黄泥土不同粒径微团聚体对Cd2+的吸附与解吸研究

对采自太湖地区黄泥土进行了低能量超声波分离,采用平衡吸附法研究了不同粒径微团聚体颗粒对重金属Cd²⁺的吸附和解吸特点.结果表明,不同粒径微团聚体对Cd²⁺的吸附特性均符合Freundlich方程,模拟方程得到的K值介于152～503之间,以粘粒级和粗砂级为最大.微团聚体对Cd²⁺的吸附容量与其中游离氧化铁含量、CEC呈显著正相关.不同微团聚体Cd的解吸特点不同,粘粒级的解吸率仅为8.4%,远远低于其它粒径的微团聚体,这些结果有助于了解田间条件下土壤重金属化学行为和微观尺度的化学过程.     

基于SPA模型的煤矿瓦斯危险源风险评价

根据危险源理论和三类危险源的观点,采用集对分析(SPA)方法,进行了安全一事故集对的同异反分析,指出应采取措施控制不确定项,尤其要控制其中的第二类、第三类危险源才能使系统趋于安全状态;同时建立了煤矿瓦斯危险源风险评价模型,通过联系度的计算得出煤矿瓦斯的安全等级.研究表明,将集对分析方法应用于某煤矿瓦斯危险源风险评价,计算简单,结果较为精确、可靠,为不确定系统的评价提供了一条新思路.     

重金属Cd、Cu对小麦(Triticum aestivum)幼苗生理生化过程的影响及其毒性机理研究

对Cd、Cu单因子处理下小麦幼苗叶片和根系的SOD、POD酶活、可溶性蛋白含量以及叶片中叶绿素含量的变化进行了研究.结果表明,Cd、Cu胁迫下,小麦幼苗受到损伤的明显症状之一是叶片叶绿素含量下降;小麦植株叶片POD、SOD酶活能够被诱导而升高;重金属Cd、Cu对小麦幼苗根系的损伤较叶片大;重金属对小麦幼苗的毒害机理之一是抑制了蛋白质的生物合成;重金属引起的各个生化指标随着处理浓度和处理时间的变化远比有机污染物(如豆磺隆)简单.     

Phytoremediation of Cadmium-Contaminated Soils by Rorippa globosa Using Two-Phase Planting (5 pp)

Background Phytoextraction of contaminated soils by heavy metals can provide a great promise of commercial development. Although there are more than 400 species of hyperaccumulators found in the world, phytoremediation technology is rarely applied in field practice for remedying contaminated soils, partially due to low biomass and long growth duration for most of discovered hyperaccumulating plants. In order to enhance the metal-removing efficiency in a year, the two-phase planting countermeasure of phytoextraction by harvesting anthesis biomass was investigated on the basis of the newly found Cd-hyperaccumulator Rorippa globosa (Turcz.) Thell. with 107.0 and 150.1 mg/kg of the Cd accumulation in stems and leaves, respectively, when soil Cd added was concentrated to 25.0 mg/kg. Methods The field pot-culture experiment was used to observe the distribution property of R. globosa aboveground biomass and to examine characteristics of accumulating Cd by the plant at different growth stages. The concentration of Cd in plants and soils was determined using atomic absorption spectrophotometry (AAS). Results and Discussion The results indicated that the total dry stem and leaf biomass of R. globosa harvested at the flowering phase was up to 92.3% of that at its full maturity and the concentration of Cd in stems and leaves harvested at the flowering phase was up to 73.8% and 87.7% of that at the mature phase, respectively. The Cd-removing ratio by shoots of R. globosa harvested at the flowering phase was up to 71.4% of that at the mature phase. It was also found, by observing the growth duration of R. globosa, that the frostless period at the experiment site was twice as long as the growth time from the seedling-transplanted phase to the flowering phase of the hyperaccumulator. Conclusion R. globosa could be transplanted into contaminated soils twice in one year by harvesting the hyperaccumulator at its flowering phase based on climatic conditions of the site and traits of the plant growth. In this sense, the extraction efficiency of Cd in shoots of R. globosa increased 42.8% compared to that of at its single maturity when the plant was transplanted into contaminated soils after it had been harvested at its flowering phase and the plant accumulated Cd from soil at the same extraction ratio at its second flowering phase. Thus, the method of anthesis biomass regulation by the two-phase planting is very significant to increase the Cd-removing efficiency by phytoremediation used in practice over the course of a year. Recommendation and Outlook As for some hyperaccumulators that the growth duration from the seedling-transplanted phase to the flowering phase are short and the concentrations of heavy metals accumulated in their shoots at the flowering phase are high, the efficiency of phytoremediation can greatly be improved using the method of the two-phase planting.     

pp´DDT and pp´DDE Accumulation in a Food Chain of Lake Maggiore (Northern Italy): Testing Steady-State Condition

- DOI: http://dx.doi.org/10.1065/espr2006.01.010 Background, Aims and Scope Although pp'DDT usage was strongly limited or banned in most parts of the world during the last three or four decades, the parent compound, its homologues and their metabolites still occur at levels which might pose a risk for many ecosystem components. A case of DDT pollution of industrial origin was discovered in 1996 in Lake Maggiore, the second largest (212 km2) and deepest (370 m) lake in Italy, causing concern for wildlife and human health. The extensive monitoring of many biotic and abiotic compartments which followed from 1998 in order to assess the pollution level and its trend in time, provided a great availability of data referring to DDT contamination of the different fish species of the lake. In this study, the recent contamination levels in selected fish species were compared to those measured in 1998 to evaluate the temporal pollution trend of the lake and its natural recovery, given that no remediation measures were carried out on the contaminated soils and sediments in this time span. Moreover, a modelling approach to test the equilibrium condition between water and pelagic fish species was used. Analytical results of pp'DDT and pp'DDE concentrations in lake water were used as input data in the bioenergetic model by Connolly & Pedersen (1988) to calculate concentrations in two fish species and to compare the predicted and the measured contamination. Methods Sampling and analytical determination of DDT homologues in lake water: Five water sampling campaigns were carried out from May 2002 to February 2004 in three sampling sites of Lake Maggiore. Suspended and dissolved pollutants were determined separately. Quantitative DDT homologue analyses were performed by HRGC coupled with ECD detection by the external standard method. Single water extracts were put together in correspondence with the stratification zones of the water column inferred on the basis of the temperature profile to improve analytical sensitivity. Selection of fish data: Concentrations of DDT and DDE in fishes were selected from recent literature (CIPAIS 2003, 2004). Bioaccumulation model: The bioenergetic model proposed by Connolly & Pedersen (1988) was used to assess the bioaccumulation of pp'DDT and pp'DDE of Alosa fallax (landlocked shad) and Coregonus spp. (whitefish), selected among the different species as representative of a secondary consumer level. Results and Discussion The average concentrations of pp'DDT and pp'DDE in water to be used as input data in the bioenergetic model were obtained considering all the concentrations measured at the three sampling stations in the epylimnion where the fish species considered in this study spend most of their life. The resulting values were 0.05 and 0.16 ng/L for pp'DDT and pp'DDE, respectively. Average measured pp'DDT and pp'DDE concentrations in landlocked shad were 0.81 +/- 0.39 and 1.69 +/- 0.71 mg/kg lipids, respectively, and were 0.29 +/- 0.12 and 1.06 +/- 0.41 mg/kg lipids for the whitefish. Calculated and measured values turned out to be in quite good agreement for pp'DDT, while measured pp'DDE concentrations were higher than expected on the basis of the bioenergetic model in both species. Probably metabolic transformations of pp'DDT accumulated in fish tissues in the past are responsible for the observed differences between calculated and expected pp'DDE concentrations in fish. Conclusions Pelagic fishes of Lake Maggiore seem to maintain the DDT accumulated during their life time and the most efficient mechanism responsible for the fish population recoveries is probably their generation changes; for this reason, equilibrium models cannot be used until negligible pp'DDT concentrations are reached in fish tissues. Recommendations and Outlook The limit proposed for pp'DDT in water by the EU Directive 2000/60, which will come in force in 2008, is 0.2 ng/L, four times higher than the average concentration measured in Lake Maggiore waters. Nevertheless, concentrations measured in Lake Maggiore fish were very close and sometimes exceeded the Maximum residue limits (MRLs) settled by the Italian legislation for foods (0.1 mg/kg w.w. for fish containing 5–20% lipid). It seems, therefore, that the 'environmental quality standard' of 0.2 ng/L cannot guarantee the suitability of fish for human consumption.     

五种重金属在小麦植株不同器官中的分布特征

为研究Cd、Pb、As、Cu、Zn等5种重金属在小麦植株不同器官的分布特征，以郑州9023为供试品种，采用田间试验方法，应用原子吸收分光光度法和电感耦合等离子体原子发射光谱法(ICPS)分别测定了小麦植株不同器官的重金属质量分数并进行了分析。结果表明，小麦植株中较易富集Cd的器官是根、叶及废弃物，较易富集Pd、As的器官是根、茎及废弃物，较易富集Zn、Cu的器官是根、茎和籽粒；在这5种重金属中，Zn在小麦茎和籽粒中的富集系数最高，Cd在地上部分其他器官的富集系数最高，而Pb在这些器官中富集系数均为最低，Cu和As则居中。     

油库泵站可燃气体智能型安全检测系统

根据目前油库泵站内存在可燃气体经常泄漏的实际情况,提出并应用计算机信息处理系统解决可燃气体泄漏监控问题。     

江苏沿江开发研究

随着中国加入WTO和经济全球化进程的加快,长江三角洲以其独特的滨江临海的区位和发达的制造业基础,正在成为新的投资热点地区。江苏省沿江地区是长江三角洲重要的组成部分,拥有800多km的长江岸线和8个经济发达、人才资源优势明显的经济中心城市。传统的制造业基础和相对低廉的加工成本、商务成本,使江苏沿江开发既有对外来资本的吸引力,又有自我发展的内生机制。重点研究了全球化背景下江苏沿江开发的战略问题,主要包括：①江苏沿江地区开发的环境和条件比较分析;②沿江产业带重组与实施跨江开发;③再造新战略据点;④打破行政区界限沿江联动实施区域一体化,等等。最后指出：加快江苏沿江开发,必须科学规划、统筹安排,做到空间合理、时间有序,同时考虑沿江的环境容量有限,应实施可持续发展和南北联动的开发战略,拓展沿江的开发空间,提升沿江的产业发展水平。     

武钢签订安全生产目标责任状制度概述

概略地分析了武钢安全生产目标责任状制度的内容、作用和目的 ,以及实施和管理该责任制的一些主要做法、措施。通过实施签订安全生产目标责任状制度 ,促使各级领导、各部门落实安全生产责任制 ,取得了成效 ,确保了安全生产     

多泥沙河流水质模型研究

针对黄河泥沙含量大、泥沙对河流CODMn浓度影响大的突出特点,运用模拟实验方法,探讨了泥沙对CODMn浓度的影响,揭示了浑水、清水中CODMn浓度与含沙量间的关系.研究表明,黄河浑水中CODMn浓度随含沙量增大呈显著上升趋势,而去除泥沙后清水CODMn浓度测定值随其原含沙量增大呈微上升趋势.依据质量平衡原理,建立了充分考虑泥沙影响的CODMn衰减经验模型.清水中CODMn浓度的变化采用完全混合反应器概念来模拟,浑水中CODMn浓度通过清水中CODMn浓度与泥沙中CODMn浓度之和来量化.模型基本方程的求解采用稳态解析解.模型中的参数通过利用实际监测数据及室内实验结果与优化结合的方法确定.同时,利用实际监测数据对参数和模型进行检验.结果表明,模型结构合理,参数取值可靠,模型精度较好.模型既能揭示汇流区间人为污染对河段水质的影响,又可以反映作为面污染源的黄河泥沙对污染的影响,可作为水质预测的实用工具及规划管理的依据.