全文获取类型
收费全文 | 3256篇 |
免费 | 210篇 |
国内免费 | 751篇 |
专业分类
安全科学 | 355篇 |
废物处理 | 85篇 |
环保管理 | 312篇 |
综合类 | 1913篇 |
基础理论 | 619篇 |
环境理论 | 1篇 |
污染及防治 | 270篇 |
评价与监测 | 205篇 |
社会与环境 | 243篇 |
灾害及防治 | 214篇 |
出版年
2024年 | 8篇 |
2023年 | 40篇 |
2022年 | 78篇 |
2021年 | 82篇 |
2020年 | 68篇 |
2019年 | 74篇 |
2018年 | 93篇 |
2017年 | 108篇 |
2016年 | 127篇 |
2015年 | 139篇 |
2014年 | 160篇 |
2013年 | 326篇 |
2012年 | 200篇 |
2011年 | 247篇 |
2010年 | 172篇 |
2009年 | 198篇 |
2008年 | 122篇 |
2007年 | 228篇 |
2006年 | 237篇 |
2005年 | 191篇 |
2004年 | 131篇 |
2003年 | 187篇 |
2002年 | 149篇 |
2001年 | 148篇 |
2000年 | 101篇 |
1999年 | 86篇 |
1998年 | 85篇 |
1997年 | 68篇 |
1996年 | 63篇 |
1995年 | 74篇 |
1994年 | 48篇 |
1993年 | 34篇 |
1992年 | 41篇 |
1991年 | 20篇 |
1990年 | 16篇 |
1989年 | 6篇 |
1988年 | 18篇 |
1987年 | 9篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 10篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1973年 | 2篇 |
排序方式: 共有4217条查询结果,搜索用时 512 毫秒
221.
研究了采用柴油低温临界吸收法回收装车挥发油气的效果。实验结果表明:按装车挥发油气中的总烃体积分数为20.88%、装车挥发油气流量为280 m3/h、年运行时间为2 668 h计,装置年回收油气量为291 t,装置年最大运行功率为206.770 MW,装置投资回收期为3 a;处理后净化气中的总烃体积分数为1.24%,排放质量浓度低于25 g/m3,油气回收率达95%。处理后净化气满足GB 20950—2007《储油库大气污染物排放标准》,取得了较好的环保效益和经济效益。 相似文献
222.
利用高压塑片法制备掺杂镧和活性炭以及聚四氟乙烯(PTFE)的新型二氧化铅电极,采用X衍射(XRD),循环伏安曲线(CV),扫描电镜(SEM)等手段对电极性能进行表征,研究了其电催化处理有机染料废水(亚甲基蓝)的降解效果,并对反应机理进行了相关研究。研究表明,该电极具有良好的抗腐蚀能力,对亚甲基蓝具有较好的降解效果。通过与普通二氧化铅电极比较,该电极在染料脱色和去除COD方面都有较明显优势,显示出较好的工业应用前景。 相似文献
223.
224.
225.
226.
Herranz M Romero LM Idoeta R Olondo C Valiño F Legarda F 《Journal of environmental radioactivity》2011,102(11):987-994
In this paper the inventory of 90Sr in 34 points distributed along the Spanish peninsular territory is presented. Obtained values range between 173 Bq/m2 and 2047 Bq/m2. From these data set and those 137Cs data obtained in a previous work the 137Cs/90Sr activity ratio has been established, laying this value between 0.9 and 3.6. Also the migration depth of both radionuclides has been analysed obtaining for 137Cs an average value 57% lower than that obtained for 90Sr.Additionally, this paper presents the results obtained in 11 sampling points in which the activity vertical profile has been measured. These profiles have been analysed to state the behaviour of strontium in soils and after, by using a convective-diffusive model, the parameters of the model which governs the vertical migration of 90Sr in the soil, v (apparent convection velocity) and D (apparent diffusion coefficient) have been evaluated. Mean values obtained are 0.20 cm/year and 3.67 cm2/year, respectively. 相似文献
227.
Phthalate exposure was found to be associated with endocrine disruption, respiratory effects, reproductive and developmental toxicity. The intensive use of plastics may be increasing the exposure to phthalates in Taiwanese population, particularly for young children.We studied phthalate metabolites in pregnant women and their newborns in a prospective cohort from a medical center in Central Taiwan. One hundred maternal urine samples and 30 paired cord blood and milk samples were randomly selected from all of participants (430 pregnant women). Eleven phthalate metabolites (MEHP, 5OH-MEHP, 2cx-MEHP, 5cx-MEPP, 5oxo-MEHP, MiBP, MnBP, MBzP, OH-MiNP, oxo-MiNP, and cx-MiNP) representing the exposure to five commonly used phthalates (DEHP, di-isobutyl phthalate (DiBP), DnBP, BBP, DiNP) were measured in urine of pregnant women, cord serum and breast milk after delivery, and in urine of their children. Exposure was estimated with excretion factors and correlation among metabolites of the same parent compound. Thirty and 59 urinary samples from 2 and 5 years-old children were randomly selected from 185 children successfully followed.Total urinary phthalate metabolite concentration (geometric mean, μg L−1) was found to be higher in 2-years-olds (398.6) and 5-years-olds (333.7) than pregnant women (205.2). Metabolites in urine are mainly from DEHP. The proportion of DiNP metabolites was higher in children urine (4.39 and 8.31%, ages 2 and 5) than in adults (0.83%) (p < 0.01). Compared to urinary levels, phthalate metabolite levels are low in cord blood (37.45) and milk (14.90). DEHP metabolite levels in women’s urine and their corresponding cord blood are significantly correlated. Compared to other populations in the world, DEHP derived metabolites in maternal urine were higher, while phthalate metabolite levels in milk and cord blood were similar. The level of phthalate metabolites in milk and cord blood were comparable to those found in other populations. Further studies of health effects related to DEHP and DiNP exposure are necessary for the children. 相似文献
228.
We measured the concentration of each polychlorinated biphenyl (PCB) congener in whole blood, plasma and blood cells, and investigated the distribution of PCBs in human blood using high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS). The PCB concentrations in plasma and whole blood in terms of lipid concentrations were almost equal, with a correlation coefficient of r = 0.972. In the blood, the ratio of PCBs in blood cells to those in plasma was generally about 1:9 and the congener distribution patterns in blood cells and plasma were similar.We performed verification of a simple mass screening method by obtaining information on the main PCB congeners for investigations on human accumulation and exposure. The total concentration of the seven PCB congeners (UNEP-7) proposed to the United Nations Environment Programme (UNEP) by Muir and Morita was about 50% of the total concentration of all PCB congeners, and UNEP-30 was about 80%. The seven main congeners in the blood (MCB-7) showed a value that was about 60%, and MCB-30 showed a value that was about 90%. Determinations with the main congeners in the blood showed a correlation of r = 0.990 or more between the main eight congeners (MCB-7 plus #74) and the total PCB concentration for all congeners. The results suggest that, although total PCB concentration can be effectively estimated from the main seven congeners, the main eight congeners would be preferable, and that the use of these congeners in the simple mass screening method would be effective for populations in areas uncontaminated by PCBs. 相似文献
229.
Foliar uptake of airborne lead is one of the pathways for Pb accumulation in plant organs. However, the approximate contributions of airborne Pb to plant organs are still unclear. In the present study, aerosols (nine-stage size-segregated aerosols and total suspended particulates), a wild plant species (Aster subulatus) and the corresponding soils were collected and Pb contents and isotopic ratios in these samples were analyzed. Average concentration of Pb was 96.5 ± 63.5 ng m−3 in total suspended particulates (TSP) and 20.4 ± 5.5 ng m−3 in the fine fractions of size-segregated aerosols (SSA) (<2.1 μm), higher than that in the coarser fractions (>2.1 μm) (6.38 ± 3.71 ng m−3). Enrichment factors show that aerosols and soils suffered from anthropogenic inputs and the fine fractions of the size-segregated aerosols enriched more Pb than the coarse fractions. The order of Pb contents in A. subulatus was roots > leaves > stems. The linear relationship of Pb isotope ratios (206Pb/207Pb and 208Pb/206Pb) among soil, plant and aerosol samples were found. Based on the simple binary Pb isotopic model using the mean 206Pb/207Pb ratios in TSP and in SSA, the approximate contributions of airborne Pb into plant leaves were 72.2% and 65.1%, respectively, suggesting that airborne Pb is the most important source for the Pb accumulation in leaves. So the combination of Pb isotope tracing and the simple binary Pb isotope model can assess the contribution of airborne Pb into plant leaves and may be of interest for risk assessment of the exposure to airborne Pb contamination. 相似文献
230.
Reversed association between levels of prostate specific antigen and levels of blood cadmium and urinary cadmium 总被引:1,自引:0,他引:1
Prostate cancer associated with cadmium exposure may indicate a link between prostate specific antigen (PSA) and levels of blood cadmium (BCd) and urinary cadmium (UCd). Thus, these associations were investigated. We recruited 295 men, 50 years of age and above from a health check-up program at a health center as subjects of the study. They completed a self-reported questionnaire and provided fasting samples of blood and urine for cadmium assay. The assay was performed using atomic absorption spectrophotometry. Blood samples were also collected for the assays of total cholesterol and high-density lipoprotein measures. The means of BCd and UCd increased with age and the means of all subjects were 1.19 ± 1.04 μg L−1 and 1.37 ± 1.76 μg g−1 creatinine, respectively. The PSA levels were positively associated with the lipid levels, but reversely associated with BCd and UCd levels. The multivariate logistic regression analysis showed that men with PSA ? 4.0 ng mL−1 had an odds ratio (OR) of 0.4 (95% CI = 0.1-0.9) to have BCd > 0.49 μg L−1, and an OR of 0.4 (95% CI = 0.2-1.0) to have UCd > 0.45 μg g−1 creatinine. In conclusion, the PSA levels are reversely associated with BCd and UCd levels. 相似文献