全文获取类型
收费全文 | 377篇 |
免费 | 39篇 |
国内免费 | 160篇 |
专业分类
安全科学 | 25篇 |
废物处理 | 46篇 |
环保管理 | 21篇 |
综合类 | 251篇 |
基础理论 | 128篇 |
污染及防治 | 68篇 |
评价与监测 | 37篇 |
出版年
2023年 | 7篇 |
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 11篇 |
2017年 | 17篇 |
2016年 | 20篇 |
2015年 | 36篇 |
2014年 | 25篇 |
2013年 | 63篇 |
2012年 | 37篇 |
2011年 | 20篇 |
2010年 | 25篇 |
2009年 | 20篇 |
2008年 | 22篇 |
2007年 | 22篇 |
2006年 | 36篇 |
2005年 | 34篇 |
2004年 | 16篇 |
2003年 | 21篇 |
2002年 | 15篇 |
2001年 | 31篇 |
2000年 | 8篇 |
1999年 | 7篇 |
1998年 | 9篇 |
1997年 | 10篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有576条查询结果,搜索用时 218 毫秒
231.
生物矿化针铁矿吸附铬的机理探讨 总被引:4,自引:0,他引:4
针铁矿在自然界中广泛存在,对重金属离子在地表的迁移和转化有重要影响.利用天然生物矿化针铁矿进行了Cr(Ⅲ)吸附研究,并利用扫描电子显微镜(SEM)和X射线光电子能谱(XPS)等对吸附后的样品进行表征,发现样品中铬的含量随着Al2O3含量的增加而增加,说明表面带负电荷的含高岭土等的粘土较针铁矿对Cr(Ⅲ)有更强的吸附能力.样品的XPS研究表明,NO3-也参与了反应,且促进了Cr(Ⅲ)的氧化.研究还发现,Cr(Ⅲ)在针铁矿上的吸附不均匀,与文献报道的情况不同. 相似文献
232.
233.
234.
用二氧化硫处理含铬废水 总被引:7,自引:2,他引:5
采用二氧化作还原剂,处理高浓度大流量含铬废水,除铬效果良好,进水中产价铬含量为90.0-430.8mg/L时,经还原,沉淀处理后,出水中六价铬含量均可达到排放标准,该工艺基本上实现了二氧化硫的闭路循环,排放尾气中二氧化硫含量〈15mg/L。 相似文献
235.
236.
Herpin U Siewers U Markert B Rosolen V Breulmann G Bernoux M 《Environmental science and pollution research international》2004,11(1):57-66
This paper shows the geographic distribution in Germany of iron (Fe), nickel (Ni) and lead (Pb) analyzed in mosses in 1995/96 and compares it with the results of the 1990/91 pilot study within a European moss-monitoring programme. Other elements (As, Cd, Cr, Cu, Ti, V, Zn) are compared on basis of the overall element medians for Germany of the 1990/91 and 1995/96 survey. Samples of Pleurozium schreberi, Scleropodium purum, Hypnum cupressiforme and Hylocomium splendens were taken at a total of 1026 sites. In the 1995/96 monitoring campaign, 95% of the original sites of the 1990/91 study were resampled. The results from 1995/96 display local elevated values and many cases of areas affected by known sources of heavy-metal emissions. The industrialized and urban regions of Germany are shown up clearly by the 1995/96 moss-monitoring results: the Ruhr area, parts of Saarland and Baden-Württemberg, as well as areas in eastern Germany. Relatively low values for many elements were found in large areas of Lower Saxony and Bavaria. A comparison of the results of the 1990/91 and 1995/96 moss-monitoring programmes shows a fall in the concentration of the presented elements (except cadmium, copper and zinc) over the relevant period. Especially in the former GDR, chromium (Cr), iron (Fe), titanium (Ti) and vanadium (V) decreased significantly. This is, firstly, a reflection of the closure of and/or technological improvements to large power plants; secondly it is due to the fact that lignite has given way to other fuels. Vanadium (V) and nickel (Ni), typical constituents of crude oil, also show a decrease in the western part and thus document changes in the type of fuel consumed. The significant fall in lead concentration in 1995/96 as compared to 1990/91 in what used to be East and West Germany probably results from the increasing use of lead-free petrol. A comparison of the median values for 1990/91 and 1995/96 in mosses to the rate of emission of heavy metals in Germany for 1990 and 1995 shows similar trends in the case of elements such as arsenic (As), chromium (Cr), nickel (Ni), and lead (Pb). The comparison of the medians of the elements analyzed for 19 European countries indicates for most of the elements a general tendency to lower values in 1995, except for Lithuania, Netherlands, Portugal, Italy and United Kingdom. 相似文献
237.
通过Cr6 和Cr3 对水花生 (Alternantheraphiloxeroides)的叶及根的某些生理生化指标影响的对比研究发现 ,Cr6 和Cr3 均能对水花生产生毒害 ;铬污染后 ,水花生的叶绿素含量、超氧化物歧化酶 (SOD)、过氧化物酶 (POD)、过氧化氢酶 (CAT)活性和可溶性蛋白含量 5项重要生理生化指标发生相应变化 ;Cr6 的毒性明显大于Cr3 ,根的受害程度比叶严重。 相似文献
238.
ABSTRACTNatural polymer Moringa oleifera seed as coagulant and bentonite clay as adsorbent were used for preparing novel composite coagulant. Results obtained from FTIR, SEM, TEM and P-XRD show that the bentonite clay and M. oleifera seed biopolymers physico-chemically interact with each other during the preparation of clay-polymer composite. The FTIR results show that the major functional groups present in bentonite clay and M. oleifera seed are integrated at nano levels in the novel composite to remove heavy metals from aqueous systems. The coagulo-adsorption using clay-polymer composite may be used for the adsorption of heavy metals ions from the aqueous systems. It becomes possible due to the structural characteristics of the clay crystallites together with the functional attraction of the biopolymer and it results in the formation of clay-polymer metal complexes. The clay-polymer nano-composite of M. oleifera seed and bentonite clay showed considerable cadmium, chromium and lead removal property. 相似文献
239.
Huijing QIAN Yanjun WU Yong LIU Xinhua XU 《Frontiers of Environmental Science & Engineering in China》2008,2(1):51-56
The kinetics of Cr(VI) reduction to Cr(III) by metallic iron (Fe0) was studied in batch reactors for a range of reactant concentrations, pH and temperatures. Nearly 86.8% removal efficiency
for Cr(VI) was achieved when Fe0 concentration was 6 g/L (using commercial iron powder (< 200 mesh) in 120 min). The reduction of hexavalent chromium took
place on the surface of the iron particles following pseudo-first order kinetics. The rate of Cr(VI) reduction increased with
increasing Fe0 addition and temperature but inversely with initial pH. The pseudo-first-order rate coefficients (k
obs) were determined as 0.0024, 0.010, 0.0268 and 0.062 8 min−1 when iron powder dosages were 2, 6, 10 and 14 g/L at 25°C and pH 5.5, respectively. According to the Arrehenius equation,
the apparent activation energy of 26.5 kJ/mol and pre-exponential factor of 3 330 min−1 were obtained at the temperature range of 288–308 K. Different Fe0 types were compared in this study. The reactivity was in the order starch-stabilized Fe0 nanoparticles > Fe0 nanoparticles > Fe0 powder > Fe0 filings. Electrochemical analysis of the reaction process showed that Cr(III) and Fe(III) hydroxides should be the dominant
final products. 相似文献
240.
草酸青霉SL2对高浓度铬污染土壤的生物淋洗及胞内铬形态转化研究 总被引:1,自引:0,他引:1
铬渣无序堆存造成的铬污染土壤迫切需要修复治理.本文以新筛选的功能微生物草酸青霉SL2(Penicillium oxalicum SL2)为材料,以重度铬污染土壤为研究对象,进行生物淋洗技术优化,并利用软X射线扫描透射显微光谱技术(STXM)及同步辐射X射线近边吸收结构谱学(XANES)分析淋洗后的草酸青霉SL2胞内铬空间分布化学形态.结果表明:分步处理并进行水洗预处理可明显提高草酸青霉SL2对高浓度铬污染土壤的总铬TCr淋出率(49.4%),淋出液中Cr(VI)在3 d内全部被还原;生物淋洗后,草酸青霉SL2胞内吸收累积了Cr(VI),部分被还原为Cr(III),两个价态的Cr在空间分布上具有一定的一致性;胞内铬形态主要为磷酸铬、草酸铬钾及半胱氨酸铬类化合物,其含量分别为46.9%、33.0%和20.1%. 相似文献