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91.
Pd/CZ/Al2O3催化剂的制备、表征与三效催化性能 总被引:6,自引:0,他引:6
以共浸渍法制得的氧化铝负载铈锆固溶体为载体,并浸渍贵金属Pd得到了Pd/CZ/Al2O3催化剂.实验结果表明,该催化剂在老化前后都表现出良好的三效催化活性,新鲜样品Pd/CZ/Al2O3活性与Pd/CZ相当,老化后样品前者优于后者.结合XRD,BET,TPR等表征手段,讨论了Pd/CZ/Al2O3的催化活性特别是高温老化后活性与其组成结构之间的内在关系,揭示了其老化后仍具有较高活性的主要原因在于保持了Pd与CZ/Al2O3复合载体之间的强相互作用(SMSI). 相似文献
92.
上海城市土地利用转变类型及其空间关联分析 总被引:15,自引:0,他引:15
基于多时段TM遥感影像资料,通过地图代数和空间关联分析、相邻度分析等空间分析手段的综合应用,论文对上海地区近10年来城市土地利用变化类型、形成过程和相关空间机制进行了研究,结果表明:①近10年来上海城市土地利用扩展经历了“单核扩展”模式为主(1987~1990年)到“单核扩展”、“多核扩展”与“点-轴”扩展模式并存(1990~1995年),直至“多核扩展”及“点-轴”等复杂扩展模式为主(1995~2000年)的变化过程,导致上海中心城区和郊县城镇规模急剧扩张,交通干道沿线区域城市化过程明显增强,并形成整个上海地区城市化网络结构;②面积贡献率较大、转变频率较低的城市土地利用变化类型,与其他类型之间具有较高的关联度和空间亲和性,构成中心城区或卫星城、郊区城镇的扩展核心;③面积贡献率较低的类型,其转变频率较高,分布零散,构成扩展核的外围部分,这些城市周边地区存在一定程度紊乱、不合理的土地利用、开发活动;④城市化过程的内在空间机制与土地利用类型的面积和转变频率有密切关系。在更精细的尺度上依据转变频率划分的类别在一定程度上能更好体现城市土地利用变化类型的空间分异,及其作为宏观驱动机制的社会经济因子所具有的空间差异性。 相似文献
93.
Tyler Mehler W Schuler LJ Lydy MJ 《Environmental pollution (Barking, Essex : 1987)》2008,152(1):217-224
The joint toxicity of chlorpyrifos and atrazine was compared to that of chlorpyrifos alone to discern any greater than additive response using both acute toxicity testing and whole-body residue analysis. In addition, acetylcholinesterase (AChE) inhibition and biotransformation were investigated to evaluate the toxic mode of action of chlorpyrifos in the presence of atrazine. The joint toxicity of atrazine and chlorpyrifos exhibited no significant difference in Lepomis macrochirus compared to chlorpyrifos alone; while studies performed with Pimephales promelas and Chironomus tentans, did show significant differences. AChE activity and biotransformation showed no significant differences between the joint toxicity of atrazine and chlorpyrifos and that of chlorpyrifos alone. From the data collected, the combination of atrazine and chlorpyrifos pose little additional risk than that of chlorpyrifos alone to the tested fish species. 相似文献
94.
Summary. Larvae of Trichoplusia ni Hübner (Lepidoptera: Noctuidae) that ingested latex from Asclepias curassavica L. (Asclepiadaceae) often regurgitated and convulsed with spasms before becoming immobile and unresponsive. Some larvae required
over a day to recover sufficiently to feed. Latices from four other plant species in three families were all deterrent, but
none caused detectable poisoning. The toxicity of A. curassavica latex was evidently due to cardenolides because pure cardenolides had similar effects when ingested by T. ni. Other species of noctuid caterpillars (Rachiplusia ou Guenée, Anagrapha falcifera Kirby, and Autographa precationis Guenée) sometimes also suffered spasms and temporary immobility when fed A. curassavica latex. A more distantly related noctuid, Spodoptera ornithogalli, was deterred by the latex, but showed no overt physiological responses at the dosage tested. T. ni larvae failed to develop on intact leaves of A. curassavica, on leaves with latex canals deactivated by midrib severance, and on excised leaves. Similarly, larvae reared on excised
A. syriaca L. leaves to the final instar died when transferred to A. curassavica leaves with either intact or severed midribs. The final instar larvae sometimes suffered from spasms and immobility even
when confined on leaves with depressurized canal systems. Evidently, cardenolides stored outside the latex system suffice
to poison larvae. We conclude that cardenolides in A. curassavica have potent physiological effects on some generalist caterpillars and that the presence of these compounds both inside and
outside laticifers effectively protects the plant.
Received 30 June 1999; accepted 18 October 1999 相似文献
95.
96.
在考虑流固耦合和断层活动作用的情况下,应用ADINA中流固耦合分析求解器ADINA-FSI,建立了埋地管道破坏分析的有限元模型,介绍了固体模型和流体模型的建模过程以及流固耦合计算过程、断层位移荷载加载和约束的实现以及模型参数选择等。依据计算结果,分析了管内介质及流速等参数对管道破坏的影响。管道内输送的介质密度和流速越大,管道越易破坏,故在埋地管道设计中应充分考虑管内介质的密度与流速。针对计算结果,提出了几点认识和建议。 相似文献
97.
The complex capacity of different types of organic matters (OMs) for Cu was quantitatively studied by simulation experiments using different adsorbents prepared from the sediment in Taihu Lake. The free Cu was measured with ion selective electrode (ISE) and complex capacity was calculated using a conditional formation constant model. The result indicated that the complex capacity was 0.048 mmol·g-1, 0.009 and 0.005 mmol.g-1for raw sediment, sediment without DOM, sediment without insoluble organic matters but with DOM and sediment without OM. Insoluble organic matter played a major role in the sorption of Cu in sediment and it can adsorb most Cu from water column. In the solution, Cu mainly existed as a complex with DOM and the DOM-Cu complexation capacity was 327.87 mg. g-1. The change of TOC and pH indicated ion-exchange in the interaction between free Cu and DOM. When the Cu concentration in the experiment reached the complex capacity of DOM, precipitation was the major mechanism to remove Cu from water phase, which was observed from UV absorbance change of DOM, that is, its aromaticity increased while molecular weight decreased. The desorption result indi- cated that DOM was more capable of desorbing Cu from adsorbents without OM than adsorbent with OM. The desorbed quantity with DOM was 1.65, 1.78 and 2.25 times higher than that with water for adsorbents without OM, raw adsorbents (sediment) and adsorbents without DOM. 相似文献
98.
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