全文获取类型
收费全文 | 3041篇 |
免费 | 440篇 |
国内免费 | 1228篇 |
专业分类
安全科学 | 201篇 |
废物处理 | 144篇 |
环保管理 | 353篇 |
综合类 | 2611篇 |
基础理论 | 359篇 |
污染及防治 | 322篇 |
评价与监测 | 468篇 |
社会与环境 | 235篇 |
灾害及防治 | 16篇 |
出版年
2024年 | 36篇 |
2023年 | 99篇 |
2022年 | 180篇 |
2021年 | 224篇 |
2020年 | 210篇 |
2019年 | 184篇 |
2018年 | 185篇 |
2017年 | 216篇 |
2016年 | 240篇 |
2015年 | 232篇 |
2014年 | 255篇 |
2013年 | 344篇 |
2012年 | 325篇 |
2011年 | 367篇 |
2010年 | 213篇 |
2009年 | 199篇 |
2008年 | 128篇 |
2007年 | 154篇 |
2006年 | 141篇 |
2005年 | 110篇 |
2004年 | 82篇 |
2003年 | 103篇 |
2002年 | 70篇 |
2001年 | 82篇 |
2000年 | 70篇 |
1999年 | 58篇 |
1998年 | 41篇 |
1997年 | 38篇 |
1996年 | 27篇 |
1995年 | 31篇 |
1994年 | 22篇 |
1993年 | 21篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1982年 | 1篇 |
排序方式: 共有4709条查询结果,搜索用时 218 毫秒
461.
462.
根据污染源现场调研结果,结合现有污染控制工艺所能达到的技术水平,建议污水排放标准中As浓度由现国家排放标准的0 5mg/L调整为0 1mg/L;Pb不变为1 0mg/L。大气污染物排放标准中As和Pb不变为1 0mg/L。大气污染物排放标准As和Pb的浓度限值分别是为0 5mg/m3和0 7mg/m3。 相似文献
463.
Mei Li Yao Zhang Chenglei Pei Jinwen Zhang Chunlei Cheng Xiufeng Lian Mubai Chen Bo Huang Zhong Fu Zhen Zhou 《环境科学学报(英文版)》2023,35(2):806-822
The real-time detection of the mixing states of polycyclic aromatic hydrocarbons (PAHs) and nitro-PAHs in ambient particles is of great significance for analyzing the source, aging process, and health effects of PAHs and nitro-PAHs; yet there is still few effective technology to achieve this type of detection. In this study, 11 types of PAH and nitro-PAH standard samples were analyzed using a high performance-single particle aerosol mass spectrometer (HP-SPAMS) in lab studies. The identification principles ‘parent ions’ and ‘mass-to-charge (m/z) = 77’ of each compound were obtained in this study. It was found that different laser energies did not affect the identification of the parent ions. The comparative experiments of ambient atmospheric particles, cooking and biomass burning emitted particles with and without the addition of PAHs were conducted and ruled out the interferences from primary and secondary organics on the identification of PAHs. Besides, the reliability of the characteristic ions extraction method was evaluated through the comparative study of similarity algorithm and deep learning algorithm. In addition, the real PAH-containing particles from vehicle exhaust emissions and ambient particles were also analyzed. This study improves the ability of single particle mass spectrometry technology to detect PAHs and nitro-PAHs, and HP-SPAMS was superior to SPAMS for detecting single particles containing PAHs and nitro-PAHs. This study provides support for subsequent ambient observations to identify the characteristic spectrum of single particles containing PAHs and nitro-PAHs. 相似文献
464.
465.
可交易排污许可证在传统的排污许可证基础上,引入市场机制。不但对企业选择污染控制手段赋予更大的灵活性,而且可以大大节约水污染控制费用、剌激企业开发并建设更加经济有效的污染控制技术。国外十多年的研究和实践证明可交易排污许可证是一种经济而有效的环境管理手段。水污染排放许可证制度在我国的应用已有一定基础。在条件具备的地区可以引进可交易水污染物排放许可证制度,本文回顾了“可交易水污染许可证制度”的理论分析和国外实践,进而探讨在中国的应用前景 相似文献
466.
467.
Metal complexation by natural ligands is important for metal transport and distribution in surface and ground water. The goal of the work was to study the ligand exchange rate for two important metal ions in natural aquatic systems (Al, Fe) was determined using EDTA and natural organic matter (NOM) of humic type as ligands. After adding EDTA to a solution containing metal-NOM complexes, these complexes dissociated and metal-EDTA complexes were formed. Metal-NOM complexes were separated from metal-EDTA complexes with the help of size-exclusion chromatography and detected by on-line inductively coupled plasma-mass spectrometry (ICP-MS). Injecting the samples into the system over time after addition of EDTA allowed us to measure the rate of the exchange of NOM by EDTA. The experiments could be well described with a first-order rate law assuming that the dissociation of the metal-NOM complexes is the rate-determining step. The exchange rate of Fe was found to be faster than that of Al. This corresponds well with the exchange rate of water molecules from the coordination sphere of the metal ions, which is also faster for Fe than for Al. Furthermore, the UV and the fluorescence signal of the chromatograms were measured. The results indicate that no disaggregation of NOM molecules took place, although about 75-85% of the aggregate-forming metal ions exchanged NOM by EDTA in their coordination sphere. This suggests clearly the fundamental role of NOM in colloidal transport of metals and in their bioavailability. 相似文献
468.
机动车排放遥感监测反映实际道路行驶中的排放状况,对全面分析排放水平有很强的统计意义。北京市机动车排放遥感监测的CO、HC和NOx的平均浓度分别为1.94%、388×10-6和700×10-6。北京市机动车排放的CO、HC和NOx中50%分别来自于15.90%、13.98%、11.13%的高排放车,但某车辆对于一种污染物出现高排放并不意味着它对其他污染物也是高排放。根据遥感监测得到北京市轻型汽油车基于油耗的CO、HC和NOx平均尾气管排放因子分别为200.1g/L、11.05 g/L和6.68 g/L。 相似文献
469.
470.
随着温室效应和全球变暖的加剧,煤燃烧所排出的CO2作为引起温室效应的主要气体而引起人们的密切关注.由于燃煤锅炉所排放的尾气中所含的CO2的体积份额低、排放量大,而且处于微负压状态,因此目前控制和分离吸收CO2的方法,包括各类吸收法、吸附法、膜分离法和O2/CO2燃烧技术等,能够经济可行地适用于电力工业燃煤锅炉尾部烟气中CO2分离的方法非常少.与上述各类方法相比,钙基吸收剂CCRs(calcination/carbonation reactions)法是一种新兴的经济可行的分离燃煤锅炉尾部烟气中CO2的方法.对采用该法时,吸收剂的选择、吸收剂在多次CCRs过程中结构特点的变化、提高吸收剂对CO2的吸收容量以及防止吸收剂反应性的衰减等方面进行了详细的阐述. 相似文献