COMBUSTIVE APPROACH FOR MEASURING TOTAL VOLATILE PHOSPHORUS CONTENT IN LANDFILL GAS

A technique was developed to measure the total gaseous phosphorus content in biogas. The amount of air needed for a neutral to oxidising flame was mixed with the biogas. The gas mixture was burnt in a closed quartz burner and the combustion gasses were bubbled through a nitric acid solution. The phosphate content in the bubbling liquid was determined with sector field ICP-MS. The technique was validated in the lab with phosphine. Afterwards the set-up was installed on a landfill. The total gaseous phosphorus content in the landfill gas, measured with the combustive technique, ranged from 1.65 to 4.44 g P/m³. At the same time the phosphine concentration in the landfill gas was determined gas chromatographically (GC). The phosphine (PH₃) content measured with GC ranged from 7.6 to 16.7 g PH₃-P/m³. Since the phosphine-P content (GC) was consistently higher than the total gaseous phosphorus content (burner/ICP-MS), the hypothesised presence of highly toxic gaseous phosphorus compounds other than phosphine could not be demonstrated.     

表征室外人体暴露的监测网络设计(续一)

对悬浮颗粒物室外人体暴露的测定一直受到可用资源的限制，设计有效的网络就要求对测定方法的选择、采样点的数量、采样时间、采样频率等进行调整。采样位置要求能表征因周围污染源对附近地区和城市最小影响的空间数值。虽然大多数判定PM是否达标的测定方法是每第3天至第6天的24h监测，但是室外人体暴露的评价要求连续监测一整天，最好有1h或更短时间的监测时段。更详细的粒径大小和化学性质数据也很有必要，因为较小的颗粒及其特殊的化学物质要比总的样品质量更有助于反映对缝康的不良影响。     

生物传感器快速测定BOD在海洋监测中的应用

选用一株耐高渗透压的酵母菌种作为敏感材料可以实现BOD的快速测定。采用海藻酸钙包埋法和聚乙烯醇包埋法两种细胞固定化方法并进行了比较。就聚乙烯醇固定化微生物进行了渗稼压和重金属离子影响的研究。     

Production of laccase by Coriolus versicolor and its application in decolorization of dyestuffs: (Ⅱ) Decolorization of dyes by laccase containing fermentation broth with or without self-immobilized mycelia

The capability of decolorization for commercial dyes by Coriolus versicolur fermentation broth containing laccase with or without immobilized mycelium was evaluated.With cell-free fermentation broth containing laccase,high decolorization ratio was achieved for acid orange 7,but not for the other dyes concerned.The immobilized mycelium was proved to be more efficient than the cell-free system.All the four dyestuffs studied were found being decolourized with certain extent by immobilized mycelium.The repeated-batch decolorization was carried out with satisfactory results.The experimental data showed that the continuous decolorization of wastewater from a printing and dyeing industry was possible by using self-immobilized C.Versicolor.     

包埋法固定化细胞技术及其在水处理中的应用研究

固定化细胞技术(主要为包埋技术),由于方法简单、条件温和、较高的稳定性及细胞容量,在废水处理中应用广泛.本文主要介绍了近年来固定化细胞技术在污水深度处理中的应用研究现状和发展前景,并对固定化细胞技术在污水深度处理过程中的影响因素进行简要论述.     

镉胁迫下大豆中镉的分布状况及其籽粒品质

溶液培养中0.5μmol·L-1镉胁迫浓度下,大豆表现出轻微受害症状,籽粒减产25 . 7%,而籽粒中粗脂肪和粗蛋白含量变化不大.镉在大豆中的积累分布状况为根>叶>籽>油,比例为32.100:1.690:1.000:0.003.大豆籽粒含镉4.89mg/kg,超过了国家环境标准规定的最高容许量.而大豆粗脂肪中含镉仅0.015mg/kg,远低于国家食品环境卫生标准.豆粕中含镉6.17mg/kg,表明大豆籽粒中的镉主要存在于粗蛋白和淀粉中.     

Connecting sources, fractions and algal availability of sediment phosphorus in shallow lakes: An approach to the criteria for sediment phosphorus concentrations

Although point and nonpoint sources contribute roughly equal nutrient loads to lakes, their relative role in supporting algae growth has not been clarified. In this research, we have established a quantitative relationship between algae-available phosphorus (P) and P chemical fractions in sediments; the latter indicates the relative contribution of point versus nonpoint sources. Surface sediments from three large shallow lakes in eastern China, namely, the Chaohu, Taihu and Hongzehu Lakes, were sampled to assess their algae-available P and chemically extracted P fractions. The algae-available P primarily comes from iron/aluminium (hydr)oxide-bound P (Fe/Al-bound P), 45% of which is algae-available P. The ratio of Fe/Al-bound P to calcium compound-bound P (Ca-bound P) indicated the relative contribution of point to nonpoint sources, with the point sources contributing the majority of increased Fe/Al-bound P in sediments. Therefore, the reduction of point sources from urbanized areas, rather than nonpoint sources from agricultural areas that primarily contribute to the Ca-bound P fraction, should be prioritized to alleviate cyanobacterial algal blooms (CyanoHABs) in shallow lakes with sediment P as a potential source to support algae growth. With these important results, we proposed a conceptual model for “P-pumping suction” from sediments to algae to aid in the development of the criteria for sediment P concentrations in shallow lakes.     

软式排球健身价值的研究

运用文献、调查访问、观察、实验、统计及分析等研究方法,对有、无排球技术基础学生的对比分析,探讨软式排球的健身价值。研究结果表明:软式排球较硬式排球技术更易学习掌握,更易在学生中组织比赛,有着很重要的健身价值。为使软式排球更具有健身和娱乐性,应在比赛中灵活制定比赛规则。     

固定化微生物技术在环境工程中的应用

固定化微生物技术是一种新技术，与普通生物处理法相比有许多优点，对固定化微生物技术、微生物的固定化方法、固定化栽体及固定化技术在环境工程中的应用和研究进展状况进行了综述，并对其发展问题做了探讨。     

浅谈环境信息公开与环境管理

环境信息公开是通过社区和公众的舆论，使环境行为主体产生改善其环境行为的压力，从而达到环境保护的目的。环境信息是环境管理和环境保护的基础，环境信息公开能够有效地加强环境管理的公众参与和监督，促进政府重视环境质量的改善，促使污染者加强污染防治，改善其环境行为。本文将对环境信息与环境管理的关系与作用进行阐述。