全文获取类型
收费全文 | 1866篇 |
免费 | 194篇 |
国内免费 | 855篇 |
专业分类
安全科学 | 190篇 |
废物处理 | 166篇 |
环保管理 | 157篇 |
综合类 | 1473篇 |
基础理论 | 271篇 |
污染及防治 | 477篇 |
评价与监测 | 166篇 |
社会与环境 | 9篇 |
灾害及防治 | 6篇 |
出版年
2024年 | 9篇 |
2023年 | 21篇 |
2022年 | 51篇 |
2021年 | 49篇 |
2020年 | 76篇 |
2019年 | 72篇 |
2018年 | 67篇 |
2017年 | 78篇 |
2016年 | 100篇 |
2015年 | 142篇 |
2014年 | 167篇 |
2013年 | 210篇 |
2012年 | 203篇 |
2011年 | 182篇 |
2010年 | 138篇 |
2009年 | 162篇 |
2008年 | 111篇 |
2007年 | 188篇 |
2006年 | 174篇 |
2005年 | 125篇 |
2004年 | 91篇 |
2003年 | 85篇 |
2002年 | 75篇 |
2001年 | 70篇 |
2000年 | 49篇 |
1999年 | 43篇 |
1998年 | 50篇 |
1997年 | 39篇 |
1996年 | 21篇 |
1995年 | 9篇 |
1994年 | 9篇 |
1993年 | 22篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有2915条查询结果,搜索用时 15 毫秒
281.
Mixtures of dense non-aqueous phase liquids (DNAPLs) trapped in the subsurface can act as long-term sources of contamination by dissolving into flowing groundwater. In general, the components of higher solubility are removed more quickly, thus altering the composition of the remaining DNAPL, and possibly leading to changes in its physical properties. Through the development of a simple compositional model, Roy et al. [J. Contam. Hydrol. 2002 (59) 163] showed that preferential dissolution of a mixed DNAPL could potentially result in changes in density and interfacial tension that could subsequently lead to remobilization of an initially static DNAPL pool. The laboratory experiments presented in this next paper provide a proof-of-concept for the previously presented theory, demonstrating and quantifying this process of remobilization. In addition, the experiments provide a data set for evaluation of the model presented by Roy et al. [J. Contam. Hydrol. 2002 (59) 163]. In the four experiments, a DNAPL pool comprised of tetrachloroethene and benzene was created as an open pool overlying glass beads within a water-saturated 2-D flow box. Experiments included rectangular and triangular pools. In each of the experiments, remobilization (as breakthrough) was observed more than 2 weeks after formation of the initial pool. During each experiment, the pool height declined as mass was lost by dissolution, while sampling indicated a decrease in the mole fraction of benzene, the more soluble component. Small protuberances formed along the bottom of the pool as its composition changed with time and the displacement pressure was achieved for various pore throats. Eventually one of the protuberances extended further, forming a finger (breakthrough). In general, the pool emptied as the finger proceeded further into the beads. It was also shown theoretically and experimentally that remobilization will occur sooner for pools with a triangular (pointing down), rather than rectangular, shape. The experimental results were simulated using the model developed by Roy et al. [J. Contam. Hydrol. 2002 (59) 163]. The model matched the observations well, suggesting that it accurately represents the primary mechanisms involved with natural remobilization under the conditions of the study. 相似文献
282.
283.
焚烧法处理环己酮生产中的皂化液 总被引:1,自引:0,他引:1
用环已烷氧化生产环已酮的生产过程中会产生大量的皂化液 ,它含有大量的有害物质 ,是一种难处理的高污染有机废水。某石化厂在借鉴造纸行业的黑液焚烧技术的基础上 ,采用焚烧法来处理皂化液 ,并得到副产蒸气和回收了碳酸钠 ,实现了皂化液的无害化与资源化 ,具有良好的社会效益、环境效益和经济效益 ,每处理 1t皂化液可盈利 10 0~ 2 0 0元 相似文献
284.
285.
286.
应用错流式动态膜-生物反应器(CDMBR)对己内酰胺废水进行了180 d的实验,实验过程中测定反应器的膜出水和上清液的水质,并对污泥进行了耗氧呼吸速率测定.结果表明,上清液COD一直保持在100mg/L以下,而膜出水的则保持在50 mg/L以下,膜对上清液的COD去除率达50%,而对氮的去除没有贡献.可溶性细胞产物(SMP)在反应器内容易积累,停留足够的时间后能被生物降解.通过投加抑制剂测定耗氧呼吸速率,发现异养菌、硝化细菌和亚硝化细菌的活性由于F/M的降低和SMP积累受到一定的抑制,但不影响系统的处理效率.跨膜压力、膜面流速越大,通量衰减得也就越快. 相似文献
287.
膜生物反应器在污水处理中的应用现状及展望 总被引:2,自引:0,他引:2
综述了膜生物反应器(MBR)的研究进展,介绍了其分类及特点、处理机理与MBR运行的影响因素以及膜污染的控制等,并概括了MBR的发展及展望。MBR是近来发展较迅速的一种污水治理设备,具有占地少、能耗低等优点,但也存在一定的缺点,其中膜污染是影响其推广应用的主要因素,目前国内外学者一般都以膜污染作为切入点进行研究,通过改变料液性质、优化操作参数、提高膜清洗效率等方法得以防治膜污染。 相似文献
288.
289.
The effect of methanol of low concentration on adsorption and leaching of atrazine and tebuconazole was studied in this paper. The adsorption coefficients and the retardation factors (Rm) of pesticides on EUROSOIL 3# log-linearly decreased as volumetric fraction of methanol (fc) was increased in the binary solvent mixtures of methanol and water. These data are consistent with solvophobic theory formerly outlined for describing the adsorption and transport of hydrophobic organic chemicals from mixed solvents. Nevertheless, the adsorption of these pesticides in soil–water system slightly increased when the soil was pre-washed with methanol in comparison with that pre-washed with water (pure water system). Furthermore, their adsorption coefficients were still higher in binary solvent systems with methanol of very low concentrations, i.e. fc<0.03 for atrazine and fc<0.01 for tebuconazole, than those in pure water system. The adsorption coefficients (logKw) of atrazine and tebuconazole predicted by solvophobic theory were 0.5792 and 1.6525, respectively, and their experimental logKw were 0.3701 and 1.6275 in pure water system. Obviously, the predicted logKw of the two pesticides was higher than the experimental log Kw in pure water system. The predicted Kw and the retardation factor (Rw) in pure water system by solvophobic theory are thus possibly inaccurate. 相似文献
290.
Fenton试剂在乳化液废水处理中的应用 总被引:1,自引:0,他引:1
用Fenton试剂处理乳化液废水,通过试剂在不同配比条件下对废水处理效果的实验比较,选择了最佳反应条件,废水处理后的COD测量结果表明,反应处理在实验室可行。 相似文献