Conversion characteristics and mechanism analysis of gaseous dichloromethane degraded by a VUV light in different reaction media

The photodegradation of gaseous dichloromethane (DCM) by a vacuum ultraviolet (VUV) light in a spiral reactor was investigated with different reaction media and initial concentrations. Through the combination of direct photolysis, O₃ oxidation and HO. oxidation, DCM was ultimately mineralized into inorganic compounds (such as HCl, CO₂, H₂O, etc.) in the air with relative humidity (RH) of 75%-85%. During the photodegradation process, some small organic acids (including formic acid, acetic acid) were also detected and the intermediates were more soluble than DCM, providing a possibility for its combination with subsequent biodegradation. Based on the detected intermediates and the confirmed radicals, a photodegradation pathway of DCM by VUV was proposed. With RH 75%-80% air as the reaction medium, the DCM removal followed the second-order kinetic model at inlet concentration of 100-1000 mg/m³. Kinetic analysis showed that the reaction media affected the kinetic constants of DCM conversion by a large extent, and RH 80% air could cause a much lower half-life for its conversion. Such results supported the possibility that VUV photodegradation could be used not only for the mineralization of DCM but also as a pretreatment before biodegradation.     

高氟地下水形成的组态分析——以豫东平原区为例

高氟地下水的形成机理研究是目前相关理论研究的关键问题,文章在系统思想指导下将传统的水化学类型分类方法进行改进,以组态分析的方法进行形成机理研究,得出以下结论:(1)高氟地下水的形成是多因子协同作用的结果;(2)作为非线性系统,高氟地下水的形成是个多态问题,就某一个区段而言是一个"暂态",一直处于多态的变化过程中,在此过程中各个因子相互作用形成多组态;(3)Na+>Ca2+型的水化学组态的高氟率(平均51%)明显大于Na+相似文献   

Interannual variability of carbon cycle implied by a 2-d atmospheric transport model

A 2-dimensional atmospheric transport model is deployed in asimplified CO2 inverse study. Calculated carbon flux distribution for the interval from 1981 to 1997 confirms the existence of a terrestrial carbon sink in mid-high latitude area of North Hemisphere. Strong interannual variability exists in carbon flux patterns, implying a possible link with ENSO and other natural episodes such as Pinatubo volcano eruption in 1991. Mechanism of this possible link was investigated with statistic method. Correlation analysis indicated that in North Hemisphere, climatic factors such as temperature and precipitation, to some extend, could influence the carbon cycle process of land and ocean, thus cause considerable change in carbon flux distribution. In addition, correlation study also demonstrated the possible important role of Asian terrestrial ecosystems in carbon cycle.     

Electrochemical oxidation of polyethylene glycol in electroplating solution using paraffin composite copper hexacyanoferrate modified (PCCHM) anode

Electrochemical oxidation of polyethylene glycol (PEG) in an acidic(pH 0.18 to 0.42) and high ionic strength electroplating solution was investigated. The electroplating solution is a major source of wastewater in the printing wiring board industry. A paraffin composite copper hexacyanoferrate modified(PCCHM) electrode was used as the anode and a bare graphite electrode was used as the cathode. The changes in PEG and total organic carbon (TOC) concentrations during the course of the reaction were monitored. The efficiency of the PCCHM anode was compared with bare graphite anode and it was found that the former showed significant electrocatalytic property for PEG and TOC removal. Chlorides present in the solution were found to contribute significantly in the overall organic removal process. Short chain organic compounds like acetic acid, oxalic acid, formic acid and ethylene glycol formed during electrolysis were identified by HPLC method. Anode surface area and applied current density were found to influence the electro-oxidation process, in which the former was found to be dominating. Investigations of the kinetics for the present electrochemical reaction suggested that the two stage first-order kinetic model provides a much better representation of the overall mechanism of the process if compared to the generalized kinetic model.     

生态风险与生态安全的评价方法及前景

各种生态环境问题的严重后果引起了人们对环境与生态的重视,并催生了生态风险与生态安全评价.为了更好地进行这两方面的评价,首先分别综述生态风险和生态安全评价的发展进程,突出主要研究方法的介绍,由此总结生态风险评价与生态安全评价的关系以及生态风险与生态安全评价的发展趋势.生态风险评价主要有健康危险度法、环评指数法、景观生态法、空间统计或地统计法、相对风险模型等方法;生态安全评价主要有综合指数法、景观生态法、生态承载力和生态足迹方法、突变级数等方法.生态风险与生态安全评价是从相反的角度研究生态系统的状况和潜在威胁,生态风险评价偏重细节分析,生态安全评价偏重整体分析.空间和时间尺度的扩大、评价方法的改进、评价标准的制定和评价的可信性检验都是生态风险评价与生态安全评价的发展趋势.     

中外灭火防护服标准对比研究

通过对我国灭火防护服外层材料防火阻燃性能、防护服隔热性能、耐静水压性能及透水蒸汽性、反光带性能标准与欧美国家灭火防护服标准中具体技术指标的比较分析,指出我国灭火防护服标准与欧美国家的差距;提出我国灭火防护服装标准修订的建议。     

胜利油田推行安全经济管理的可行性分析

社会主义市场经济形势,决定了安全生产工作实行经济管理的必然性和可行性。安全经济管理效益有"滞后效应"的"隐形"性的特点,我们在实践操作中,不但要关心采取哪一种安全管理方案或措施所获得的安全水平最高,减少事故的效果最好,而且也要研究哪种方案或措施能够实现最省时、所投入的费用最少、达到的安全效果最好。实际上是把安全经济管理当作一种投资活动,怎样通过最小的投入获取最大化的投资收益。我们既要研究直接效果和间接效果,还要研究近期效果和远期效果;不仅要从局部单位出发计算经济效果,还要从全企业整体出发计算近期和远期的经济效果。在胜利油田推行安全经济管理应搞好"三同时"管理、开展安全管理经济评价、运用经济手段加强安全管理等工作。我们应建立胜利油田安全经济管理效益评价体系,寻找提高油田安全经济管理效益的新途径。     

生态农业模式的环境经济学分析及政策研究

从环境经济学角度分析生态农业模式,并以此为基础提出适当的环境经济政策调控手段促进其发展。通过案例（四川省大足县稻田养鱼生态模式）分析研究,作者试图建立一种以环境经济学分析为工具,寻求适当的生态农业发展环境经济促进政策的理论方法框架。      

Ecological recovery of vegetation at a former industrial sludge basin and its implications to phytoremediation

Examination of a former industrial sludge basin containing organic pollutants showed that the basin had undergone substantial ecological recovery through natural forces following the removal of surface water in 1982. Conventional phases of ecological recovery (plant invasion and succession) have occurred, but the structure of the biodiverse plant community (51 species and 22 families) was different from that at a recovering non-polluted disturbed site. Three plant species (Bermuda grass, mulberry, and sunflower) believed to be early invaders of the basin still persist in large numbers indicating that these species are well suited to cope with normal environmental stresses at this area (i.e. seasonal drought and flood) as well as organic pollutants. There was an indication that early invaders of the site fostered disappearance of contaminants thereby creating more favorable conditions for a broader spectrum of plants to grow. Vegetation analyses of naturally vegetated hazardous waste sites hold promise as a screening device for identifying plant species and management practices worthy of further phytoremediation investigations.     

无污泥化生物技术在真丝染色综合废水处理中的研究及应用

本文主要对真丝染色综合废水Ａ／Ｏ处理中所产生的污泥进行无污泥化生物处理的研究,并把技术运用在日处理９００ｔ／ｄ的综合废水生化处理装置上,设施经四年连续运行表明：出水ｐＨ＝７． ３６,ＳＳ＝４８ｍｇ／１,ＣＯＤｃｒ＝９５ｍｇ／１,ＢＯＤ５＝３８ｍｇ／１,ＮＨ３－Ｎ＝１８ ．８ｍｇ／１,出水水质指标全部达到国家规定的排放标准,该技术不仅解决了污泥的难治理问题,而且利用生物技术彻底解决了污泥的二次污染问题,还节约了可观的运行费用和投资费用,并提高了Ａ／Ｏ的处理效果。