高温高压下煤孔隙结构的变化对瓦斯吸附特性的影响

为了研究高温高压条件下煤孔隙结构变化对瓦斯吸附特性的影响,选取九里山矿无烟煤,在压力为7 MPa、温度为40～130℃的条件下进行等温吸附实验和压汞实验。研究结果表明:煤样对甲烷的等温吸附曲线在该压力、温度条件下符合Ⅰ型吸附曲线特性,吸附规律符合Langmuir吸附模型;在压力7 MPa和温度130℃条件下,煤样的孔隙结构发生一定的变化,煤的比表面积增大、累计孔体积降低,可见孔及裂隙的数量比例增高,加强了煤样孔隙之间的连通度,导致原本吸附在煤样表面的甲烷分子大量解吸;在压力不变的情况下,随着温度的不断增高,煤的极限吸附量逐渐减小,其主要原因是样品孔隙结构的破坏和分子间作用力的变化。     

基于尾涡强度的无人机与民机纵向安全间隔评估研究

为了解决无人机频频入侵机场净空,与民航客机发生危险接近的问题,以碰撞风险为量化指标,对无人机与民机需要保持的纵向安全间隔进行评估研究。分析民机尾涡流场对无人机运行的影响,利用Crow近场涡强度消散理论,得到实际尾迹影响区改进Reich碰撞模板,据此建立CNS/GPS性能环境下的纵向间隔评估模型,通过Matlab进行间隔值求解。研究结果表明:模型可以较为准确地反映民机起飞初始爬升阶段无人机尾随运行时导航性能和尾涡迹对所需最小间隔值的影响,并得到给定安全目标水平的计算结果。     

钙钛矿型La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3催化剂的制备及其三效催化活性

采用自燃烧法制备了一组钙钛矿型复合氧化物La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3(x=0.9,0.7,0.5,0.3,0.1),并考察了其对CO、C_3H_6和NO的三效催化活性。XRD和SEM表征结果显示,La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3具有良好的钙钛矿型晶体结构,晶粒大小为纳米级并自组装成片状结构。催化剂的比表面积为14.73~22.43 m~2/g,含有微孔和介孔结构。催化活性评价结果表明:La_(0.8)Ce_(0.2)Fe_(0.1)Co_(0.9)O_3具有很好的三效催化活性,在理论空燃比的条件下,CO、C_3H_6和NO的起燃温度分别为195℃、264℃和290℃,完全转化温度分别为239℃、418℃和415℃,低温三效催化活性良好;Fe和Co的掺杂量同时影响着La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3的催化效果。     

臭氧氧化—湿式钙法吸收工艺对烟气的同时脱硫脱硝

采用臭氧氧化—湿式钙法吸收工艺对模拟烟气进行同时脱硫脱硝处理。O₃于150 ℃下具有较高的热稳定性,可将NO氧化为高价态氮氧化物,且NO氧化率随n（O₃）∶n（NO）的增大而逐渐提高。烟气中SO₂和H₂O的存在对NO氧化率的影响不大。O₃对SO₂的氧化率较低,约为5%。3%（w）石灰石浆液对SO₂的吸收率接近100%,NO_x吸收率随n（O₃）∶n（NO）的增大而逐渐提高,当n（O₃）∶n（NO）为1.6时NO_x吸收率可达约65%。SO₂能促进吸收液对NO_x的脱除。石灰石浆液中加入0.2%（w）的（NH₄）₂SO₃或Na₂SO₃后NO_x吸收率可达约85%或82%,且吸收率随添加剂加入量的增加而提高,添加（NH₄）₂SO₃的NO_x吸收率略高于添加Na₂SO₃。     

Deliberative democracy meets democratised science: a deliberative systems approach to global environmental governance

The main achievements of the debates on deliberative democracy and democratised science are investigated in order to analyse the reasons, meanings and prospects for a democratisation of global environmental policy. A deliberative systems approach, which emphasises the need to explore how processes in societal spheres interact to shape the deliberative qualities of the system as a whole, is adopted. Although science plays a key role in this, its potential to enhance deliberative capacity has hardly been addressed in deliberative theories. The democratisation of science has potential to contribute to the democratisation of global environmental policy, in that it also shapes the potential of deliberative arrangements in the policy sphere. Deliberative arrangements within the policy sphere may stimulate the democratisation of science to different degrees.     

Water Management Decision Making in the Face of Multiple Forms of Uncertainty and Risk

In the Wasatch Range Metropolitan Area of Northern Utah, water management decision makers confront multiple forms of uncertainty and risk. Adapting to these uncertainties and risks is critical for maintaining the long‐term sustainability of the region's water supply. This study draws on interview data to assess the major challenges climatic and social changes pose to Utah's water future, as well as potential solutions. The study identifies the water management adaptation decision‐making space shaped by the interacting institutional, social, economic, political, and biophysical processes that enable and constrain sustainable water management. The study finds water managers and other water actors see challenges related to reallocating water, including equitable water transfers and stakeholder cooperation, addressing population growth, and locating additional water supplies, as more problematic than the challenges posed by climate change. Furthermore, there is significant disagreement between water actors over how to best adapt to both climatic and social changes. This study concludes with a discussion of the path dependencies that present challenges to adaptive water management decision making, as well as opportunities for the pursuit of a new water management paradigm based on soft‐path solutions. Such knowledge is useful for understanding the institutional and social adaptations needed for water management to successfully address future uncertainties and risks.     

Impacts of Changes in Precipitation Amount and Distribution on Water Resources Studied Using a Model Rainwater Harvesting System

Water supply reliability is expected to be affected by both precipitation amount and distribution changes under recent and future climate change. We compare historical (1951‐2010) changes in annual‐mean and annual‐maximum daily precipitation in the global set of station observations from Global Historical Climatology Network and climate models from the Inter‐Sectoral Impact Model Intercomparison Project (ISI‐MIP), and develop the study to 2011‐2099 for model projections under high radiative forcing scenario (RCP8.5). We develop a simple rainwater harvesting system (RWHS) model and drive it with observational and modeled precipitation. We study the changes in mean and maximum precipitation along with changes in the reliability of the model RWHS as tools to assess the impact of changes in precipitation amount and distribution on reliability of precipitation‐fed water supplies. Results show faster increase in observed maximum precipitation (10.14% per K global warming) than mean precipitation (7.64% per K), and increased reliability of the model RWHS driven by observed precipitation by an average of 0.2% per decade. The ISI‐MIP models show even faster increase in maximum precipitation compared to mean precipitation. However, they imply decreases in mean reliability, for an average 0.15% per decade. Compared to observations, climate models underestimate the increasing trends in mean and maximum precipitation and show the opposite direction of change in reliability of a model water supply system.     

Augmenting Watershed Model Calibration with Incorporation of Ancillary Data Sources and Qualitative Soft Data Sources

Watershed simulation models such as the Soil & Water Assessment Tool (SWAT) can be calibrated using “hard data” such as temporal streamflow observations; however, users may find upon examination of model outputs, that the calibrated models may not reflect actual watershed behavior. Thus, it is often advantageous to use “soft data” (i.e., qualitative knowledge such as expected denitrification rates that observed time series do not typically exist) to ensure that the calibrated model is representative of the real world. The primary objective of this study is to evaluate the efficacy of coupling SWAT‐Check (a post‐evaluation framework for SWAT outputs) and IPEAT‐SD (Integrated Parameter Estimation and Uncertainty Analysis Tool‐Soft & hard Data evaluation) to constrain the bounds of soft data during SWAT auto‐calibration. IPEAT‐SD integrates 59 soft data variables to ensure SWAT does not violate physical processes known to occur in watersheds. IPEAT‐SD was evaluated for two case studies where soft data such as denitrification rate, nitrate attributed from subsurface flow to total discharge ratio, and total sediment loading were used to conduct model calibration. Results indicated that SWAT model outputs may not satisfy reasonable soft data responses without providing pre‐defined bounds. IPEAT‐SD provides an efficient and rigorous framework for users to conduct future studies while considering both soft data and traditional hard information measures in watershed modeling.     

A real-time simulating non-isothermal mathematical model for the passive feed direct methanol fuel cell

In order to understand the complex transport phenomena in a passive direct methanol fuel cell (DMFC), a theoretical model is essential. The analytical model provides a computationally efficient framework with a clear physical meaning. For this, a non-isothermal, analytical model for the passive DMFC has been developed in this study. The model considers the coupled heat and mass transport along with electrochemical reactions. The model is successfully validated with the experimental data. The model accurately describes the various species transport phenomena including methanol crossover and water crossover, heat transport phenomena, and efficiencies related to the passive DMFC. It suggests that the maximum real efficiency can be achieved by running the cell at low methanol feed concentration and moderate current density. The model also accurately predicts the effect of various operating and geometrical parameters on the cell performance such as methanol feed concentration, surrounding temperature, and polymer electrolyte membrane thickness. The model predictions are in accordance with the findings of the other researchers. The model is rapidly implementable and can be used in real-time simulation and control of the passive DMFC. This comprehensive model can be used for diagnostic purpose as well.     

Highly efficient conversion of sugarcane bagasse pretreated with liquid hot water into ethanol at high solid loading

Liquid hot water (LHW), an environmental-friendly physico-chemical treatment, was applied to pretreat the sugarcane bagasse (SCB). Tween80, a non-ionic surfactant, was used to enhance the enzymatic hydrolysis of the pretreated SCB. It found that 0.125 mL Tween80 /g dry matter could make the maximum increase (33.2%) of the glycan conversion of the LHW-pretreated SCB. A self-designed laboratory facility with a plate-and-frame impeller was applied to conduct batch hydrolysis, fed-batch hydrolysis, and the process of high-temperature (50°C) fed-batch hydrolysis following low-temperature (30°C) simultaneous saccharification and fermentation (SSF) which was adopted to overcome the incompatible optimum temperature of saccharification and fermentation in the SSF process. After hydrolyzing LHW-pretreated SCB for 120 h with commercial cellulase, the total sugar concentration and glycan conversion obtained from fed-batch hydrolysis were 91.6 g/L and 68.3%, respectively, which were 9.7 g/L and 7.3% higher than those obtained from batch hydrolysis. With Saccharomyces cerevisiae Y2034 fermenting under the non-sterile condition, the ethanol production and theoretical yield obtained from the process of SSF after fed-batch hydrolysis were 55.4 g/L and 88.3% for 72h, respectively, which were 15.5 g/L and 24.7% higher than those from separate fed-batch hydrolysis and fermentation. The result of this work was superior to the reported results obtained from the LHW-pretreated SCB.