焦炭塔现场操作的危险原因分析和解决措施

根据具体的事故案例,对焦炭塔现场操作过程存在的各种危险进行了原因分析,提出要从完善仪表控制、加强操作工培训、改善操作条件、进行技术动改及不断完善操作规程和各类制度等方面入手,切实做好各类基础工作,才能消除危险,保障安全。     

常减压装置自燃危险分析及对策

通过对常减压装置内介质温度和自燃点的比较分析,绘制装置自燃危险分析图,确定自燃危险的重点防护区,并提出对策措施。     

易燃、易爆危险化学品铁路运输危险性分析

从定性和定量两个方面对易燃、易爆危险化学品的铁路槽罐车运输过程和装卸过程的危险性进行分析,利用道化学火灾爆炸指数法计算易燃、易爆危险化学品铁路罐车的火灾爆炸指数,进行重大危险源辨识,并对重大危险源的概念进行了理论探讨,提出移动式重大危险源的概念。     

Thermal hazard and decomposition kinetics of 1-butyl-2,3-dimethylimidazolium nitrate via TGA/DSC and FTIR

1-Butyl-2,3-dimethylimidazolium nitrate ([Bmmim][NO₃]), a kind of versatile and novel ionic liquids, is widely applied in the modern petrochemical industry. Nevertheless, its thermal hazard safety data at high temperature or thermal disturbance conditions are currently unavailable. Therefore, this study aimed to characterize the thermal risk of [Bmmim][NO₃] through auto-ignition temperature measurements, flash point analysis, thermal gravimetric analysis/differential scanning calorimetry (TGA/DSC), TGA-Fourier transform infrared spectroscopy (TGA-FTIR) and thermal decomposition kinetics analysis. Additionally, [Bmmim][NO₃] was examined using isothermal thermogravimetric analysis at different temperatures (220, 230, 240, 250, 260 and 270 °C). The experimental results show that the flash point of [Bmmim][NO₃] is 305.70 ± 9.30 °C and the auto-ignition temperature is 341.00 ± 21.60 °C with an ignition delay time of 8.6 s. In addition, using the nitrogen atmosphere TGA data to calculate the activation energy according to the Friedman, Kissinger and Flynn-Wall-Ozawa methods, roughly the same results were obtained. Finally, TGA-FTIR results show that [Bmmim][NO₃] produced acetylene, butane, butanol and carbon dioxide during the thermal decomposition process. This study could provide data support and some guidance for the thermal hazard assessment and safety control of [Bmmim][NO₃] during its use and storage.     

Challenges and Opportunities for Creating Intelligent Hazard Alerts: The “FloodHippo” Prototype

Disasters evolving from hazards are a persistent and deadly occurrence in the United States. Despite this, hazard alerts have remained spatially vague, temporally imprecise, and lack actionable information. These deficiencies indicate a divide between the status quo and what is possible given modern environmental models, geographic information systems (GIS), and smartphone capabilities. This work describes an alternative, prototype system, “FloodHippo,” which integrates operational model outputs, cloud‐based GIS, and expanded communication channels to provide personal and interactive disaster alerts for floods. The precepts and methods underpinning FloodHippo apply equally to other disasters that evolve over space and time, presenting the opportunity for a more intelligent disaster response system. The development of such a system would not only minimize current shortcomings in disaster alerts but also improve resilience through individual action, along with community, academic, and federal cooperation.     

基于安全理念的长春市重大危险源控制规划研究

重大危险源控制规划与城市规划紧密结合,不仅是科学建设城市的要求,也是维护社会稳定的要求.通过对长春市现状居住用地布局、工业用地布局、仓储用地布局、燃气工程及加油站等概况及存在的安全隐患进行分析,根据城市规划和管理的需要,从城市的安全功能区划、重大危险源辨识、重大危险源安全规划对象、风险评价、风险控制等方面,提出了长春市重大危险源控制规划编制工作的迫切性及研究内容.将重大危险源的布局结合在城市规划当中,一方面可以使城市规划充分考虑重大危险源的安全问题,另一方面能够从规划层面上减小重大危险源对人民生命财产安全造成的危害.     

石油化工企业常见危险源分析及其安全对策研究

随着石化企业新技术、新工艺、新材料的不断应用,石化企业危险化学品的数量及种类逐渐增多,危险源和安全隐患日益突出,石化企业的发展面临安全生产新挑战.本文从石油化工原料产品、化工反应装置等方面人手,分析了石化企业的主要危险源,并分析了常减压蒸馏装置、催化裂化装置、聚丙烯装置、延迟焦化装置及汽油加氢装置等常见生产装置的危险性...     

企业实施环境因素和危险源辨识中遇到的问题及解决办法

环境因素和危险源的辨识是环境管理体系和职业健康安全管理体系建设的一项重要内容.本文针对企业在实施环境因素和危险源辨识过程中遇到的环境因素和危险源的描述不准确、辨识程度如何掌控、三种时态和状态的运用、重大危险源的确定等问题进行了分析,并阐述了对标准要求的理解和具体解决办法.     

水下爆破冲击波危害及安全控制措施的模拟分析

水下爆破工程已广泛应用于经济建设的许多领域,但由于水下爆破的特殊性和复杂性,使得人们对水下爆破的危害及控制难以预测.本文采用数值模拟的方法分析了水下爆破冲击波危害及安全控制措施,为水下爆破作业中的安全控制提供了有效的方法.     

Application of microcosm and species sensitivity distribution approaches in the ecological hazard assessment of 4-tert-butylphenol

In order to evaluate the ecological hazard of 4-tert-butylphenol (4-TBP), species abundances and physicochemical properties were monitored for 63 days in a microcosm system containing planktonic algae, rotifers, shrimps and Daphnia. The 63 days-NOEC (no observed effect concentration) of 4-TBP for this system was calculated. At the same time, species sensitivity distribution curves were constructed based on the toxicity data of EC₁₀, EC₅₀ and NOEC derived from laboratory single-species toxicity tests, which further gives no obvious hazard concentrations for 95% species in the ecosystem (HC₅). In both the microcosm and the single-species tests, the shrimp (Neocaridina sp.) was the most sensitive species to 4-TBP exposure, while most algae species were relatively insensitive compared to the zooplankton. For the microcosm exposed to 4-TBP, significant changes occurred to the community structure instead of the community function, resulting in a NOEC_microcosm of 265.38?μg?L^–1 which approached the EC₁₀-based HC₅ (0.376?mg?L^–1). Nevertheless, EC₅₀-based HC₅ was higher than the NOEC_microcosm, and the NOEC-based HC₅ was lower. The data showed that the EC₁₀-based HC₅ was protective at the similar level with the result of microcosm for 4-TBP, providing supportive data for chemical risk assessment.