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171.
Mohamed Edali Ahmed Aboudheir Raphael Idem 《International Journal of Greenhouse Gas Control》2009,3(5):550-560
New comprehensive numerically solved 1D and 2D absorption rate/kinetics models have been developed, for the first time, to interpret the experimental kinetic data obtained with a laminar jet apparatus for the absorption of carbon dioxide (CO2) in CO2 loaded mixed solutions of mixed amine system of methyldiethanolamine (MDEA) and monoethanolamine (MEA). Three MDEA/MEA weight ratios ranging from 27/03 to 23/07, over a concentration range of 2.316–1.996 kmol/m3 for MDEA and of 0.490–1.147 kmol/m3 for MEA were studied. The models take into account the coupling between chemical equilibrium, mass transfer, and the chemical kinetics of all possible chemical reactions involved in the CO2 reaction with MDEA/MEA solvent. The partial differential equations of the 1D model were solved by two numerical techniques; the finite difference method (FDM) based on in-house coded Barakat–Clark scheme and the finite element method (FEM) based on COMSOL software. The FEM comprehensive model was then used to solve the set of partial differential equations in the 2D cylindrical coordinate system setting. Both FDM and FEM produced very accurate results for both the 1D and 2D models, which were much better than our previously published simplified model. The reaction rate constant obtained for MEA blended into MDEA at 298–333 K was kMEA = 5.127 × 108 exp(−3373.8/T). In addition, the 2D model, for the first time, has provided the concentration profiles of all the species in both the radial and axial directions of the laminar jet, thereby enabling an understanding of the correct sequence in which the reaction steps involved in the reactive absorption of CO2 in aqueous mixed amines occur. 相似文献
172.
战时火力发电厂重要目标分类防护探讨 总被引:3,自引:2,他引:1
基于重要目标防护准则和模糊聚类算法,构建火力发电厂目标评价准则指标体系和模糊聚类模型,实现了火力发电厂重要目标的分类防护,进而选用具有针对性的防护措施,解决了重要目标在战时防护措施选择不完善、不合理的问题,有效地提升了战时火力发电厂的生存能力;通过模糊聚类模型实现分类防护,不仅有利于提高重要目标防护效率,而且使得防护资源少、力量弱,供需突出的问题得以改善,同时,在应对自然灾害等重大突发事件发生时,有助于保护发电厂的生产能力。通过案例给出战时某火力发电厂的具体防护措施,合理地解决了发电厂重要目标和关键部位的防护问题。 相似文献
173.
Two cage designs and fingernail clams(Sphaerium fabale) were evaluated for theirsuitability for use in in situ bioassays toassess the ecological condition of a stream andpredict ecological recovery potential. One design(referred to as tray design) was a modified plastictray about one-fourth full of small gravels andcovered with 1 mm fiberglass mesh. The second design(referred to as tube-plates) consisted of shortplexiglass tubes about one-third full of small gravelsand attached horizontally to a plexiglass plate. Oneend of each tube faced into the current; both endswere covered with mesh. Cages containing clams weredeployed at reference and impacted (test) sites forperiods of 70 to 135 d. Growth and survival were theprimary endpoints evaluated, but the tube-platesallowed isolation of individual clams so that natalityalso could be evaluated as an endpoint. Results ofbenthic macroinvertebrate surveys, performed foranother study, were included to help validate bioassayresults. Both cage designs yielded good quantitative,site-specific results for clam survival and growth;results for natality, though, were less conclusive. Clam survival and growth results were in good generalagreement with the results for the benthicmacroinvertebrate community surveys. At a site wherethe macroinvertebrate community was the mostdepauperate, clam mortality was always rapid. At asite where the condition of the macroinvertebratecommunity was only slightly less impacted than themost impacted site, clam growth was almost alwayssignificantly lower than at reference sites. Survivalof clams was significantly reduced in <25 d at thissite in some trials, but in other trials there waslittle mortality. At a minimally impacted site, clamsurvival was similar to that found at reference sites,and differences in clam growth were not detectableuntil after 40 to 50 d of exposure. The tube-platedesign was easier to use, allowed more flexibility inselection of response parameters, and required lesshandling time of test animals, thus, this was thepreferred design. Our results demonstrated thateither in situ bioassay design can be used toaugment monitoring and assessment programs. Their useas a predictor of ecological recovery, however,requires further evaluation. 相似文献
174.
奎屯市城市污水的处理现阶段采用一级处理后接生物稳定塘的处理工艺是较为适宜的,但要注意做好污水及处理水的排放监测,加强排水管理,今后要逐步完善为规范的二级处理工艺。对污水处理要制定切实可行的水污染防治规划,不拘泥于现有的排水方案和污水处理厂选址,在污水厂下游建设规范的污水库作为处理水资源化利用的必要措施。我区多数城市水污染防治路线与奎屯市有着相似性,对各城市污水处理方式及利用途径可采用此方法进行深入细致的研究论证,为未来城市污水的有效处理及无害化、资源化利用打下基础。 相似文献
175.
176.
Schröder P Scheer CE Diekmann F Stampfl A 《Environmental science and pollution research international》2007,14(2):114-122
Background, Aim and Scope
Numerous herbicides and xenobiotic organic pollutants are detoxified in plants to glutathione conjugates. Following this enzyme
catalyzed reaction, xenobiotic GS-conjugates are thought to be compartmentalized in the vacuole of plant cells. In the present
study, evidence is presented for long range transport of these conjugates in plants, rather than storage in the vacuole. To
our knowledge this is the first report about the unidirectional long range transport of xenobiotic conjugates in plants and
the exudation of a glutathione conjugate from the root tips. This could mean that plants possess an excretion system for unwanted
compounds which give them similar advantages as animals.
Materials and Methods:
Barley plants (Hordeum vulgare L. cv. Cherie) were grown in Petri dishes soaked with tap water in the greenhouse.
- Fluorescence Microscopy. Monobromo- and Monochlorobimane, two model xenobiotics that are conjugated rapidly in plant cells
with glutathione, hereby forming fluorescent metabolites, were used as markers for our experiments. Their transport in the
root could be followed sensitively with very good temporal and spatial resolution. Roots of barley seedlings were cut under
water and the end at which xenobiotics were applied was fixed in an aperture with a thin latex foil and transferred into a
drop of water on a cover slide. The cover slide was fixed in a measuring chamber on the stage of an inverse fluorescence microscope
(Zeiss Axiovert 100).
- Spectrometric enzyme assay. Glutathione S-transferase (GST) activity was determined in the protein extracts following established
methods. Aliquots of the enzyme extract were incubated with 1-chloro-2,4-dinitrobenzene (CDNB), or monochlorobimane. Controls
lacking enzyme or GSH were measured.
- Pitman chamber experiments. Ten days old barley plants or detached roots were inserted into special incubation chambers, either
complete with tips or decapitated, as well as 10 days old barley plants without root tips. Compartment A was filled with a
transport medium and GSH conjugate or L-cysteine conjugate. Compartments B and C contained sugar free media. Samples were
taken from the root tip containing compartment C and the amount of conjugate transported was determined spectro-photometrically.
Results:
The transport in roots is unidirectional towards the root tips and leads to exsudation of the conjugates at rates between
20 and 200 nmol min-1. The microscopic studies have been complemented by transport studies in small root chambers and spectroscopic
quantification of dinitrobenzene-conjugates. The latter experiments confirm the microscopic studies. Furthermore it was shown
that glutathione conjugates are transported at higher rates than cysteine conjugates, despite of their higher molecular weights.
This observation points to the existence of glutathione specific carriers and a specific role of glutathione in the root.
Discussion:
It can be assumed that long distance transport of glutathione conjugates within the plant proceeds like GSH or amino acid
transport in both, phloem and xylem. The high velocity of this translocation of the GS-X is indicative of an active transport.
For free glutathione, a rapid transport-system is essential because an accumulation of GSH in the root tip inhibits further
uptake of sulfur. Taking into account that all described MRP transporters and also the GSH plasmalemma ATPases have side activities
for glutathione derivatives and conjugates, co-transport of these xenobiotic metabolites seems credible.
- On the other hand, when GS-B was applied to the root tips from the outside, no significant uptake was observed. Thus it can
be concluded that only those conjugates can be transported in the xylem which are formed inside the root apex. Having left
the root once, there seems to be no return into the root vessels, probably because of a lack of inward directed transporters.
Conclusions:
Plants seem to possess the capability to store glutathione conjugates in the vacuole, but under certain conditions, these
metabolites might also undergo long range transport, predominantly into the plant root. The transport seems dependent on specific
carriers and is unidirectional, this means that xenobiotic conjugates from the rhizosphere are not taken up again. The exudation
of xenobiotic metabolites offers an opportunity to avoid the accumulation of such compounds in the plant.
Recommendations and Perspectives:
The role of glutathione and glutathione related metabolites in the rhizosphere has not been studied in any detail, and only
scattered data are available on interactions between the plant root and rhizosphere bacteria that encounter such conjugates.
The final fate of these compounds in the root zone has also not been addressed so far. It will be interesting to study effects
of the exuded metabolites on the biology of rhizosphere bacteria and fungi. 相似文献
177.
Analysis of the nitrifying bacterial community in BioCube sponge media using fluorescent in situ hybridization (FISH) and microelectrodes 总被引:2,自引:0,他引:2
There is growing interest in the development of more cost-effective and retrofit technologies for the upgrade and expansion of existing wastewater treatment plants with extreme space constraints. A free-floating sponge media (BioCube) process, using a 24L lab scale reactor, was operated to study the nitrification profiles and microbial community. The COD removal efficiencies were maintained, at an average of 95%, with the mixed liquor suspended solids (MLSS) inside the BioCube sponge media maintained at 12,688mg/L. The nitrification removal efficiencies were between 92% and 100%, with an average value of 99%. From the results of microelectrode measurements, the ammonium ion concentration was found to rapidly decrease from the surface of the BioCube sponge media to a depth of 2mm due to chemical reactions carried out by ammonia oxidizing bacteria (AOB) species. Multi-fluorescence in situ hybridization (FISH) has been used to investigate the spatial distributions of various microbial activities within reactors. Microbial communities were targeted using different oligonucleotide probes specific to AOB and nitrite oxidizing bacteria (NOB). There were a large number of AOB populations, but these were not uniformly distributed in the biofilm compared to the NOB populations. 相似文献
178.
采用体外受精技术评价环境污染物 2 ,2’ ,4,4’ 和 3,3’ ,4,4’ 四氯联苯对小白鼠卵母细胞受精能力和 2 细胞胚胎发育的毒性作用 .实验结果表明 :ρ(PCB) =0 .1,1.0 ,10 .0mg/mL的 2 ,2’ ,4,4’ 和 3,3’ ,4,4’ 四氯联苯均显著降低小白鼠卵母细胞的受精能力 ;ρ(PCB) =1.0 ,10 .0mg/mL的 2 ,2’ ,4,4’ 和 3,3’ ,4,4’ 四氯联苯使卵母细胞的退化率和 2 细胞的畸形率显著增加 ;两种四氯联苯对小白鼠卵母细胞体外受精能力、退化率和 2 细胞胚胎的畸形率无统计差异 .表 2参 2 5 相似文献
179.
180.
黄河下游历史泥沙灾害的宏观特征及其与流域因素和人类活动的关系(Ⅱ):—人类活动、历史地震及地形因子的影响 总被引:2,自引:1,他引:1
以历史上黄河下游的决溢频率为泥沙灾害的代用指标,研究了人类活动,历史地震及地形因子对黄河下游历史泥沙灾害的影响,研究表最,人类活动是影响黄河下游泥沙灾害的重要因素,历史上人口的增加使下游决溢频率增大,人口低谷与决溢频率的低值时段相应,历史上农牧交错带的南移与下游决溢频率的减小相伴发生。北移则导致决溢频率的增大,历史地震对黄河下游历史泥沙灾害有一定的影响,黄河下游历史泥沙灾害表现出明显的空间分异,这种分异与平原地貌条件的沿程变化有密切的关系。 相似文献