全文获取类型
收费全文 | 6820篇 |
免费 | 918篇 |
国内免费 | 4650篇 |
专业分类
安全科学 | 290篇 |
废物处理 | 390篇 |
环保管理 | 679篇 |
综合类 | 6991篇 |
基础理论 | 1323篇 |
环境理论 | 4篇 |
污染及防治 | 1886篇 |
评价与监测 | 393篇 |
社会与环境 | 416篇 |
灾害及防治 | 16篇 |
出版年
2024年 | 97篇 |
2023年 | 373篇 |
2022年 | 520篇 |
2021年 | 503篇 |
2020年 | 457篇 |
2019年 | 478篇 |
2018年 | 474篇 |
2017年 | 518篇 |
2016年 | 644篇 |
2015年 | 593篇 |
2014年 | 556篇 |
2013年 | 913篇 |
2012年 | 835篇 |
2011年 | 837篇 |
2010年 | 562篇 |
2009年 | 485篇 |
2008年 | 408篇 |
2007年 | 497篇 |
2006年 | 493篇 |
2005年 | 328篇 |
2004年 | 265篇 |
2003年 | 298篇 |
2002年 | 228篇 |
2001年 | 196篇 |
2000年 | 153篇 |
1999年 | 143篇 |
1998年 | 102篇 |
1997年 | 90篇 |
1996年 | 81篇 |
1995年 | 55篇 |
1994年 | 64篇 |
1993年 | 46篇 |
1992年 | 31篇 |
1991年 | 20篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
71.
《环境科学学报(英文版)》2023,35(3):309-318
Accurate quantification of dissolved organic nitrogen (DON) has been a challenge due to the cumulative analytical errors in the conventional method via subtracting dissolved inorganic nitrogen species (DIN) from total dissolved nitrogen (TDN). Size exclusion chromatography coupled with an organic nitrogen detector (SEC-OND) has been developed as a direct method for quantification and characterization of DON. However, the applications of SEC-OND method still subject to poor separations between DON and DIN species and unsatisfied N recoveries of macromolecules. In this study, we packed a series of SEC columns with different lengths and resin materials for separation of different N species and designed an independent vacuum ultraviolet (VUV) oxidation device for complete oxidation converting N species to nitrate. To guarantee sufficient N recoveries, the operation conditions were optimized as oxidation time ≥ 30 min, injection mass (sample concentration × injection volume) < 1000 µL × mg-N/L for macromolecular proteins, and neutral pH mobile eluent. The dissolved O2 concentration in SEC mobile phase determined the upper limit of VUV oxidation at a specific oxidation time. Compared to conventional HW50S column (20 × 250 mm), HW40S column (20 × 350 mm) with mobile phase comprising of 1.5 g/L Na2HPO4·2H2O + 2.5 g/L KH2PO4 (pH = 6.85) could achieve a better separation of DON, nitrite, nitrate, and ammonia. When applied to river water, lake water, wastewater effluent, groundwater, and landfill leachate, the SEC-OND method could quantify DON as well as DIN species accurately and conveniently even the DIN/TDN ratio reached 0.98. 相似文献
72.
Yang Zhang Tianyi Zhao Yu Yan Bian Zhou Xuezhen Zhong Xiaoyu Hu Lijia Zhang Peng Huo Kang Xiao Yuanxun Zhang 《环境科学学报(英文版)》2023,35(2):835-845
Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future. 相似文献
73.
74.
75.
温泉宾馆室内PM_(10),PM_(2.5),CO_2和~(222)Rn的研究 总被引:1,自引:0,他引:1
对广东省 4座温泉宾馆室内外氡(222Rn)浓度和温泉水氡浓度进行研究,同时利用便携式探测器对室内外 PM10,PM2.5,CO2和CO 等污染物暴露水平进行直接测定.结果表明,温泉宾馆室内使用温泉水时氡浓度明显高于广东省室内平均氡浓度.除 CO 外,室内 PM10,PM2.5 和CO2 浓度都较高,其中 PM10 和 CO2 的超标率分别达到 67%和 89%.说明温泉宾馆室内不仅存在一般性污染物,而且存在高浓度的 Rn. 222 相似文献
76.
77.
本文对国内外下古生界海相碳酸盐岩研究的四个主要方面作了总结:(1)有机质丰度及其影响因素;(2)有机质赋存形式;(3)下古生界海相碳酸盐岩有机质丰度和生烃潜力恢复方法和原理;(4)下古生界海相碳酸盐岩热成熟度研究。这四个方面是评价我国下古生界海相碳酸盐岩勘探前景至关重要的因素,也是近年来我们研究下古生界海相碳酸盐岩的热点和难点问题。 相似文献
78.
活性炭厌氧流不处理毒性有机废水存在问题,对含有活性炭能吸附而生物难降解成份的废水,通过定期替换少量活性炭、能维持工艺的稳定运行。 相似文献
79.
80.
超临界二氧化碳流体萃取土壤中有机污染物的研究进展 总被引:4,自引:0,他引:4
就近年来人们利用超临界二氧化碳流体对有机污染物污染的土壤所做的研究工作以及所取得的成果进行了总结。 相似文献