全文获取类型
收费全文 | 1866篇 |
免费 | 194篇 |
国内免费 | 855篇 |
专业分类
安全科学 | 190篇 |
废物处理 | 166篇 |
环保管理 | 157篇 |
综合类 | 1473篇 |
基础理论 | 271篇 |
污染及防治 | 477篇 |
评价与监测 | 166篇 |
社会与环境 | 9篇 |
灾害及防治 | 6篇 |
出版年
2024年 | 9篇 |
2023年 | 21篇 |
2022年 | 51篇 |
2021年 | 49篇 |
2020年 | 76篇 |
2019年 | 72篇 |
2018年 | 67篇 |
2017年 | 78篇 |
2016年 | 100篇 |
2015年 | 142篇 |
2014年 | 167篇 |
2013年 | 210篇 |
2012年 | 203篇 |
2011年 | 182篇 |
2010年 | 138篇 |
2009年 | 162篇 |
2008年 | 111篇 |
2007年 | 188篇 |
2006年 | 174篇 |
2005年 | 125篇 |
2004年 | 91篇 |
2003年 | 85篇 |
2002年 | 75篇 |
2001年 | 70篇 |
2000年 | 49篇 |
1999年 | 43篇 |
1998年 | 50篇 |
1997年 | 39篇 |
1996年 | 21篇 |
1995年 | 9篇 |
1994年 | 9篇 |
1993年 | 22篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有2915条查询结果,搜索用时 15 毫秒
141.
好氧颗粒污泥膜生物反应器的运行特性 总被引:6,自引:0,他引:6
以人工合成模拟废水对好氧颗粒污泥膜生物反应器(MBR)的运行特性和膜污染进行了研究.结果表明:在HRT为6h,溶氧浓度为4~6mg.L-1,COD的容积负荷为7.24kg·(m3·d)-1的条件下,COD的去除率可达96%以上.当NH3-N的容积负荷为0.17kg·(m3·d)-1时,NH3-N的去除率可达60%.COD/N比的变化,对好氧颗粒污泥MBR的COD及NH3-N去除率基本没有影响.稳定运行过程时,MBR中好氧颗粒污泥浓度(MLSS)基本维持在14~16mg·L-1.较高的污泥浓度和颗粒污泥内部缺氧和厌氧环境的存在,使MBR中硝化和反硝化过程能同时存在.同时,比较了2种不同形态的活性污泥(颗粒污泥和絮状污泥)在MBR运行过程中膜通量的变化趋势,结果表明,颗粒污泥MBR膜通量的下降速度明显比絮状污泥MBR的下降速度慢很多,且通过空气反冲或用水清洗即可使通量基本恢复. 相似文献
142.
内置转盘式膜-生物反应器处理污水的工艺条件研究 总被引:2,自引:0,他引:2
对内置转盘式膜-生物反应器(SRMBR)处理污水工艺进行了研究.进水COD 160~368 mg/L时,出水COD在运行1d后降低到20 mg/L以下,去除率大于90%;转盘式膜组件的转速在0~25 r/min范围内,平衡膜通量随转速增大而快速增加,继续增大转速则平衡膜通量的增加变得不显著;在一定范围(0~1min)内延长停抽时间有助于缓解膜污染;SRMBR在较低的气水比(15∶1)下运行,也可达到较高的平衡膜通量.研究表明,SRMBR在最佳组合操作条件(转速为25r/min,抽/停为9min/1min,气水比为15∶1,抽吸压力为25kPa)下运行,其平衡膜通量高达53.75L/(m2·h). 相似文献
143.
好氧膜生物反应器的硝化性能研究 总被引:2,自引:0,他引:2
以含有高浓度氨氮的垃圾渗滤液为对象,针对好氧膜生物反应器的硝化性能进行了研究。结果表明:当进水氨氮<1000mg/L和负荷<1.5kgNH4+-N/m3d时,氨氮去除率保持在80%~99.7%之间,表明好氧MBR具有良好的硝化性能;硝酸菌在进水氨氮浓度>600mg/L时受到了抑制,而亚硝酸菌在进水氨氮浓度>1200mg/L时才受到抑制;在试验过程中,MBR污泥经历了由以异养细菌为主到自养细菌为主的转型过程。以硝化菌为主的污泥具有良好的沉淀性能,污泥的SV和SVI分别稳定在20%~30%之间和40~70mL/g之间。 相似文献
144.
Fenton反应可以氧化分解有机物,在反应中的关键氧化剂羟基自由基(HO·)是通过亚铁离子与过氧化氢作用生成的,因此,传统的Fenton氧化必须由外部添加过氧化氢.研究了一种新的方法,即采用Nafion膜固定化亚铁离子,并通过光催化反应提供Fenton氧化所需的过氧化氢,使得Fenton反应在不添加过氧化氢的条件下也能够连续进行.结果表明,以甲酸为代表有机物,该方法可以在不添加过氧化氢的条件下起到分解甲酸的作用.而且,通过对负载亚铁离子Nafion膜的再生,可以使该方法的降解能力保持在稳定的范围. 相似文献
145.
The paper is focused on studying how to convert rice husk and sawdust into liquid fuel. Rice husk, sawdust and their mixture were pyrolyzed at the temperature between 420℃ and 540℃, and the main product of liquid fuel was obtained. The experimental result showed that the yield of liquid fuel heavily depended on the kind of feedstock and pyrolysis temperature. In the experiments, the maximum liquid yields for rice husk, sawdust and their mixture were 56% at 465 ℃, 61% at 490℃ and 60% at 475℃ respectively. Analysis with GC-MS and other apparatus indicated that the liquid fuel is a complicated organic compound with low caloric value and can be directly used as fuel oil without any up-grading. As a crude oil, the liquid fuel can be refined to be vehicle oil. 相似文献
146.
AbstractThe roles of PM2.5-induced mitochondrial damage and oxidative stress on mast cell degranulation were examined in vitro. Mast cells were treated with suspensions of PM2.5 in Dulbecco’s modified Eagle’s medium at concentrations from 25 to 200?mg/L in the absence or presence of 10?mmol/L N-acetyl-L-cysteine. Biological effects and mitochondrial function were assessed by determining cell viability, β-hexosaminidase release, interleukin-4 secretion, reactive oxygen species generation, adenosine triphosphate production, potential alteration of mitochondrial membrane, and activities of mitochondrial electron transport chain complexes I and III. Exposure of mast cells to PM2.5 induced reduction of adenosine triphosphate production, collapse of mitochondrial membrane potential, and inhibition of the activity of complex III. Co-treatment of mast cells exposed to PM2.5 with N-acetyl-L-cysteine attenuated cytotoxicity and the production of reactive oxygen species, and decreased the release of β-hexosaminidase and interleukin-4. Evidently, PM2.5-induced oxidative stress plays an essential role in mitochondrial toxicity and mast cell activation. 相似文献
147.
建立了一种同时测定饮用水中22种邻苯二甲酸酯(PAEs)的高效液相色谱-三重四级杆/复合线性离子阱质谱方法:饮用水样品经针头过滤器过滤,选用Biphenyl液相色谱柱进行分离,以含0.1%甲酸的水溶液和含0.1%甲酸的甲醇溶液为流动相,电离模式为电喷雾正离子,选用多反应监测触发增强子离子扫描模式进行检测。结果表明,22种PAEs的灵敏度良好,定量限为0.001~0.1 μg/L。配制浓度为0.1~100.0 μg/L的混标溶液进行进样分析,分析结果显示,22种PAEs在该范围内的线性关系良好,相关系数均大于0.995,方法的平均回收率为82.9%~108.9%,相对标准偏差为0.9%~11.2%。同时,使用增强子离子扫描谱图进行搜库匹配,定性准确性高。该方法适用于饮用水中PAEs的检测。 相似文献
148.
149.
Many release problems involve two-phase releases of hazardous materials of superheated liquids with high energy into the atmosphere. Such accidents are accompanied by violent phase transition and form catastrophic flashing jets. In this work, experimental and theoretical analyses were conducted to investigate dynamic characteristics of flashing jet morphology and their dependence on pressure-decay dynamics under different storage pressures, superheats, and nozzle diameters. Flashing jet morphology and angle throughout two-phase releases were captured by a high-speed camera, and the corresponding source pressure in the superheated liquid tank was measured simultaneously. Results show that three typical phases, expansion, stabilization, and decay, are characterized throughout two-phase release based on the evolution of flashing jet morphology. The jet initially expands gradually due to the enhancement of phase transition intensity, and then keeps stable when the intensity reaches its maximum, and terminally decays rapidly due to the depletion of superheated liquid. Phase transition intensity at the nozzle exit is mainly controlled by the pressure-decay dynamics. Bubbles nucleation inception sites gradually move upstream of the nozzle during the pressure decay process increasing the phase transition intensity. The increase of storage pressure, superheat and nozzle diameter promotes the mechanical and thermodynamic effects on the jet breakup. The significant increase of mechanical and thermodynamic effects effectively accelerates droplets evaporation and further affects flashing jet morphology. 相似文献
150.
Aluminum powder was always chosen as an additive to improve the explosive performance. In this work, experiments were performed to investigate the lower flammability limit (LFL) of volatile liquid fuel-aluminum powder mixtures using a 20 L closed spherical stainless steel vessel at a temperature of 20 °C (293 K) and 40 °C (313 K). The volatile liquid fuels tested in the work were diethyl ether (DEE), epoxypropane (PO), n-pentane and n-hexane. DEE, PO and n-pentane are in the liquid phase at room temperature and can easily transition to the gas phase at 40 °C (313 K). Through a series of experiments carried out, it was found that the change in phase would affect the interaction between the components. Aluminum powder always has an inhibitory effect on the flammability of the mixtures when it is mixed with gas-phase fuels. The inhibition effect was most obvious when the aluminum powder concentration reached 200 g/m3. While the interaction between aluminum powder and liquid-phase volatile fuels was promotion and was influenced by the component proportion and the type of the volatile fuels. 相似文献