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Aerobic degradation of methyl tert-butyl ether by a Proteobacteria strain in a closed culture system 总被引:4,自引:0,他引:4
The contamination of methyl ten-butyl ether (MTBE) in underground waters has become a widely concerned problem all over the world. In this study, a novel dosed culture system with oxygen supplied by H2O2 was introduced for MTBE aerobic biodegradation. After 7 d, almost all MTBE was degraded by a pure culture, a member of β-Proteobacteria named as PMI, in a closed system with oxygen supply, while only 40% MTBE was degraded in one without oxygen supply. Dissolved oxygen (DO) levels of the broth in closed systems respectively with and without H2O2 were about 5-6 and 4 mg/L. Higher DO may improve the activity of monooxygemase, which is the key enzyme of metabolic pathway from MTBE to tert-butyl alcohol and finally to CO2, and may result in the increase of the degrading activity of PM1 cell. The purge and trap GC-MS result of the broth in closed systems showed that tea-butyl alcohol, isopronol and acetone were the main intermediate products. 相似文献
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目的 从微观分子的角度对硝酸羟胺(HAN)基电控固体推进剂(Electrically Controlled Solid Propellants,ECSP)的性能参数进行模拟与计算。方法 利用分子表面静电势(ESP)对HAN分子2种可能的构型进行优化和稳定性分析。通过真空非周期性分子动力学模拟得到聚乙烯醇(PVA)分子稳定构型,并以HAN基ECSP的主要成分按一定比例构建凝胶模型。基于RESP(Restrained Electrostatic Potential)电荷生成更准确的凝胶模型拓扑文件,并进行凝胶模型的分子动力学模拟、模型稳定分析以及模型参数计算。结果 凝胶模型总能量相对平均值的周期性波动不超过7%。由于三维PVA链的包裹,H2O分子的扩散系数被大幅削弱。氢键分析和径向分布函数表明氢键键长主要分布在0.282 6 nm附近,PVA与H2O间的氢键较少,H2O与HAN、H2O与H2O之间的氢键较多。模型密度为1.405 g/cm3,与实验值吻合度高。在283、293、303 K下,HAN基ECSP凝胶模型的拉伸模量依次降低,剪切模量先增后减。在15 K/600 ps冷却速率下,HAN基ECSP凝胶模型的拉伸模量和剪切模量均增大。结论 ECSP制备结束后,冷却过程中的环境温度不宜过高,否则容易造成ECSP力学性能的快速下降,快速冷却可以提高ECSP的力学性能。 相似文献
54.
乙醛废水处理的工程实例 总被引:2,自引:0,他引:2
溧阳市某化工厂以乙醇氧化法生产乙醛,该厂原有一套污水处理站,但系统出水难以达标.在改造过程中,利用原有污水处理系统,在调节池后新建多级内循环厌氧(MIC)反应器.该废水经过冷却到35~39℃、在调节池加营养和碱调节pH为7左右,MIC反应器进水CODCr约为3200mg/L、HRT为24h时,CODCr去除率为85%以上,MIC出水进入推流式好氧池,采用微孔曝气器曝气,HRT为36h,好氧出水CODCr小于100mg/L.该工艺运行稳定,为乙醛化工企业处理该废水提供一条新途径. 相似文献
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采用投加优势菌群的水解 -混凝法对糖蜜酒精废水进行试验 ,研究投加优势菌的水解阶段的处理效果 ,同时 ,以 10 %碱式AlCl3为混凝剂 ,对水解段的出水进行混凝处理 ,并对处理条件进行研究。结果表明 ,采用投加优势菌群的水解 -混凝法工艺处理该废水 ,可以取得 5 8%的CODCr去除率 ,且可去除一定的色度 相似文献
58.
Trapp S Yu X Mosbaek H 《Environmental science and pollution research international》2003,10(6):357-360
BACKGROUND: Methyl tertiary butyl ether (MTBE) is the second most highly produced industrial chemical in the US and a frequent groundwater pollutant. At the same time, MTBE is quite persistent to biotic and abiotic decomposition. The goal of this study was to find plant species that could degrade MTBE and might be used in phytoremediation. METHODS: Excised roots and leaves (0.3 g) from more than 24 Danish plant species out of 15 families were kept in glass vessels with 25 ml spiked aqueous solution for 2 to 4 days. MTBE concentrations were 1 to 5 mg/L. Samples were taken directly from the solution with a needle and injected to a purge and trap unit. MTBE and the main metabolite, TBA, were measured by GC/FID. RESULTS AND DISCUSSION: Solutions with roots of poplar (Populus robusta) and a willow hybrid (Salix viminalis x schwerinii) produced TBA in trace amounts, probably stemming from bacteria. Significant MTBE reduction (> 10%) was not observed in any of the tests. Leaves from none of the species (trees, grasses and herbs) reduced the concentration of MTBE in the solution and no TBA, nor any other known metabolite of MTBE, was detected. CONCLUSION: It was not possible to find plants capable of efficiently degrading MTBE. This gives rise to the conclusion that plants probably cannot degrade MTBE at all, or only very slowly. RECOMMENDATIONS AND OUTLOOK: For phytoremediation projects, this has, as consequence, that the volatilization by plants (except with genetically engineered plants) is the only relevant removal process for MTBE. For risk assessment of MTBE, degradation by the plant empire is not a relevant sink process. 相似文献
59.
采用活性炭吸附,二硫化碳解析,毛细管气相色谱法同时测定空气与废气中的正丁烷、丁酮、醋酸异丙酯,采样体积以45L计,方法最低检出限分别为:正丁烷0.002mg/m^3,丁酮0.0024mg/m^3,醋酸异丙酯0.0028mg/m^3。 相似文献
60.
厌氧-气浮-UASB-SBR工艺处理酒精废水 总被引:2,自引:0,他引:2
介绍了厌氧-气浮-UASB-SBR处理工艺在酒精废水处理工程中的实际应用,分析并总结了工程设计及运行的经验。实践表明,经厌氧-气浮-UASB-SBR的工艺处理后,废水中COD和SS总去除效率分别可达到99.6%和99.8%以上,并可以回收大量的沼气和部分废水回用于生产过程中。该工艺具有运行稳定和处理效率高等优点,为企业带来了良好的经济效益和社会效益。 相似文献