电极旋转放电条件下O3合成效率的理论研究

根据低温等离子体理论和电磁场理论，在实验的基础上研究了电极旋转条件下低温等离子体的产生机制和臭氧的合成机制，分析了放电过程中二次放电重叠对臭氧合成的影响，建立了旋转放电与二次放电的理论模型，并根据这一理论模型导出电极旋转条件下的臭氧合成效率与二次放电重叠概率以及电极旋转速度间的理论关系．这一理论结果表明：二次放电重叠使得臭氧合成效率降低，而电极以适当地速度旋转则可以有效地避免二次放电的重叠，从而提高臭氧的合成效率．理论值和实验结果能够较好地吻合．     

我国环境标准体系现状分析

环境标准是评价环境质量和环境保护工作的法定依据。标准体系的有效运作依赖于体系中标准的科学性和标准间的协调性，文章分析了我国现行环境标准体系存在的问题：一些环境标准的宽严程度不适当；环境标准所覆盖的保护范围不够，不利于我国经济的可持续发展，环境标准的制订缺乏连贯性，环境标准体系之间缺乏相互间的协调和统一，对环境标准体系的调整提出建议：探索制定标准的科学方法；建立健全产品的环境标准体系；建立标准制定发布机制和后评价机制等。     

水库触发地震研究进展

水库诱发的地震活动由于其潜在的破坏性巨大而受到重视。自1945年Carder首次指出美国米德湖水库蓄水触发地震后,各国学者针对不同地区的水库触发地震进行了大量研究。本文总结前人研究的结果,将人类对水库触发地震的研究内容从以下四个方面进行了归纳:(1)空间分布;(2)触发机理;(3)类型;(4)特征。并提出了今后研究的重点和方向。通过水库触发地震研究综述,为我国进一步开展地震活动与水库运行之间关系的研究提供了科学依据。     

Influence of new town development on the urban heat island - The case of the Bundang area

Five new towns have been developed around the Seoul metropolitan area since 1996. However, these new towns generate lots of traffic and related problems in the areas including those new towns and Seoul as a result of increases in population and a lack of ecological-self-sufficiency. Currently, construction of another new town is under deliberation, and what should be a major consider is the notion that the new town be located within a wide, green zone. Many studies have revealed that green space can play an important role in improving urban eco-meteorological capability and air quality. In order to analyze the urban heat island which will be created by the new urban development, and to investigate the local thermal environment and its negative effects caused by a change of land use type and urbanization, Landsat TM images were used for extraction of urban surface temperature according to changes of land use over the last 15 years. These data are analyzed together with digital land use and topographic information. As a study result, it was found the urban heat island of the study area from 198.5 to 1999 rapidly developed which showed a difference of mean temperature above 2.0. Before the Bundang new town construction the temperature of the residential area was the same as a forest, but during the new town construction in 1991 analysis revealed the creation of an urban heat island. The temperature of a forest whose size is over 50% of the investigation area was lowest, and thus the presence of a forest is believed to have a direct cooling effect on the urban environment and its surroundings. The mean temperature of the residential and commercial areas in the study was found to be 4.5 higher than the forest, and therefore this part of land use is believed to be the main factor causing the temperature increase of the urban heat island.     

Decomplexation of Cu-1-hydroxyethylidene-1,1-diphosphonic acid by a three-dimensional electrolysis system with activated biochar as particle electrodes

The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10⁻³ and 1.94 × 10⁻⁵ min⁻¹respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H₂O₂ and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed.     

Fe3+催化氧化S(Ⅳ)反应机理初探

通过分析酸性条件下(pH为1～3),Fe3 催化氧化S(Ⅳ)过程中溶液吸光度变化的趋势,对Fe3 催化氧化S(Ⅳ)的反应机理进行了初步推导.实验证明,液相中该反应机理主要是催化氧化与自由基反应相结合,O2的存在对于反应有重要作用,O-2的生成是S(Ⅳ)被氧化的关键;当水中溶解氧接近耗尽时,反应进程发生改变.当Fe3 、S(Ⅳ)浓度增加,自由基生成量增加时,有利于反应进行;作为反应产物,Fe2 、S(Ⅵ)浓度增加,反应推动力减小,反应速率降低;同时Fe2 、SO24-可以与溶液中的其它物质形成配合物,影响了Fe3 -S(Ⅳ)配合物的生成与分解,不利于S(Ⅵ)的氧化.     

人工湿地植物在污水处理系统中的作用探讨

人工湿地污水系统由于具有独特的净化机理和功能而越来越多地被用于处理生活污水和工业废水.湿地植物在人工湿地中起着非常重要的作用,不但可以直接摄取和利用污水中的营养物质、吸收富集污水中的重金属等有毒有害物质;而且还能输送氧气到根区,提供根区微生物生长、繁殖和降解过程中对氧的需求.文章通过详细阐述植物对水中营养元素的吸收作用,说明了植物在人工湿地处理污水中的重要性.     

全自动自适应四边形有限元网格生成/再生成方法与软件AUTOMESH-2D/PC

独立提出并研究开发了一种密度控制和区域分解相结合的四边形网格自动生成方法 ,简称区域分解法。以区域分解法为基础 ,自主开发了商品化网格自动生成 /再生成软件AU TOMESH ,并已经在中国版权保护中心进行了软件著作权登记。介绍区域分解法和软件AU TOMESH ,并给出多个划分实例     

新疆诺尔特地区石炭纪火山岩的成岩机制

诺尔特地区位于阿尔泰北部山区 ,西伯利亚板块西南缘。诺尔特地区石炭纪火山岩赋存于下石炭统红山嘴组中 ,火山岩属钙碱性系列 ,主要是酸性陆相火山岩。火山岩岩浆起源于诺尔特地区中地壳位置 ,成岩物质来源于地壳。痕量元素协变关系、皮尔斯元素比值、元素丰度关系及氧同位素特征的研究表明 ,石炭纪火山岩具有明显的部分熔融成岩机制的特点 ,而结晶分异作用特点不明显 ,无混合作用特点的显示。石炭纪火山岩为部分熔融作用的产物。     

气动絮凝动力学机理探讨及试验分析

对气动絮凝动力学机理进行进一步探讨,并在设定的絮凝条件下,进行试验室小试,分析气动絮凝对浊度、COD等污染指标的去除效果和提高溶解氧的意义,并简单比较了其气动絮凝与机械絮凝的差异。通过机理探讨和试验效果分析,展望气动絮凝方式进行污水强化一级处理的研究方向。