循环流化床烟气脱硫机理研究

对影响脱硫效率的关键因素进行了分析,同时进行了实验验证,认为水分的蒸发是主要影响因素,而流化床的运行温度和床内的相对湿度则是影响循环床脱硫效率的主要运行参数,对排烟循环流化床的床料进行了电镜扫描分析。结果表明,床料的再循环,一方面为脱硫剂的再循环提供了载体,另一方面,扩大了脱硫反应的面积,提高了脱硫效率。     

生活废弃物焚烧处置烟气中二(口恶)英排放特性研究

研究了某市10座生活垃圾焚烧炉烟气中二噁英的排放特性,对比了焚烧炉炉型、焚烧处理量、烟气净化系统对二噁英排放特性的影响.结果表明:10座生活垃圾焚烧炉二噁英的排放浓度为0.016~0.104 ng·Nm~(-3)(以I-TEQ计),9座垃圾焚烧炉二噁英排放满足国家相应的排放标准(0.1 ng·Nm~(-3)(以I-TEQ计)).根据二噁英排放浓度排序对应的烟气净化系统分别为SNCR(Selective Non-Catalytic Reduction)+半干法+活性炭喷射+布袋湿法+活性炭喷射+布袋半干法+活性炭喷射+布袋,表明安装SNCR装置有利于二噁英的减排.另外,不同垃圾焚烧炉排放的二噁英指纹特性不仅与烟气净化系统和炉型有关,还与垃圾来源有一定关联.     

络合铁法脱除硫化氢技术

在此介绍了络合铁脱硫原理 ;并进行了络合铁法脱除酸性气体中硫化氢的研究 ,实验结果表明 :络合铁脱硫工艺具有吸收速度快、脱硫效率高等特点。     

还原铁粉/紫外光体系对活性艳红X-3B溶液的脱色

研究了在紫外杀菌灯（λmax=253．7nm,30W）照射下,添加还原铁粉的活性艳红X－3B水溶液的脱色作用。当pH=3．5,铁粉投加量为2．0g／L时,20mg／L活性艳红X－3B溶液在光照180min后的脱色率为79％。脱色为动力学零级反应。染料溶液的pH、铁粉投加量、活性艳红初始浓度对脱色有影响。初步探讨了脱色反应的机理。     

人工湿地系统植物床内CODcr动态变化规律探讨

人工湿地处理污水系统植物床内各监测点的上、下层 Ｃ Ｏ Ｄｃｒ值虽有一定的差别,但经过成对平均数比较分析发现这种差别并未形成明显的趋势。污水在植物床基质中流动时,随着迁移距离的延长,其中的 Ｃ Ｏ Ｄｃｒ的降解速率呈现先快后慢的趋势,根据形成的动态变化曲线,建立了 Ｃ Ｏ Ｄｃｒ在植物床内沿程动态变化模型： Ｃ Ｌ＝ Ｃｏｅｘｐ（４６２９×１０－ ５ Ｌ２－ ００１５６７ Ｌ,０≤ Ｌ≤１００）。经验证,模型预测值与实际监测值呈非常显著相关（ｄｆ＝ ４,ｒ≥０９９４６＞ ｒ００００５（４）,ｒ００００５（４）＝ ０９７４１）。     

铁的环境地球化学综述

本文详细介绍了铁在表生地球化学环境中的存在状态,亚铁的氧化动力学,铁微生物地球化学及铁在表生带迁移转化的环境学意义,强调了铁环境地球化学研究的重要性     

海绵铁对印染废水脱色研究

海绵铁脱色是电化学、氧化还原、电场作用、絮凝沉淀以及物理吸附等的共同作用。实验结果表明 :海绵铁对色度的吸附过程符合Freundlich等温式。研究了海绵铁对几种不同颜色废水的脱色情况 ,海绵铁对酸性金黄、酸性藏蓝以及大红色染料都有较好的脱色效果 ,脱色率在 90 %以上 ;对耐晒黑染料的脱色效果相对较差为 80 %左右。同时通过几种影响因素的研究 ,确定了脱色的最佳实验条件。并在实际废水中得到了有效的验证 ,当滤速为 6m/h时 ,脱色率可达到 94%以上     

UASCB-SMBR处理垃圾渗滤液的试验研究

研究了厌氧污泥复合床 (UASCB) 序批式膜生物反应器 (SMBR)串联工艺 ,处理垃圾渗滤液的工艺性能及影响因素 ,并与单纯的SMBR工艺进行了对比。试验结果表明 ,在进液COD浓度平均为 2 50 0mg/L ,NH+ 4-N平均浓度为 360mg/L ,厌氧反应器COD的负荷为 7～2 0kgCOD/m3·d ,SMBR负荷为 1～ 5kgCOD/m3·d,系统总水力停留时间为 1 4～ 2 8h时 ,该串联工艺COD去除率达到 92 %以上 ,NH+ 4-N的去除率在 80 %以上     

Volatilization of heavy metals during incineration of municipal solid wastes

Incineration experiments with MSW, which had been impregnated with heavy metals, were presented to obtain information on the volatilization behavior of the elements cadmium (Cd), lead (Pb), and zinc (Zn) under different conditions. Experiments were carried out in a bubbling fluid bed system connected to a customized inductively coupled plasma optical emission spectroscopy(ICP-OES) for analyzing metals in the flue gas. The results indicated that the combustion temperature, the gas atmosphere, and the chlorine content in the flue gas could affect the volatilization behavior of heavy metals. In the fluidized bed combustion, a large surface area was provided by the bed sand particles, and they may act as absorbents for the gaseous ash-forming compound. Comparer with the metals Cd and Pb, the vaporization of Zn was low. The formation of stable compounds such as ZnO.Al2O3 could greatly decrease the metals volatilization. The presence of chlorine would enhance the volatilization of heavy metals by increasing the formation of metal chlorides. However, when the oxygen content was high, the chlorinating reaction was kinetically hindered, which heavy metals release would be delayed.     

Rapid treatment of atrazine-contaminated water by nickel/iron bimetallic system

The utility of nickel/iron in the remediation of atraz.ine-contaminated water was investigated. The experimental results showed that nickel/iron had effective catalytic activity in dechlorinating atraz.ine under acidic conditions. The dechlonnation reaction approximately followed the first-order kinetics under the experimental conditions( nickel/iron: 1.0 g/250 ml: Ca~r~ = 20.0 mg/L), the reaction rate increased with decreasing pH value of the reaction solution and increasing the proportion of Ni: Fe within 2.95 %. For condition with 2.95% nickel/iron, the reaction rate constants were 0.07518( R = 0.9927), 0.06212( R = 0.9846) and 0.00131 min^-1 ( R = 0.9.565) at pH = 2.0, 3.0 and 4.0, respectively. HPLC analysis was used to monitor the decline of atraz.ine concentration.