Preparation of activated carbon from chicken waste is a promising way to produce a useful adsorbent for Hg removal. A three-stage activation process (drying at 200℃, pyrolysis in N2 atmosphere, followed by CO2 activation) was used for the production of activated samples. The effects of carbonization temperature (409-4500℃), activation temperature (700-900℃), and activation time (1-2.5 h) on the physicochemical properties (weight-loss and BET surface) of the prepared carbon wereinvestigated. Adsorptive removal of mercury from real flue gas onto activated carbon has been studied. The activated carbon from chicken waste has the same mercury capacity as commercial activated carbon (Darco LH) (Hg^v: 38.7% vs. 53.5%, Hg^0: 50.5% vs. 68.8%), although its surface area is around 10 times smaller, 89.5 m^2/g vs. 862 m^2/g. The low cost activated carbon can be produced from chicken waste, and the procedure is suitable. 相似文献
The explosion at a plant of the Jilin Petrochemical Corporation on 13 November,2005,and the spill of an estimated 100 t of toxic substances (nitrobenzene as the main component) into the Songhua River received worldwide attention.This study has focused on the adsorption behavior of nitrobenzene that spilled onto sediments along the Songhua River,which was one of the efforts to evaluate the fate of nitrobenzene after the spillage event.The organic carbon contents of these sediments along the Songhua River ... 相似文献
Powdered activated carbon (PAC) prepared from Eucalyptus camaldulensis Dehn. bark was tested for its adsorption capacity for Cu(Ⅱ) and Pb(Ⅱ). The experiment was conducted to investigate the effects of pH, contact time, initial metal concentration, and temperature. The best adsorption of both Cu(Ⅱ) and Pb(Ⅱ) occurred at pH 5, where the adsorption reached equilibrium within 45 min for the whole range of initial heavy metal concentrations (0.1-10 mmol/L). The adsorption kinetics was found to follow the pseudo-... 相似文献
The adsorption behaviors of Hg(Ⅱ) on laterite from Guizhou Province,China,were studied and the adsorption mechanism was discussed.The results showed that different mineral compositons in the laterite will cause differences in the adsorption capacity of laterite to Hg(Ⅱ).Illite and non-crystalloids are the main contributors to enhancing the adsorption capacity of laterite to Hg(Ⅱ).The pH of the solution is an important factor affecting the adsorption of Hg(Ⅱ) on laterite.The alkalescent environment (pH 7-9) ... 相似文献
A new adsorbent sulfhydryl and carboxyl functionalized magnetite nanocellulose composite [(MB-IA)-g-MNCC] was synthesized by graft co-polymerization of itaconic acid onto magnetite nanocellulose (MNCC) using EGDMA as cross linking agent and K2S2O8 as free radical initiator. The adsorption occurs maximum in the pH 6.5. The best fitted kinetic model was found to be pseudo-second-order kinetics. Therefore the mechanism of Co(II) adsorption onto (MB-IA)-g-MNCC follows ion exchange followed by complexation. The Langmuir model was the best fitted isotherm model for the adsorption of Co(II) onto the (MB-IA)-g-MNCC. Simulated nuclear power plant coolant water samples were also treated with (MB-IA)-g-MNCC to demonstrate its efficiency for the removal of Co(II) from aqueous solutions in the presence of other metal ions. To recover the adsorbed Co(II) ions and also to regenerate the adsorbent to its original state 0.1?M HCl was used as suitable desorbing agent. Six cycles of adsorption-desorption experiments were conducted and was found that adsorption capacity of (MB-IA)-g-MNCC has been decreased from 97.5% in the first cycle to 84.7% in the sixth cycle. Recovery of Co(II) using 0.1?M HCl decreased from 93.2% in the first cycle to 79.3% in the sixth cycle.
Abbreviations: T: absolute temperature; qe: amount adsorbed at equilibrium; qt: amount adsorbed at time t; CELL: cellulose; Co: cobalt; Ce: concentration at equilibrium; CHCl: concentration of HCl; CNaOH: concentration of NaOH; CA: concentrations of acid; CB: concentrations of base; Wg: dry weight of composite; Wi: dry weight of MNCC; DS: energy dispersive spectra; EGDMA: ethylene glycol dimethacrylate; Ce: equilibrium concentration; KL: equilibrium constant; F: Faradays constant; FTIR: Fourier transform infrared spectra; ΔGo: free energy change; KF: Freundlich adsorption capacity; 1/n: Freundlich constant; R: gas constant; D: grafting density; ECo: initial concentration; IA: itaconic acid; IA-g-MNCC: itaconic acid-grafted-magnetite nanocellulose composite; b: Langmuir constant; MNCC: magnetite nanocellulose composite; Q0: Maximum adsorption capacity; (MB-IA)-g-MNCC: 2-mercaptobenzamide modified itaconic acid-grafted-magnetite nanocellulose composite; NC: nanocellulose; pHpzc: Point of zero charge; K2S2O8: potassium peroxy sulphate; k1: pseudo-first-order rate constant; k2: pseudo-second-order rate constant; SEM: scanning Electron Microscope; bs: Sips adsorption capacity; Qs: Sips maximum adsorption capacity; ΔH°: standard enthalpy change; ΔS°: standard entropy change; A: surface area; σ0: surface charge density; 1/ns: surface heterogeneity factor; VSM: vibrating sample magnetometer; V: volume of solution; W: weight of (MB-IA)-g-MNCC; Mcomposite: weight of the composite; XRD: X-ray diffraction 相似文献