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181.
目的 针对包含模糊样本的复合抽检型产品开展贮存寿命评估。方法 针对批次产品中的出厂失效数据和贮存失效数据,开展批次数据的相容性检验。通过出厂失效样本数随机化处理,量化贮存过程中模糊样本的不确定性。将出厂试验数据作为先验信息,贮存过程中的出厂试验数据作为观测信息,基于Bayes融合方法,更新出厂失效概率。通过更新后的出厂失效概率,确定模糊样本的组成,筛选出贮存失效概率样本。针对筛选后的样本,基于样本量加权最小二乘方法,开展贮存寿命评估。结果 将所提方法应用于某弹箭产品案例,有效评估了批次出厂失效概率及其估计方差,并给出了可靠寿命评估结果。结论 所提Bayes评估方法融合了出厂抽检数据和贮存抽检数据,有效解决了含模糊样本的失效概率估计问题,提高了估计的精确性,基于样本量权重的加权最小二乘法,考虑了样本的可信程度,提升了方法的科学性。 相似文献
182.
酶底物法与多管发酵法和纸片法监测环境水样大肠菌群的比较 总被引:3,自引:0,他引:3
用标准菌株对比了酶底物法和多管发酵法及快速纸片法,监测分析了分组环境水样中的大肠菌群。结果表明,酶底物法操作快速、简单、结果稳定、无二次污染,能满足水质监测和应急监测的需求。 相似文献
183.
纳米TiO 2 -碳纳米管复合膜修饰电极伏安法测定水中α -萘酚和β -萘酚 总被引:2,自引:1,他引:1
摘要:制备了一种新型的纳米TiO2-碳纳米管复合膜修饰电极,在pH值为5.57的NaAc-HAc缓冲溶液中,研究了α-萘酚和β-萘酚在该修饰电极上的电化学行为,据此建立了纳米TiO2-碳纳米管复合膜修饰电极伏安法测定水中α-萘酚和β-萘酚的方法。优化了试验条件,α-萘酚和β-萘酚分别在8.3×10^-7mol/L—1.0×10^-5mol/L和7.8×10^-7mol/L—1.0×10^-5mol/L范围内,浓度与氧化峰电流呈良好的线性关系,开路富集3min,检出限分别为3.5××10^-7mol/L和2.3×10^-7mol/L,模拟水样测定的回收率为97.6%—101%。 相似文献
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186.
Claude Schummer Elodie Mothiron Anne-Laure Rizet Maurice Millet 《Environmental pollution (Barking, Essex : 1987)》2010,158(2):576-8129
Atmospheric samples have been collected in Strasbourg between April 18 and May 29, 2007 and were analyzed for 71 current-use pesticides, of which 38 were detected. Average concentrations ranged from 0.09 ng m−3 for Fenarimol to 110.42 ng m−3 for Dimethachlor, which was slightly higher than the concentrations reported from other, comparable agricultural regions.Significant temporal variations were observed for 30 pesticides, and for most of them it could be shown that these were linked to time, temperature or atmospheric pressure. In several cases this helped to identify pesticide application just before or at the beginning of the sampling period, or ongoing treatment. Humidity, in contrast to previous reports, could not be linked to these variations. For the other 8 pesticides, only very little temporal variations were observed. Generally, these concentrations were low (less than 1 ng m−3), and it was assumed that they are not in use in Alsace at present. 相似文献
187.
Srivastava SK Rai V Srivastava M Rawat AK Mehrotra S 《Environmental monitoring and assessment》2006,116(1-3):315-320
Popularity of herbal drugs is increasing all over the world because of lesser side effects as compared to synthetic drugs.
Besides, it costs less and easily available to poor people particularly in developing countries. But quality assurance of
herbal drugs is very necessary prior to its use. Because in today's polluted environment, even herbal drugs are not safe.
Berberis spp. is very important medicinal plant, having various medicinal properties. It is also included in Indian and British pharmacopoeias.
Its demand is quite high in herbal drug market. So, to check the quality of market samples of this drug, ten different samples
were procured from different drug markets of India for heavy metal estimation. Besides, genuine samples of four species of
Berberis viz. B. aristata, B. chitria, B. lycium, B. asiatica were also collected from natural habitats to compare heavy metal concentration in both market and genuine samples. It was found that market samples were much more contaminated than genuine samples. Lead (Pb) concentration is far beyond
from WHO permissible limit (10 ppm) for herbal drugs, reaching to maximum 49.75 ppm in Amritsar market sample. Likewise, concentration
of all other metals like Cd, Cr and Ni were also very high in market samples as compared to genuine samples. 相似文献
188.
IntroductionNitrousoxide (N2 O)isoneoftheenvironmentallyimportanttracegases ,currentlyaccountingfor 2 %—4 %oftotalGreenhouseWarmingPotential (GWP ) .Itisalsoinvolvedinthedepletionofstratosphericozone .SoilhasbeenknownasthemajorsourceofN2 O ,accountingfor 6 5 %oftotalglobalemissions(Prather,1995 ) .Thus,reducingN2 Oemissionsfromsoilsisamaintaskfortheprotectionoftheglobalatmosphere .N2 Oisproducedastheresultofsoilmicrobialprocesses ,primarillybynitrification ,whentheoxidationhappensofNH+… 相似文献
189.
选用对氯苯酚固体和市售对氯苯酚标准溶液分别配制成2种可吸附有机卤素(AOX)标准溶液和标准样品进行实验.结果表明,使用对氯苯酚固体配制的AOX标准溶液,其分析曲线和带标分析结果良好,检出限为6.6μg/L,加标回收率为80.1% ~106%;使用市售对氯苯酚标准溶液配制的AOX标准样品,其测定结果均在参考不确定度范围内... 相似文献
190.
Kumar KS Suvardhan K Rekha D Kiran K Rao GC Jayaraj B Janardhanam K Chiranjeevi P 《Environmental monitoring and assessment》2007,129(1-3):271-276
Facile, selective and sensitive spectrophotometric method has been developed for the determination of carbosulfan in insecticidal
formulations, fortified water, food grains, agriculture wastewater and soil samples with newly synthesized reagents. The method
was based on acid and alkaline hydrolysis of the carbosulfan pesticide, and the resultant hydrolysis product of carbosulfan
was coupled with 2,6-dibromo-4-methylaniline to give a yellow color product with λ
max of 464 nm or interaction with 2,6-dibromo-4-nitroaniline to produce yellow colored product with λ
max of 408 nm or coupling with 2,4,6-tribromoaniline to form red colored product has a λ
max of 471 nm. Under optimal conditions, Beer’s law range for 2,6-dibromo-4-methylaniline (DBMA) was found to be 0.2–12.0 μg
ml−1, 0.6–16.0 μg ml−1 for 2,6-dibromo-4-nitroaniline (DBNA) and 0.4–15.0 μg ml−1 for 2,4,6-tribromoaniline (TBA). The molar absorptivity of the color systems were found to be 3.112 × 104 l mol−1 cm−1 for DBMA, 3.214 × 104 l mol−1 cm−1 for DBNA and 3.881 × 104 l mol−1 cm−1 for TBA. Sandell’s of the color reactions are 0.013 μg cm−2 (DBMA), 0.012 μg cm−2 (DBNA) and 0.011 μg cm−2 (TBA) respectively. The effect of the non-target species on the determination of carbosulfan was studied to enhance the selectivity
of the proposed methods. The formation of colored derivatives with the coupling agents is instantaneous and stable for 28,
30, and 26 h. Performance of the proposed methods were compared statistically in terms Student’s F and t-tests with the reported methods.
An erratum to this article can be found at 相似文献