使用除草定应该引起足够重视。     

压煤村庄搬迁对农业生产的影响——以兖州市为例

我国的煤炭资源开采大部分都是采取井下开采的方式,该种开采方式在进行过程中容易引起覆岩层的原始平衡状态遭受破坏,同时伴随冒落、断裂或者弯曲等移动变形的情况出现,并最终涉及地表。到目前为止,由采矿引起的地面塌陷和地表开裂,已经导致了大量建筑物被破坏,给农民的生产生活带来了极大的不便,对农业生产的发展造成了极大的阻扰,减少了耕地,形成了社会的不稳定因素,严重影响地区的社会的发展与稳定。压煤村庄搬迁能改善矿区居民的生活环境和基础设施建设,加快小城镇建设和城乡一体化发展的进程,但是由于村庄搬迁引起的耕作半径增加,改变了从居住区到田地的距离,引起机械化程度、耕种方式和农业劳动力需求等变化,从而将在一定程度上影响本地区的社会稳定性,也会增加整个社会的就业压力。山东省是重要的产煤发展基地,村庄搬迁后远离耕地,为农民的往返与出入带来了不便。本文以兖州市已搬迁的八个村庄为研究对象,采取调查问卷的形式进行了实地调研,并将调查后的数据进行了分类统计与回归分析,运用SPSS软件进行Logit模型回归分析,最终确定主要生活来源和田间道路修建两个因子与农民从事农业生产的意愿存在密切的相关性,交通工具的变更与大型机械的配备对其也有较大的影响作用,研究结果可为该政府相关部门制定村庄搬迁和农业生产有着重要的理论指导意义。     

经济增长和环境规制对雾霾的区际影响差异

为探究不同省级区域雾霾、经济增长和环境规制之间的空间关联效应,本文提出针对雾霾的引力模型空间权重矩阵,并利用该矩阵建立了空间杜宾模型,分别对全国、西部、中部和东部省区的面板数据进行了空间计量检验。实证结果显示:全国雾霾的莫兰指数值显著,且取值介于0.367—0.460之间;雾霾"重心"呈现先向东南再向西北移动的趋势,移动距离为76 557 m;雾霾的莫兰指数值为东部省区最大,西部省区最小,中部省区介于二者之间。全国的雾霾与经济增长之间呈显著的"U"型曲线,而西部、中部和东部省区则呈倒"U"型曲线,其中中部省区的曲线最为陡峭,西部省区次之,东部省区最为平缓。环境规制每增加1%,只有西部和东部的雾霾相应减少,且各自相应下降0.009和0.010个百分点。西部和东部经济增长的溢出效应均显著,而环境规制的溢出效应不显著。研究结果表明:(1)雾霾在空间上表现出集聚的特点,全国和三个区域的雾霾都存在显著的正向空间溢出效应,这种空间依赖性在时间维度上大致呈加强的趋势;雾霾的空间相关性表现为东部省区最强,西部省区紧随其后,中部省区最低。(2)西部和东部省区部分省市还未过拐点,全国意义上的环境库茨涅兹假说是不存在的,或者是至少还未出现。(3)西部和东部环境规制效果较为理想,而中部省区的环境规制效果不佳;从全国总体来看,当前的环境规制整体上对雾霾并未起到有效的抑制作用。(4)东西部省区和中部省区经济增长对雾霾溢出效应分别表现为正向和反向;环境规制对雾霾的溢出效应并不显著。建议加强对雾霾的区域协同治理,重点推进西部和东部省区经济结构的转型升级,调整和完善西部、中部和东部省区的环境规制政策。     

A network approach to prioritize conservation efforts for migratory birds

Habitat loss can trigger migration network collapse by isolating migratory bird breeding grounds from nonbreeding grounds. Theoretically, habitat loss can have vastly different impacts depending on the site's importance within the migratory corridor. However, migration-network connectivity and the impacts of site loss are not completely understood. We used GPS tracking data on 4 bird species in the Asian flyways to construct migration networks and proposed a framework for assessing network connectivity for migratory species. We used a node-removal process to identify stopover sites with the highest impact on connectivity. In general, migration networks with fewer stopover sites were more vulnerable to habitat loss. Node removal in order from the highest to lowest degree of habitat loss yielded an increase of network resistance similar to random removal. In contrast, resistance increased more rapidly when removing nodes in order from the highest to lowest betweenness value (quantified by the number of shortest paths passing through the specific node). We quantified the risk of migration network collapse and identified crucial sites by first selecting sites with large contributions to network connectivity and then identifying which of those sites were likely to be removed from the network (i.e., sites with habitat loss). Among these crucial sites, 42% were not designated as protected areas. Setting priorities for site protection should account for a site's position in the migration network, rather than only site-specific characteristics. Our framework for assessing migration-network connectivity enables site prioritization for conservation of migratory species.     

超重力-磷酸钠法脱除低浓度SO2

为开发脱硫率高、成本低、可回收SO2的脱硫技术,以旋转填料床为吸收设备,磷酸钠溶液为吸收剂,系统开展了液气比L／G、转速N、气体中SO2浓度CSO2,in吸收剂磷酸浓度CL和初始pH等工艺参数和溶液再生循环次数对脱硫率叼影响的实验研究。结果表明,叩随L／G、N、CL和初始pH的增加而增大,且它们的值越低时,叩增加越明显;受G和CSO2,in影响较小。在适宜操作条件下,脱硫率达99％以上,出口SO2浓度低于100mg／m^3。磷酸钠溶液可再生循环使用,脱硫率稳定在99％以上。表明超重力-磷酸钠法脱硫技术在小的液气比下即可达到高的脱硫率,吸收剂循环使用,可实现低成本并达标治理SO2废气,且适用范围宽,具有良好的工业应用前景。     

Regional-scale application of the decision support system MOIRA-PLUS: an example of assessment of the radiological impact of the Chernobyl accident on the fresh water ecosystem in Italy

The present work illustrates the customisation and application of the decision support system MOIRA-PLUS (a MOdel-based computerised system for management support to Identify optimal remedial strategies for Restoring radionuclide contaminated Aquatic ecosystems and drainage areas) to the fresh water environment in Italy. MOIRA-PLUS is aimed at evaluating the behaviour of radiocaesium and radiostrontium in fresh water ecosystems and at assessing the appropriateness of suitable strategies for the management of contaminated water bodies by the application of multi-attribute analysis techniques. MOIRA-PLUS can be applied to complex networks of lakes, rivers and tributaries and can be straightforwardly customised utilising data and information from readily accessible sources such as official websites provided by scientific or government organisations. The present work shows an application of the decision system to 10 lakes and 18 rivers in Italy contaminated with ¹³⁷Cs of Chernobyl origin. Site-specific values of some aggregated transfer parameters were estimated for the most important Italian lakes. Although high values of fish and water consumptions were hypothesised, very low doses to public from the fresh water pathway following the accident were calculated.     

超重力-磷酸钠法脱除低浓度SO2

为开发脱硫率高、成本低、可回收SO₂的脱硫技术,以旋转填料床为吸收设备,磷酸钠溶液为吸收剂,系统开展了液气比L/G、转速N、气体中SO₂浓度CSO₂,in、吸收剂磷酸浓度CL和初始pH等工艺参数和溶液再生循环次数对脱硫率η影响的实验研究。结果表明,η随L/G、N、CL和初始pH的增加而增大,且它们的值越低时,η增加越明显;受G和CSO₂,in影响较小。在适宜操作条件下,脱硫率达99%以上,出口SO₂浓度低于100 mg/m³。磷酸钠溶液可再生循环使用,脱硫率稳定在99%以上。表明超重力-磷酸钠法脱硫技术在小的液气比下即可达到高的脱硫率,吸收剂循环使用,可实现低成本并达标治理SO₂废气,且适用范围宽,具有良好的工业应用前景。     

Predictors of urinary bisphenol A and phthalate metabolite concentrations in Mexican children

Exposure to endocrine disrupting chemicals such as bisphenol A (BPA) and phthalates is prevalent among children and adolescents, but little is known regarding important sources of exposure at these sensitive life stages. In this study, we measured urinary concentrations of BPA and nine phthalate metabolites in 108 Mexican children aged 8–13 years. Associations of age, time of day, and questionnaire items on external environment, water use, and food container use with specific gravity-corrected urinary concentrations were assessed, as were questionnaire items concerning the use of 17 personal care products in the past 48-h. As a secondary aim, third trimester urinary concentrations were measured in 99 mothers of these children, and the relationship between specific gravity-corrected urinary concentrations at these two time points was explored. After adjusting for potential confounding by other personal care product use in the past 48-h, there were statistically significant (p < 0.05) positive associations in boys for cologne/perfume use and monoethyl phthalate (MEP), mono(3-carboxypropyl) phthalate (MCPP), mono(2-ethyl-5-hydroxyhexyl) phthalate (MEHHP), and mono(2-ethyl-5-oxohexyl) phthalate (MEOHP), and in girls for colored cosmetics use and mono-n-butyl phthalate (MBP), mono(2-ethylhexyl) phthalate (MEHP), MEHHP, MEOHP, and mono(2-ethyl-5-carboxypentyl) phthalate (MECPP), conditioner use and MEP, deodorant use and MEP, and other hair products use and MBP. There was a statistically significant positive trend for the number of personal care products used in the past 48-h and log-MEP in girls. However, there were no statistically significant associations between the analytes and the other questionnaire items and there were no strong correlations between the analytes measured during the third trimester and at 8–13 years of age. We demonstrated that personal care product use is associated with exposure to multiple phthalates in children. Due to rapid development, children may be susceptible to impacts from exposure to endocrine disrupting chemicals; thus, reduced or delayed use of certain personal care products among children may be warranted.     

红浅稠油污水回用锅炉处理技术研究与应用

文章介绍了红浅稠油污水处理站采用的"离子调整旋流反应+216t/h软化水"处理工艺,该工艺创新性的采用了分置式反应罐,将混凝、反应、加药、沉降、颗粒吸附有机结合,优选出高效的污水处理药剂,首次在新疆油田公司污水处理工艺中应用改性纤维束过滤器和216t/h软化水处理装置,优化了各节点的配套工艺,使处理后的污水水质达到回用锅炉水质标准,取得了良好的效果。同时,通过对加药浓度、隔油、反冲洗周期等参数优化,保证了红浅稠油污水回用锅炉处理系统的平稳运行,累计处理回用污水约730万m3,有效地节约了水资源,保护了环境,综合效益显著。     

Migration and biological effect of natural heavy radionuclides on plants

A complex radioecological study of technogenic landscapes of southern Yakutia showed that the main factor responsible for their contamination with uranium and radium is radionuclide dispersal by air with products of rock weathering. Coefficients of biological absorption by plants decrease with an increase in the contamination level, which is explained by the fact that strongly fixed forms of uranium and radium prevail in the contaminated areas. In addition, the root barrier plays an important role. Radiation load is mainly determined by background gamma-radiation. The contribution of internal irradiation accounted for by incorporated radionuclides does not exceed 16% and decreases with an increase in the level of soil contamination. Manchurian alder seeds produced under conditions of enhanced background radiation are more viable than those from the control area. It is shown that seed generations of plants growing under conditions of chronic irradiation are highly resistant to the radiation factor.