竹丝生物膜反应器修复校园景观水体的实验研究

以竹丝作为填料而组建的接触氧化生物膜工艺对校园景观水体进行易位修复,通过设置5个不同工况以探明竹丝载体在修复轻度污染水体的特性,研究表明:当进水CODMn、氨氮和浊度分别为7.79~24.32 mg/L、1.36~11 mg/L和0.63~33.11 NTU的情况下,其去除率分别为10.57%~74.34%、-83.33%~57.55%和20.01%~100%,不同的运行工况对修复效果的影响不显著;系统在启动后的8 d内即可形成丰富成熟的生物相,而且竹丝上的细菌主要以短杆菌为主;竹丝生物膜反应器修复后的景观水体中的活细菌数量可减少1个数量级。竹丝上的亲水性基团和良好的生物亲和性以及从竹丝上脱落下来的零散竹丝纤维是竹丝填料生物膜快速形成的基础,宏观和微观"网捕"结构是该系统能在极短时间实现高效去除浊度、有机物和细菌等高分子物质的主要原因。     

Sun light degradation of 4-chloroaniline in waters and its effect on toxicity. A high performance liquid chromatography - Diode array - Tandem mass spectrometry study

This paper studies the degradation reactions that 4-chloroaniline can naturally undergo in waters for the action of sun light. 10.00 mg L⁻¹ 4-chloroaniline aqueous solution, without any addition of organic solvent, are undergone to photoirradiation under conditions that simulate sun light. The degradation pathway, followed by HPLC-DAD-MS/MS methods, is complex since the pollutant gives rise to many photoproducts: the predominant species are characterized by m/z values of 217 (P5) and 218 (P6) and are compatible with dimeric structures of 4-chloroaniline. Vibrio fischeri tests indicate that the photoproducts of 4-chloroaniline are characterized by a toxicity level significantly greater than the precursor.     

Elevated CO2 response of photosynthesis depends on ozone concentration in aspen

The effect of elevated CO₂ and O₃ on apparent quantum yield (?), maximum photosynthesis (P_max), carboxylation efficiency (V_cmax) and electron transport capacity (J_max) at different canopy locations was studied in two aspen (Populus tremuloides) clones of contrasting O₃ tolerance. Local light climate at every leaf was characterized as fraction of above-canopy photosynthetic photon flux density (%PPFD). Elevated CO₂ alone did not affect ? or P_max, and increased J_max in the O₃-sensitive, but not in the O₃-tolerant clone. Elevated O₃ decreased leaf chlorophyll content and all photosynthetic parameters, particularly in the lower canopy, and the negative impact of O₃ increased through time. Significant interaction effect, whereby the negative impact of elevated O₃ was exaggerated by elevated CO₂ was seen in Chl, N and J_max, and occurred in both O₃-tolerant and O₃-sensitive clones. The clonal differences in the level of CO₂ × O₃ interaction suggest a relationship between photosynthetic acclimation and background O₃ concentration.     

弹性系数在“绿色GDP”核算研究中的应用

本文总结了四川省在"中国环境经济核算体系总体框架"下"绿色GDP"核算结果的局限性,进而提出了"绿色弹性系数"的概念,并比较分析了2005~2007年四川省各地区的"绿色弹性系数",有效地反映了环境污染负荷的变化与社会经济的发展相互制约的关系以及发展趋势和规律。     

基于Voronoi图的居民点空间分布特征研究——以甘肃省为例

采用GIS查询统计与Voronoi图CV值相结合的分析方法,通过计算点状目标的Voronoi多边形面积的变异系数(CV值)方法来分析点状目标的空间分布特征。分析结果表明,甘肃省有9个市、县为随机分布,其余市、县为集群分布,但总体上为集群分布。最近邻指数和CV值通过级差变换后,发现其存在相关性,相关系数为负值,表明两者之间存在负相关关系。     

云南省耕地生产效率的时空差异及影响因素

以第二次全国土地调查完成以来的2009~2013年为研究时段,在测算云南省16个州(市)的耕地生产效率基础上,综合运用ESDA技术、基尼系数等方法系统分析云南省耕地生产效率的时空差异,并构建计量经济模型研究影响不同区域耕地生产效率变化的主要因素。结果表明:(1)2009~2013年,云南省耕地生产效率呈总体上升趋势,但增幅逐年降低;效率低值地区增长明显,高值地区则并不显著;(2)云南省耕地生产效率区域差异呈缩小态势,并表现出由西南向东北递减的空间分布特征;(3)滇中、滇西南等粮食主产区受≤6°耕地面积比重、旱涝保收面积的影响较大,而滇东地区则更易受到6°坡耕地面积和人均GDP的影响,滇西北地区受≤6°耕地面积比重和人均GDP的影响显著。     

Size characterization of the associations between carbon nanotubes and humic acids in aqueous media by asymmetrical flow field-flow fractionation combined with multi-angle light scattering

This work focuses on the influence of humic acids (HAs) on the fate of carbon nanotubes (CNTs) in aqueous media. This influence was demonstrated by mixing CNT powder with HAs in aqueous solution in varying concentrations. The aqueous media containing HAs and CNTs were size-characterized by asymmetrical flow field-flow fractionation (AsFlFFF) coupled with multi-angle light scattering (MALS). This coupling yielded information concerning the size distribution of single- and multi-walled CNTs (SWCNTs and MWCNTs) and HAs under different physico-chemical conditions that can occur in environmental water. HAs can disperse individual CNTs in aqueous media. However, the difference in the physical structure between SWCNTs and MWCNTs leads to significant differences in the quantity of HA that can adsorb onto the nanotube surface and in the stability of the CNT/HA complex. Compared with MWCNTs, SWCNTs suspended in HAs are less affected by changing ionic strength with respect to stability and the amount suspended.     

Relevant parameters for assessing the environmental impact of some pyridinium, ammonium and pyrrolidinium based ionic liquids

Several physico-chemical properties relevant to determine the environmental impact of ionic liquids - aqueous solubility, octanol/water partition coefficient, chromatographically derived lipophilicity and infinite dilution diffusion coefficients in water - were measured in ionic liquids based on pyridinium, ammonium and pyrrolidinium cations with bis(trifluoromethylsulfonyl)imide anions. The influence of the presence of hydroxyl or ester groups in the physico-chemical properties of these liquids was checked. It appeared that the presence of functional oxygenated moieties reduces the lipophilicity of ionic liquids and so decreases the risk of bioaccumulation in environment.     

江苏省种粮补贴区域差异化理论与实证研究

粮食种植补贴是农业补贴的核心内容。从现行种粮补贴政策出发,构建了差异化情景下种粮补贴效率的理论命题,并认为差异化补贴更体现 “效率优先,兼顾公平”原则;在此基础上,构建了种粮补贴区域差异化指标体系及计算方法并对江苏省进行实证研究。结果发现：江苏省种粮补贴应呈现苏北>苏中>苏南的态势,最高值为总额的182%,分布在苏北地区,最低值为总额的117%,分布在苏南地区;各评价指标空间分布差异显著,补贴政策地区间指向应有所不同;最后提出差异控制系数θ,通过对θ的选择,可以较为有效的控制种粮补贴差异波动范围,为政策的制定提供简便的手段     

供水管网系统地震易损性风险评估

供水管网易损性风险评估就是通过识别和分析系统的易损性,找出管网中相对比较薄弱的部分,为确定安全策略和采取控制措施提供理论依据。借鉴网络脆弱性评估理论和方法,基于震后供水管网的连通性分析和水力分析结果,采用分层的分析方法,以管网的拓扑位置和节点服务特性作为影响管网易损性的因素,分配给各节点一定的权值,计算其易损性指标,采用定性与定量相结合的方法评判其易损性程度。对一实际管网进行地震易损性风险评估,说明了该方法的有效性与合理性。