污染土壤电动修复增强方法研究进展

污染土壤电动修复是一项新兴绿色原位修复技术。其原理是在土壤上施加直流电场 ,利用电迁移和电渗去除污染物 ,土壤pH、Zeta电位以及土壤化学性质等因素影响电动修复效果。为了提高修复效率和扩大电动修复应用范围 ,现在已经发展了针对不同类型土壤和污染物的增强修复技术。本文归纳总结了 1995年以来土壤电动修复中常用增强处理效果的 8种方法 ,即酸碱中和法、阳离子选择膜法、电渗析法、络合剂法、表面活性剂法、氧化 还原法、EK 生物联用和LasagnaTM法 ,且对每种方法的典型实验装置、增强原理、方法特点和适用范围等进行了分析和讨论 ,为以后的实验设计提供了有益的参考     

厌氧发酵方式对乳渣废水产酸性能的影响

为了研究厌氧发酵方式对乳渣废水发酵产酸效果的影响,分别对乳渣废水采用自然型发酵、填料型发酵及中性型发酵（pH=7.0±0.2）,并进行连续2个周期的厌氧反应。分析乳渣废水中可溶性化学需氧量（SCOD）、蛋白质、多糖、挥发性短链脂肪酸（SCFAs）、水解酶（蛋白酶、α-葡萄苷酶）和辅酶420、NH4+-N及PO43--P指标的变化。研究发现,中性产酸系统中水解酶活性较高,蛋白质和多糖等物质水解性能较好,使乳渣废水产酸性能最佳,最大SCFAs积累量为12 328.37 mg-COD·L-1。自然发酵产酸系统中水解酶活性最低,系统中残留大量的蛋白质和多糖等物质,最低SCFAs积累量为4 322.61 mg COD·L-1。同时发现,3个发酵系统中挥发性短链脂肪酸酸成分具有显著差别,其中自然型发酵系统乙酸积累率最大,可达69.70%,中性发酵系统丙酸积累率最大可达49.27%,填料型发酵系统正丁酸积累率最大可达38.85%。     

3种制备方法对Mn-Ce/TiO2催化剂的性能影响及成本分析

制备方法对催化剂的性能和成本有重要影响。选择共沉淀法、浸渍法和溶胶凝胶法制备Mn-Ce/TiO₂催化剂,在90~220 ℃对比测试不同方法制得催化剂样品的低温SCR性能,利用BET、SEM、XRD、FT-IR、H₂-TPR和NH₃-TPD分析样品的物理化学性质,并对3种方法的实验室制备过程进行成本分析。结果表明：共沉淀法和浸渍法制备的催化剂低温SCR性能均较好,在反应温度为150 ℃的条件下,催化剂的脱硝效率达到100%;制备方法不仅会影响催化剂的比表面积、表面形貌,还会对催化剂的氧化还原能力和表面酸性位产生影响;成本由低到高依次为浸渍法、溶胶凝胶法、共沉淀法。3种方法制得同样质量的催化剂时,采用浸渍法所消耗的药剂最少,而且浸渍法制备过程最短,操作最简单。本研究可为锰基低温脱硝催化剂的制备提供参考。     

高台位旱地石灰性紫色土培肥研究

本文研究了高台位旱地石灰性紫色土的肥力退化因子,并针对紫色母岩矿质养分丰富、易风化成土的特点,以一种培肥耕作法-聚土免耕耕作法培肥土壤。结果表明,采用此耕作法的土壤具有防蚀、抗旱、培肥和自调能力,能提高系统生产力。     

FRACTIONAL DIFFERENCING MODELING IN HYDROLOGY1

ABSTRACT: Fractional differencing is a tool for modeling time series which have long-term dependence; i.e., series in which the correlation between distant observations, though small, is not negligible. Fractionally differenced ARIMA models are formed by permitting the differencing parameter d in the familiar Box-Jenkins ARIMA(p, d, q) models to take nonintegral values; they permit the simultaneous modeling of the long-term and short-term behavior of an observed time series. This paper discusses the usefulness of fractional differencing to time-series modeling, with emphasis on hydrologic applications. A methodology for fitting fractionally differenced ARIMA models is described, and examples are presented.     

SOIL EROSION AWARENESS AND USE OF CONSERVATION TILLAGE FOR WATER QUALITY CONTROL1

Water pollution through loss of topsoil from farmland continues to be a major problem, despite nearly 50 years of providing farmers technical and financial assistance for soil and water conservation. The technology for controlling erosion and water pollution is available, but farmers have been slow in implementing control practices. Past research has shown that farmers tend to be unaware of the seriousness of the erosion problem on their own operations. Using a random sample of farmers from central Iowa, the relationship is examined between awareness of a soil erosion problem and the use of conservation tillage. Results indicate that awareness of a soil erosion problem effects the use of conservation tillage, and that awareness can be enhanced by experiential educational strategies such as the development and implementation of a soil and water conservation plan.     

EFFECTS OF TIME STEP SIZE IN IMPLICIT DYNAMIC ROUTING1

ABSTRACT The effects of the size of the Δt time step used in the integration of the implicit difference equations of unsteady open-channel flow are determined for numerous typical hydrographs with durations in the order of days or even weeks. Truncation errors related to the size of the Δt time step cause a numerical distortion (dispersion and attenuation) of the computed transient. The magnitude of the distortion is related directly to the size of the time step, the length of channel reach, and the channel resistance and inversely to the time of rise of the hydrograph. The type of finite difference expression which replaces spatial derivatives and non-derivative terms in the partial differential equations of unsteady flow has an important influence on the magnitude of the numerical distortion, as well as the numerical stability of the implicit difference equations. Time step sizes in the range of 3 to 6 hrs generally tend to minimize the combination of required computation time and numerical distortion of transients having a time of rise of the order of several days.     

DETECTION OF FRESH WATER AQUIFERS IN THE GLACIAL DEPOSITS OF NORTHWESTERN MISSOURI BY GEOELECTRICAL METHODS1

Geoelectrical investigations in Grundy County of northwestern Missouri, where the groundwater resources of the glacial deposits have already been examined through an extensive drilling program by the Missouri Geological Survey and Water Resources, indicate that water-bearing gravel deposits can be distinguished from glacial deposits containing appreciable amounts of clay and limited amounts of water. The Schlumberger method used for the geoelectric depth soundings in the vicinity of the Survey's drillholes demonstrates the exploratory usefulness of the method in that it can partly replace the more expensive procedure of drilling. The method also provides improved interpretation between drillholes. Results of the investigation show that, in the area, clay has a resistivity below 20in, that the fresh water-bearing gravel at the bottom of the buried glacial stream channels has a resisitivity of 40 to 50fim, and that the near surface glacial gravel deposits have a resistivity above lOOfim. Interpretation of the depth soundings and the conductivity of water obtained from a local well implies that its water is drawn from the saline water of the bedrock. A recommendation is made for the quality improvement of this particular well.     

测定单个粒子的薄膜法及其应用

本文介绍改进后的薄膜法,主要是形态分析法和复合薄膜法。它们都是基于粒子和薄膜反应生成物的形态特征通过电镜来确定粒子成分的。前者可以检测单个酸性粒子,检出下限为７ ×１０－ １９ｇ;后者能同时检出一个粒子中所含的ＮＯ－３ 和ＳＯ２ －４ ,检出下限分别为３ ×１０－ １５ｇ 和７ ×１０－ １８ｇ。利用该方法对广州大气粒子进行了观察,结果表明改进后的薄膜法完全适用于对单个粒子的观察和测定。     

Contour Farming Based on Natural Vegetative Strips: Expanding the Scope for Increased Food Crop Production on Sloping Lands in Asia

In the agriculture of the future, there is a compelling place for agroecologically-based practices alongside practices based on the best available chemical, genetic, and engineering components. This paper explores this issue in the context of the development and spread of a conservation farming system based on natural vegetative contour buffer strips in smallholder production systems in southeast Asia. Farmers adapted contour hedgerow farming practices into a simpler, buffer-strip system as a labor-saving measure to conserve soil and sustain yields on steeply sloping cropland in Claveria, Mindanao, Philippines. Permanent-ridge tillage systems were also adapted to smallholder farming systems by researchers. Natural vegetative buffer strips resulted in gradually increasing yields, with an estimated benefit of 0.5t/ha/crop. They were seen to increase land values, facilitate investment in more intensive and profitable cropping systems, and expand the land base for food crop agriculture. They induced an institutional innovation of farmer-led Landcare organizations, which have spread this and other agroforestry practices to thousands of households in the southern Philippines.