Determination of Heavy Metals in Honey in Kahramanmaraş City, Turkey

Heavy metals in honey are of interest not only for quality control, but also for determination environmental contamination. The objective of this work was to determine distribution of the levels of selected heavy metals. Levels of copper (Cu), cadmium (Cd), manganese (Mn), Iron (Fe), magnesium (Mg) and nickel (Ni) in honey samples (21) in Kahramanmaraş region were determined by atomic absorption spectrometer (AAS). The mean values for Cu, Cd, Mn, Fe, and Mg were 0.01, 0.32, 0.03, 0.36 and 10.45 ppm, respectively. Nickel was not detected in honey samples. Kahramanmaraş honey samples were not free of heavy metals but the levels of them were found well below the permitted levels. The results suggested that honey may be useful for assessing the presence of environmental contaminants.     

Biomonitoring heavy metals in estuaries: a field comparison of two brown algae species inhabiting upper estuarine reaches

Biomonitoring dissolved heavy metals within estuaries,particularly at their upper reaches, frequently has to relyon several biomonitors; rarely a single species thrives allalong the salinity gradient. To properly do so, it must beestablished whether those biomonitors actually accumulateheavy metals alike. In this study, two brown seaweeds fromthe upper section of three NW Spain estuaries – the widely-known Fucus vesiculosus and the estuarine Fucusceranoides – were compared as metal biomonitors. Bothspecies were collected at five locations where they eithercoexist or live close to each other and their heavy metalcontent (Cu, Cr, Mn, Zn, Fe, Al) was measured. Analyseswere appropriately replicated for each species x locationcombination to allow a statistically reliable detection ofdifferences in bioaccumulation, with particular emphasis onthe magnitude of interspecific differences. The lack of significant differences for Cu, Mn, and Zncontents in F. ceranoides and F. vesiculosussupports the feasibility of their joint use to monitorthese metals along the estuaries. Conversely, F.ceranoides concentrated significantly higher levels of Cr,Fe, and Al than F. vesiculosus and hence combiningdata for both fucoids to monitor these elements seemsimpractical. The correlation of species differencestogether with a similar Al:Fe ratio in both weed tissue andsediment suggest that Cr, Fe, and Al tissue-burdens mightbe considerably biased by sediment retained on the surfaceof the weed. Parallel analyses of Al and/or Fe in seaweedsand sediments could serve to keep track of thisinterference and may help to combine data from both fucoidsfor monitoring elements like Cr.     

Cadmium and Lead Levels in Fish (Tilapia Nilotica) Tissues as Biological Indicator for Lake Water Pollution

Cadmium and lead were determined in different tissues (muscle,gill, stomach, intestine, liver, vertebral column and scales) of Tilapia nilotica from the High Dam Lake, Aswan (Egypt) to assess the lake water pollution with those toxic metals. Fish samples were chosen from different ages and weights to be analyzed along with samples of the aquatic plant(Najas armeta), sediment and lake water.The results showed that cadmium and lead concentrations were higher in fish scales and vertebral column than in the other parts of the fish. Cadmium and lead levels in High Dam lake water and fish (Tilapia nilotica) were a result of the pollution which uptakes from aquatic plants, sediments andgasoline containing lead that leaks from fishery boats. Tilapia nilotica fish was used as a good bio-assay indicator for the lake pollution with cadmium and lead. The fish musclesin this study were in the safety baseline levels for man consumption.     

Mulberry-silkworm food chain--a templet to assess heavy metal mobility in terrestrial ecosystems

Assessment of the food chain mobility of heavy metals inthe natural ecosystem receives more attention nowadays. Inthe present study, mulberry-silkworm food chain has beenfocused as a templet to assess the biomobility of heavymetals in soil-higher plant-insect hierarchy. Both in thecase of Cd and Cu treatments, higher mobility wasobserved in the level-1 (soil–root) followed by level-3(leaf–larva), level-4 (larvae–faecal) and level-2(root–leaf). Consequently, roots accumulated more amountsof Cd and Cu, with a limited transport to the leaves.Among the two metals (Cd and Cu) tested, in the plant,the transfer potential of Cd exceeds that of Cu. Whereasin the case of leaf–larval transfer, Cu precedes overCd. Accumulation of Cd and Cu in all the levels (1–4)tested showed a concentration dependent increase, except inthe level 4 (larva–faecal) of Cd treatment where adeclining trend was noticed.     

Modeling rhizofiltration: heavy-metal uptake by plant roots

The discovery of phytoaccumulation potential of plant species has led to its application for remediation of heavy-metal-contaminated soil and wastewater, which is termed as phytoextraction/rhizofiltration. For prediction, analysis, planning and cost-effective design of such systems, mathematical models not only are used as a screening tool but also provide optimal parameters like harvesting time, irrigation schedule, etc. Several laboratory and field scale studies have been carried out in the past, and mathematical expressions have been developed by various researchers for different phenomena like metal adsorption in soil, plant root growth with time, moisture and metal uptake by plant root, moisture movement in unsaturated zone, soil moisture relationship, etc. The complete design of any such phytoremediation program would require the knowledge of behavior of heavy-metal movement in soil, water and plant root system. In this paper, a model for simulating heavy-metal dynamics in soil, water and plant root system is developed and discussed. The governing non-linear partial differential equation is solved numerically by implicit finite difference method using Picard's iterative technique, and the formulation has been illustrated using a characteristic example. The source code is written in MATLAB.     

消泡剂硅油I在工业废水氨氮测定中的应用

对色泽较深，含杂质量较高的废水加硅油I以抑制测定中蒸馏产生的泡沫．结果表明，在250ml水样中加硅油IO．10～1．25ml，即可收到理想效果．硅油I性质稳定，不随水蒸汽蒸出，对测定无干扰．     

Assessment of the Heavy Metal Pollution Effects on the Soil Respiration in the Baix Llobregat (Catalonia, NE Spain)

A main goal of investigations is to determine could a soilrespiration be an indicator of the soil pollution. In this case a measured levelof the soil oxygen consumption depends of its pollution. It alsomeans that the pollution reduces biological processes in edaphon.Investigated soil samples were taken from polluted andnon-polluted places in the Baix Llobregat near Barcelona (Catalonia, NE Spain). Soil samples were taken from the top ofsoil (0–5 cm) without a litter. Soil analysis were done, determining percentage shares of coarsefragments, coarse sand, fine sand, coarse silt, fine silt, clay,CaCO₃, organic matter as well as water pH and conductivityCE (1:5 [mS cm^-1]). Also were determined (in mg kg^-1)quantities of heavy metals, as Fe, Al, Mn, Zn, Cr, Ni, V, Cu, Cd, Pb.The soil respiration was investigated in temperatures15 and 30 °C and with controlled humidity.The respiration in 30 °C is number of times greater thenin 15 °C both for polluted and non-polluted soils.Particularly high coefficients of correlation between the soilrespiration and soil pollution in polluted soils were obtainedfor Pb: r = 0.75 in 15 °C and r = 0.98 in30 °C; for Ba: 0.90 and 0.57; for V: 0.99 and 0.81. In non-polluted soils highest correlation coefficients are for Pb: r = 0.70 in 15 °C; Fe: 0.60 and 0.72; Al: 0.68 and0.64; Mn: 0.51 and 0.66; Ba: 0.63 and 0.61; Cr: 0.94 and0.70; Ni: 0.64 and 0.65; Cu: 0.69 and 0.48; as well as V: 0.62in 15 °C; and Cd: 0.69 in 15 °C.This way the soil respiration could be a good indicator of the soil pollution.     

Aliphatic and polycyclic aromatic hydrocarbons in sediments of Kaohsiung Harbour and adjacent coast, Taiwan

Surficial sediment samples collected from Kaohsiung Harbour and its nearby coast were analyzed for aliphatic hydrocarbons and parent polycyclic aromatic hydrocarbons (PAHs). According to our results, the average total concentrations of n-alkanes (n-C₁₂ to C₃₅) and aromatics (15 PAHs) were 4.33 µg g^–1 dry weight (ranged 0.46–22.60) and 0.59 µg g^–1 dry weight (ranged 0.09–1.75), respectively. The highest concentrations of aliphatic and aromatic hydrocarbons were recorded in stations near the estuaries of Qianzhen River and Love River, respectively. Aliphatic hydrocarbons in the samples indicate that there has been significant non-petrogenic, possibly terrestrial, contribution in the sediment of the open coast of Kaohsiung Harbour and that there has been dominant contribution from petrogenic sources in the sediment of the inner harbour. PAHs, detected in the samples, however, indicated a higher pyrolytic contribution in open-coast samples and a higher petrogenic contribution in the inner harbour. Overall, sediment concentrations of total alkanes in this study were comparable to those found in Victoria Harbour, Hong Kong and are higher than those found in Xiamen Harbour, China. Concentrations of total PAHs in inner Kaohsiung Harbour sediments were relatively lower than those found in Victoria Harbour, Hong Kong and Xiamen Harbour, China, but comparable to those found in Hsin-ta Harbour, Taiwan and Incheon Harbour, Korea. In comparison with several effect-based sediment quality guidelines, most PAH concentrations found in samples taken from inner harbour stations exceeded the Threshold Effect Level of Florida indicating a slight possibility of adverse effects.     

Heavy metals in water bodies purified by suspended substrate of rivers

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