全文获取类型
收费全文 | 377篇 |
免费 | 39篇 |
国内免费 | 160篇 |
专业分类
安全科学 | 25篇 |
废物处理 | 46篇 |
环保管理 | 21篇 |
综合类 | 251篇 |
基础理论 | 128篇 |
污染及防治 | 68篇 |
评价与监测 | 37篇 |
出版年
2023年 | 7篇 |
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 11篇 |
2017年 | 17篇 |
2016年 | 20篇 |
2015年 | 36篇 |
2014年 | 25篇 |
2013年 | 63篇 |
2012年 | 37篇 |
2011年 | 20篇 |
2010年 | 25篇 |
2009年 | 20篇 |
2008年 | 22篇 |
2007年 | 22篇 |
2006年 | 36篇 |
2005年 | 34篇 |
2004年 | 16篇 |
2003年 | 21篇 |
2002年 | 15篇 |
2001年 | 31篇 |
2000年 | 8篇 |
1999年 | 7篇 |
1998年 | 9篇 |
1997年 | 10篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有576条查询结果,搜索用时 328 毫秒
41.
42.
Uptake of Chromium by Trees: Prospects for Phytoremediation 总被引:3,自引:0,他引:3
43.
44.
The in vivo toxic impact of chromium in its two forms(trivalent and hexavalent) on glycogen metabolism in the tissuesof freshwater field crab Barytelphusa guerini was studied.In a sublethal long-term exposure of 30, 60 and 90 days, thedepletion of glycogen and glucose levels reflected in theactivity of glycogenphosphorylases `a' and `ab'. A tissuespecific and time-dependent variation in tissue glucose reservesparelleled the progressive accumulation of haemolymph sugars.Trivalent and hexavalent chromium induced alterations in metabolite levels and in enzyme activities in the tissues. Themagnitude of responses were found more in the hexavalent formthan in trivalent form. 相似文献
45.
Caroline Michel Marie-Thérèse Giudici-Orticoni Frauke Baymann Mireille Bruschi 《Water, Air, & Soil Pollution: Focus》2003,3(3):161-169
The treatment of soils and ground waters polluted by heavy metals is of economical and environmental interest. Reduction of Cr(VI) to the less toxic Cr(III) associated to its precipitation is a potentially useful process for bioremediation. In order to develop ecological processes using micro-organisms, we have compared various sulfate-reducing bacteria for enzymatic reduction of chromate. The best Cr(VI) reductase activity was obtained with Desulfomicrobium norvegicum. Despite morphological changes induced by the presence of chromate, this strain can grow in the presence of up to 500 M Cr(VI) and can decontaminate waters polluted by Cr(VI) when seeded in bioreactors. We have demonstrated the ability of several metalloenzymes (cytochromes c
3 and hydrogenases) to reduce chromate. Biophysical investigations of the chromate/protein interaction in order to get further informations on the mechanism of metal reduction by cytochromes c
3 are under the way. 相似文献
46.
William G. Wilber Joseph V. Hunter 《Journal of the American Water Resources Association》1979,15(3):790-800
ABSTRACT: A three-year study has been conducted on a 4.6 mile stretch of the Saddle River near Lodi, New Jersey. The primary objectives of this investigation were (1) to provide baseline information on the concentration and distribution of heavy metals in bottom sediments of the Saddle River; (2) to qualitatively evaluate which parameters affect this distribution; and (3) to determine the effect of urbanization on the concentration and distribution of these materials. Significant enrichments of several heavy metals were observed in bottom sediments of the lower Saddle River near Lodi, New Jersey, as compared to the upper Saddle River. Attempts to correlate metal concentrations in bottom sediments with chemical-oxygen demand were not successful in demonstrating a relationship between these two factors. Metal concentrations were found to be strongly dependent upon particle size. In general, metal concentrations in bottom sediments increased with decreasing partical diameter. However, metals enrichment was observed to be considerably greater in the larger sediment fractions studied (>420μ) than the smaller sediment fractions as one proceeded downstream through the urban area. Since the larger sediment fractions are least effected by scour and transport they may best reflect the effect of urbanization on the distribution of heavy metals over an extended period of time at a given location. 相似文献
47.
本文研究了皮革铬鞣废水中铬的定性特征曲线。利用吸光度加合定律对大量实测数据进行统计处理。建立测定铬的实验室校准直线方程,相关系数γ=0.9960.以此作为测定铬鞣废水及回收铬渣中铬量的实验室回归直线方程。并对本法的可靠性进行研究,结果令人满意。本法不仅大大简化了铬量测定的步骤.而且在提高分析效率的同时获得同等的检测结果。 相似文献
48.
《Chemistry and Ecology》2007,23(5):409-425
The use of a new sorbent developed from the husk of pomegranate, a famous fruit in Egypt, for the removal of toxic chromium from aqueous solution has been investigated. The batch experiment was conducted to determine the adsorption capacity of the pomegranate husk. The effects of initial metal concentration (25 and 50 mg l-1), pH, contact time, and sorbent concentration (2-6 g l-1) have been studied at room temperature. A strong dependence of the adsorption capacity on pH was observed, the capacity increased as the pH decreased, and the optimum pH value was pH 1.0. Adsorption equilibrium and kinetics were studied with different sorbent and metal concentrations. The adsorption process was fast, and equilibrium was reached within 3 h. The maximum removal was 100% for 25 mg l-1 of Cr6+ concentration on 5 g l-1 pomegranate husk concentration, and the maximum adsorption capacity was 10.59 mg g-1. The kinetic data were analysed using various kinetic models—pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion equations—and the equilibrium data were tested using several isotherm models, Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich, and Generalized isotherm equations. The Elovich and pseudo-second-order equations provided the greatest accuracy for the kinetic data, while Langmuir and Generalized isotherm models were the closest fit for the equilibrium data. The activation energy of sorption has also been evaluated as 0.236 and 0.707 kJ mol-1 for 25 and 50 mg l-1 chromium concentration, respectively. 相似文献
49.
50.
Simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions, coupled with photocatalytic oxidation of sodium dodecyl benzene sulfonate (SDBS) were studied with a trace amount of commercial titania nanoparticles and by means of a direct-photo-irradiation reactor. The co-presence of metal ions and SDBS causes metal ions reduction as well as SDBS oxidation to enhance and energy efficiency to improve. XRD, XPS and FTIR analysis were used to characterize TiO2 particles before and after usage with the aim of evaluating the mechanism of reactions. The effect of major operating parameters, pH and temperature, was investigated. Under conditions of [Cr(VI)]0 = [Ni(II)]0 = 5 mg/L, [SDBS]0 = 10 mg/L, [TiO2] = 40 mg/L, pH 6 and T = 35 °C; the removal efficiencies of 55.4%, 71.2% and 57.2% were obtained, respectively, for Cr(VI) and Ni(II) reduction, as well as for SDBS oxidation, after 110 min operation. The relevant kinetic model jointed with the Arrhenius equation was introduced. Pseudo-first-order reactions are relevant. Energy consumption (electrical and thermal) evaluations revealed that operations at higher temperatures provide significant cost reduction. Meantime, a criterion was proposed for a consistent assessment of this kind of processes. 相似文献