全文获取类型
收费全文 | 620篇 |
免费 | 95篇 |
国内免费 | 515篇 |
专业分类
安全科学 | 44篇 |
废物处理 | 116篇 |
环保管理 | 43篇 |
综合类 | 687篇 |
基础理论 | 140篇 |
污染及防治 | 178篇 |
评价与监测 | 16篇 |
社会与环境 | 5篇 |
灾害及防治 | 1篇 |
出版年
2024年 | 3篇 |
2023年 | 19篇 |
2022年 | 41篇 |
2021年 | 46篇 |
2020年 | 40篇 |
2019年 | 65篇 |
2018年 | 61篇 |
2017年 | 47篇 |
2016年 | 51篇 |
2015年 | 66篇 |
2014年 | 75篇 |
2013年 | 74篇 |
2012年 | 79篇 |
2011年 | 78篇 |
2010年 | 39篇 |
2009年 | 69篇 |
2008年 | 31篇 |
2007年 | 62篇 |
2006年 | 34篇 |
2005年 | 40篇 |
2004年 | 23篇 |
2003年 | 21篇 |
2002年 | 28篇 |
2001年 | 28篇 |
2000年 | 21篇 |
1999年 | 26篇 |
1998年 | 10篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
排序方式: 共有1230条查询结果,搜索用时 912 毫秒
411.
In this study, we present a general protocol for the making of surface-imprinted core-shell magnetic beads via reversible addition-fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized iron oxide nanoparticles as the chain transfer agent. The resulting composites were characterized by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) analysis, thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The surface-imprinted magnetic beads were demonstrated with a homogeneous polymer films (thickness of about 22 nm), spherical shape, and exhibited magnetic property (Ms = 0.41 mA m2 g−1) and thermal stability. Rebinding experiments were carried out to determine the specific binding capacity and selective recognition. The as-synthesized surface-imprinted core-shell magnetic beads showed outstanding affinity and selectivity towards bisphenol A over structurally related compounds, and easily reach the magnetic separation under an external magnetic field. In addition, the resulting composites reusability without obviously deterioration in performance was demonstrated at least five repeated cycles. 相似文献
412.
几种典型红壤模拟降雨条件下的泥沙特征研究 总被引:1,自引:0,他引:1
泥沙是土壤侵蚀过程的产物,直接反映了土壤的侵蚀特征。本文利用人工模拟降雨,研究了南方几种典型母质发育红壤侵蚀泥沙的颗粒分布特征、不同粒级中胶结物质的种类和含量。研究结果表明,径流优先选择携带0.002~0.02 mm颗粒,该级别颗粒占泥沙总量的26.68%~60.33%。粘粒含量高的第四纪粘土红壤,泥沙中粗颗粒含量较高,且多为较稳定的团聚体;沙粒和粉粒含量较高的页岩红壤和花岗岩红壤侵蚀泥沙中单粒含量较高,且泥沙分散后粉粒和粘粒的含量高于原土壤。花岗岩红壤侵蚀泥沙中Fe_d,Al_d,Al_o和Si_o含量随泥沙粒径的增大而降低,而泥质页岩红壤和第四纪粘土红壤中,Fe_d,Al_d,Al_o含量随粒径增大而增加,因此其粗粒径泥沙具有较强的稳定性。侵蚀泥沙对有机质有富集作用,泥质页岩红壤和第四纪粘土红壤的粗颗粒对有机质的富集作用强于细颗粒。 相似文献
413.
The Republic of Korea found dioxin at concentrations exceeding the Korean maximum residue limit (MRL) in pork (2 pg TEQ g−1 fat) imported from Chile in June 2008. Korea and Chile collaborated and investigated to find out the sources of contamination. An isotope dilution method and high resolution gas chromatography/mass spectrometry (HR-GC/MS) were used for the analysis of PCDD/Fs. PCDD/Fs were found from 2.17 to 36.7 pg TEQ g−1 fat from Chilean pork. 2,3,4,7,8-PeCDF, 1,2,3,4,7,8-HxCDF, 1,2,3,6,7,8-HxCDF, and 2,3,4,6,7,8-HxCDF were found as the major congeners in pork samples. 2,3,4,7,8-PeCDF showed the highest concentration and contributed about 30% among the congeners in most of the samples. 2,3,7,8-TCDD, 1,2,3,7,8,9-HxCDD, OCDD, 2,3,7,8-TCDF, 1,2,3,7,8-PeCDF, 1,2,3,7,8,9-HxCDF, and OCDF were not detected or exist at background levels in the less contaminated samples. Remarkably high concentrations of PCDD/Fs were found in samples of zinc oxide (17 147 pg TEQ g−1), zinc oxide based premix (6673 pg TEQ g−1), and the residue crust (800 pg TEQ g−1) in a mixing chamber in the feed mill. From the results of various investigations, this case concluded that zinc oxide in the feed was the major source of the dioxin contamination in pork. The dioxins were formed from a metal refinery process to collect zinc oxide. 相似文献
414.
In this study, we examined the experimental catalytic oxidation of gaseous monochlorobenzene (MCBz) with O3 over Fe2O3 in a packed bed reactor to investigate the feasibility of economical low temperature decomposition at a high space velocity (SV). We investigated the effects of several reaction parameters (temperature, O3 concentration, and SV) on the MCBz oxidation. At 150 °C, the conversion of MCBz over Fe2O3 in the absence of O3 was only 3%; it increased to 91% over Fe2O3 in the presence of 1200 ppm of O3 at a high SV of 83 s−1. A long-term operation study revealed that the conversion of MCBz was stable for more than 96 h. In the steady state, the carbon and chlorine balances were 88% and 86%, respectively. Applying a Langmuir-Hinshelwood kinetic model, we estimated an activation energy of 16.7 kJ mol−1 for MCBz oxidation over Fe2O3 in the presence of O3. 相似文献
415.
Amendment of arsenic and chromium polluted soil from wood preservation by iron residues from water treatment 总被引:6,自引:0,他引:6
An iron-rich water treatment residue (WTR) consisting mainly of ferrihydrite was used for immobilization of arsenic and chromium in a soil contaminated by wood preservatives. A leaching batch experiment was conducted using two soils, a highly contaminated soil (1033 mg kg−1 As and 371 mg kg−1 Cr) and slightly contaminated soil (225 mg kg−1 As and 27 mg kg−1 Cr). Compared to an untreated reference soil, amendment with 5% WTR reduced leaching in the highly contaminated soil by 91% for Cr and 98% for As. No aging effect was observed after 103 d. In a small field experiment, soil was mixed with 2.5% WTR in situ. Pore water was extracted during 3 years from the amended soil and a control site. Pore water arsenic concentrations in the amended soil were more than two orders of magnitude lower than in the control for the upper samplers. An increased release of arsenic was observed during winter in both fields, mostly in the deepest samplers. This is likely due to the formation of a pseudo-gley because of precipitation surplus. Stabilization of arsenic and chromium contaminated soil using WTR is a promising method but the transformation of ferrihydrite in soil proves a concern in case of waterlogged soils. Still the amendment minimized the leaching of arsenic, even in cases of seasonal releases. 相似文献
416.
Dybowska AD Croteau MN Misra SK Berhanu D Luoma SN Christian P O'Brien P Valsami-Jones E 《Environmental pollution (Barking, Essex : 1987)》2011,159(1):266-273
Understanding the behavior of engineered nanoparticles in the environment and within organisms is perhaps the biggest obstacle to the safe development of nanotechnologies. Reliable tracing is a particular issue for nanoparticles such as ZnO, because Zn is an essential element and a common pollutant thus present at elevated background concentrations. We synthesized isotopically enriched (89.6%) with a rare isotope of Zn (67Zn) ZnO nanoparticles and measured the uptake of 67Zn by L. stagnalis exposed to diatoms amended with the particles. Stable isotope technique is sufficiently sensitive to determine the uptake of Zn at an exposure equivalent to lower concentration range (<15 μg g−1). Without a tracer, detection of newly accumulated Zn is significant at Zn exposure concentration only above 5000 μg g−1 which represents some of the most contaminated Zn conditions. Only by using a tracer we can study Zn uptake at a range of environmentally realistic exposure conditions. 相似文献
417.
Lesschen JP Velthof GL de Vries W Kros J 《Environmental pollution (Barking, Essex : 1987)》2011,159(11):3215-3222
Nitrous oxide (N2O) direct soil emissions from agriculture are often estimated using the default IPCC emission factor (EF) of 1%. However, a large variation in EFs exists due to differences in environment, crops and management. We developed an approach to determine N2O EFs that depend on N-input sources and environmental factors. The starting point of the method was a monitoring study in which an EF of 1% was found. The conditions of this experiment were set as the reference from which the effects of 16 sources of N input, three soil types, two land-use types and annual precipitation on the N2O EF were estimated. The derived EF inference scheme performed on average better than the default IPCC EF. The use of differentiated EFs, including different regional conditions, allows accounting for the effects of more mitigation measures and offers European countries a possibility to use a Tier 2 approach. 相似文献
418.
419.
Tang X Chen J Wang WH Liu TW Zhang J Gao YH Pei ZM Zheng HL 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3784-3792
This study characterized the changes of nitric oxide (NO) production during the growth of Microcystis aerugrinosa, a cyanobacterium which usually cause cyanobacterial blooms. Results showed a drastic NO release accompanying with cell density and Chl-a content sharp rises when M. aerugrinosa grew from fifth day to sixth day. Moreover, high N:P ratio accelerated the cyanobacterial growth and NO burst. Sodium nitroprusside, an exogenous NO donor, promoted M. aerugrinosa growth with the optimal concentration of 0.1 mg/L. Experiments by supplementing with sodium nitrite and l-arginine demonstrated NO production in M. aerugrinosa cells was mainly through nitrate reductase (NR) pathway while minorly through NO synthase pathway. All these data suggested M. aerugrinosa produced increasing NO during its growth mainly by NR pathway, during which NO positively regulated the growth of M. aerugrinosa. 相似文献
420.