钠盐量影响下DD6单晶高温合金的高温热腐蚀规律研究

目的 开展镍基单晶高温合金DD6在950 ℃下的热盐腐蚀试验(95%Na2SO4+5%NaCl)，探明涂盐量和涂盐方式(周期涂盐和单次涂盐)对DD6高温热腐蚀的影响规律和机理。方法 结合扫描电子显微镜、X射线能量色散谱、X射线衍射等设备，对不同涂盐量及涂盐方式下DD6的表面及横截面形貌进行观察分析，分析不同涂盐量和涂盐方式下DD6的高温热腐蚀机理。结果 DD6在950 ℃下主要发生碱性熔融热腐蚀，同时伴随氧化、硫化和氯化等过程。高温热腐蚀使得DD6合金表面生成的保护性氧化膜被熔融态的腐蚀介质破坏，导致O、S、Cl等外部元素通过氧化膜的缺陷进入DD6基体中，在合金的亚表面发生内氧化、内硫化以及内氯化反应，横截面上出现明显的腐蚀层，其主要由氧化物以及硫化物组成。随着热腐蚀的进行，DD6表面物质发生了剥蚀，沉积盐量的增加导致剥蚀现象越加严重，合金内部致密的组织结构也被破坏，横截面上出现了大量孔洞、裂纹等缺陷。在相同涂盐量下，周期涂盐法使得DD6的腐蚀程度高于单次涂盐法。结论 DD6高温热腐蚀行为与涂盐量及涂盐方式密切相关，相同涂盐方式下，涂盐量越大，DD6热腐蚀更加严重。涂盐量一定时，周期涂盐法使得DD6的热腐蚀剧烈程度大于单次涂盐法，且DD6在上述热腐蚀条件下均发生剥蚀破坏。     

云南昌宁玉地里温泉水文地球化学特征及形成模式

以水化学及同位素技术为基础,对昌宁县玉地里温泉的地质及地热特征进行了研究,并取得了一些重要的认识.通过对比研究该温泉地下热水1980年和2012年的水文地球化学数据,发现经过30多年的循环演化,其水化学类型仍为HCO3-Na型.δD和δ18O同位素为该温泉首次获得,数据显示地下热水具有现代大气降水的氢氧同位素组成特征,属断裂带对流型深循环低温地下热水系统,其补给源区位于东部和南部山区,热储层和盖层的构造及岩性特征与地下热水的深循环和化学组成有着密切联系.     

武汉市耕地非农化的空间自相关分析

经济发展和城市扩张使包括耕地在内的大量开放空间被不断侵蚀,随着人们对耕地非市场价值和生态功能认识的不断加深,如何合理高效可持续地利用耕地被广泛关注。采用空间自相关分析方法从乡镇尺度定量研究了武汉市耕地非农化的空间关系,以探讨快速发展时期平原城市耕地非农化空间关系的变化及其原因。研究表明:(1)全局Morans I显示武汉市耕地非农化在1990~2011年的4个时期均呈现出显著的全局空间自相关,其聚集强度以2005年为分界点,前3个时期不断加强后有所下降;(2)通过EB修正的武汉市耕地非农化的LISA图显示武汉市耕地非农化的聚集区域由开始处于区域外围的LL型聚集为主导逐步转变为处于城乡交错区域的LH+HH型聚集为主导;(3)通过绘制不同时期不同聚集类型的重心移动路径可以发现LH+HH型聚集均出现先向东南再向东北移动的趋势,这种耕地非农化趋势与区域的产业布局有密切关系。通过空间自相关分析掌握武汉市耕地非农化的空间特征是开展耕地保护和实现耕地合理利用的基石,根据研究结果可以确定重点和优先管制区域以提升土地利用管制效果,协调好城市建设和耕地资源保护间的关系。     

中国省际碳排放效率的空间计量

本文基于至强有效前沿的最小距离法测算了我国1998-2011年的省际CO2排放效率,这种方法的优点是效率达到生产前沿后在投入或产出方面所做出的改动最小。然后在此基础上分析了我国省际碳排放效率的区域差异性以及空间相关性,最后运用1998-2011年我国30个省份的面板数据,建立空间面板数据模型,对我国碳排放效率的影响因素进行了实证研究。研究结果表明:样本期内,我国省际碳排放效率表现出较大的省际差异性,东部沿海省份的平均碳排放效率显著高于内陆省份。分地区看,东部地区的碳排放效率走势相对平稳,全国及中西部地区的碳排放效率则呈现出"U"型曲线的走势,并且东部地区的碳排放效率明显要高于中西部地区;空间自相关Moran’s I检验显示,省际碳排放效率在空间上存在着显著的空间自相关性,具有明显的集群趋势,而空间LISA图则表明省际碳排放效率不仅具有空间依赖性的特征,同时也有空间异质性的表现;经济规模、工业结构和能源消费结构对碳排放效率造成了较大的负面影响,对外开放、企业所有制结构以及政府干预对碳排放效率有正向影响,而产业结构对碳排放效率的影响则不显著。因此,对于将来中国提高碳排放效率工作的重点应该是实现经济增长模式由粗放型向集约型的转变,着重调整工业结构和能源消费结构,同时进一步提升对外开放的质量,加强政府的碳减排工作力度。     

如何保证热水锅炉的安全运行

针对热水锅炉的特点,阐述了如何保证热水锅炉的安全运行.     

Environmental assessment of dehydrated alfalfa production in Spain

Alfalfa is the major forage crop produced in temperate regions worlwide. Although this crop is currently used mainly for producing high-value livestock feed, its application for bioenergy production is a recent focus of interest. Even though it is not mandatory, alfalfa is normally dried in order to improve the quality of the final product. In this study, Life Cycle Assessment (LCA) was used to quantify the environmental impacts linked to alfalfa production in the major cultivation zone in Spain (Ebro Valley), including field activities, dehydration and transport to farms for livestock feeding. In addition, the identification of the most relevant processes contributing to the environmental impact and the potential improvements actions were also defined as objectives. Inventory data were obtained mainly from interviews with farmers complemented with published literature and comments from experts.LCA results were obtained for global warming, acidification, eutrophication, photochemical oxidant formation, land use, non-renewable cumulative energy demand and human, terrestrial and aquatic ecotoxicities. Within the life cycle of alfalfa, the dehydration process, production of phosphate fertilizer, application of nitrogen fertilizers and pesticides, water consumption and final transport to the consumer (by road and ship) were identified as hot spots. Based on these, some improvement measures were proposed and evaluated: (i) reduction of the moisture content of alfalfa and the use of a higher percentage of biomass for combustion in the dehydration process, (ii) no application of nitrogen fertilizer in maintenance years and (iii) use of more efficient trucks for transport. Their implementation would produce significant reduction of eutrophication, global warming, acidification, non-renewable cumulative energy demand and, to a lesser extent, photochemical oxidation formation and human toxicity impacts.     

中国的太阳能资源及应用潜力

太阳能资源被认为是21世纪最引人注目的可再生能源和洁净能源，为了经济的可持续发展，应该把环境保护和长期利益作为研究目标，文章估算了中国14个城市的太阳能资源，分析了太阳能热水系统和PIVP系统的经济性，研究结果表明，中国的太阳能利用潜力很大，政府应该对其发展发挥重要作用。     

Evolving patterns of agricultural frontier expansion in Mexico’s Chihuahuan Desert: a political ecology approach

ABSTRACT

This study sought to understand why and how the area of irrigated agriculture in Janos County, in northwestern Chihuahua, Mexico, has tripled since 1987. Expansion of agricultural frontiers has often been attributed to state policies and programs or von Thünian land-rent dynamics. Here, a political ecology approach relying on qualitative interviews with landowners was used to understand the drivers and patterns of conversion from native rangeland to crops. Results show that socioeconomic patterns of agricultural frontier expansion evolved over time, with different drivers at different phases. State policies, especially the land reform, were initially important for settling the agriculture frontier in small farms. Subsequently, economic differentiation, intensification, and growth of existing farms drove expansion. Since 2010, expansion has been driven by investment-oriented land purchases by absentee owners and larger-than-family farms. The Janos case details what may be common but underappreciated temporal dynamics at agricultural frontiers.     

Small scale boilover and visualization of hot zone

Experimental studies of boilover were conducted in small scale rig at Universiti Teknologi PETRONAS (UTP), Malaysia and Loughborough University, United Kingdom. The study at UTP was aimed to demonstrate the ability of conducting tests at a smaller scale to simulate the boilover phenomenon. At Loughborough University, a novel laboratory scale rig was designed and built in order to obtain visual records of fuels' behaviour in a pool fire. The ultimate objective of these studies is to develop a greater understanding of boilover pertaining to fires involving the contents of storage tanks. Fuel mixtures containing light and heavy components were burnt as to study the feasibility of reproducing hot zone formation and boilover in a smaller scale and a safe environment. Boilover occurred after certain period of burning. It is found that thickness of the hot zone changed with time. It is also found that the time needed to start boilover increased when fuel thickness increased. The visualization of the fuel behaviour during the experiments was obtained to better understand the formation and growth of hot zone, the boiling of water layer and hence the boilover occurrence. Based on the data analysis and the photographs recorded from the experiments, the laboratory scale experimental rig could be used to simulate the hot zone formation mechanism and the boilover event safely and successfully. Such information are important for the understanding towards boilover phenomenon.     

海洋环境下燃气轮机涡轮叶片的热腐蚀与防护

涡轮叶片热腐蚀是海洋环境工作下的燃气轮机的典型故障之一,也是决定涡轮叶片使用寿命的主要限制因素之一.简要分析了我国沿海地区海洋环境的特点以及涡轮叶片热腐蚀的特点,讨论了燃气轮机涡轮叶片的热腐蚀机理和影响因素,结果表明叶片表面温度、燃气中的盐含量以及燃油中的硫与钒是导致热腐蚀的重要因素.最后,着重从选材、涂层应用和维护等...