Preparation of rare-earth metal complex oxide catalysts for catalytic wet air oxidation

Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, COD_Cr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would have a promising application in CWAO treatment of high concentration organic wastewater. Translated from Techniques and Equipment for Environmental Pollution Control, 2005, 6(2): 40–44 [译自: 环境污染治理技术与设备]     

多环芳烃的几种理化参数与LC_(50)的相关性研究

对多环芳烃(PAHS)4种理化参数(K;W、Sw。X Vv。)与 LCO的相关关系进行了研究,建立了 4种一元线性回归方程。结果表明,4种参数的相关系数分别为:0.刀66、08083、09488、0.9570,经r检验,后两种属高度显著相关.用所建立的一元线性回归方程对7种PAHS的LC。进行估算,估算值与实测值相比,平均相对误差分别为58.84％、32.23％、1761％、198％,用l和V＊.H对LClj进行估算的估算精度也较高。经比较,提出用(。估算P＊比对麦穗鱼＊CO的新方法。     

GHG emission reductions and costs to achieve Kyoto target

Emission projection and marginal abatement cost curves (MACs) are the central components of any assessment of future carbonmarket, such as CDM (clean development mechanism) potentials, carbon quota price etc. However, they are products of very complex,dynamic systems driven by forces like population growth, economic development, resource endowments, technology progress and so on. The modeling approaches for emission projection and MACs evaluation were summarized, and some major models and their results were compared.Accordingly, reduction and cost requirements to achieve the Kyoto target were estimated. It is concluded that Annex I Parties‘ total reduction requirements range from 503--1304 MtC with USA participation and decrease significantly to 140--612 MtC after USA‘ s withdrawal. Total costs vary from 21--77 BUSD with USA and from 5--36 BUSD without USA if only domestic reduction actions are taken. The costs would sharply reduce while considering the three flexible mechanisms defined in the Kyoto Protocol with domestic actions‘ share in the all mitigation strategies drons to only 0--16%.     

LPWCO method for the treatment of high concentrated organic wastewater

Based on wet air oxidation (WAO) and Fenton reagent, thispaper raises a new low pressure wet catalytic oxidation(LPWCO)which requires low pressure for the treatment of highlyconcentrated and refractory organic wastewater. Compared withgeneral wet air oxidation, the pressure of the treatment(0.1-0.6MPa) is only one of tens to percentage of latter(3.5-10MPa). Inaddition, its temperature is no more than 180℃.Compared withFenton reagent, while H2O2/COD(weight ratio) less than 1.2, theremoval of COD in the treatment is over twenty percents more thanFenton's even the value of COD is more than 14000mg/L. In thispaper, we study the effect factor of COD removal and the mechanismof this treatment. The existence of synergistic effect (catalytic oxidation and carbonization) for COD removal in H2SO4-Fenton reagent system under the condition of applied pressure and heating (0.1-0.6MPa, 104-165℃) was verified. The best condition of this disposal are as follows:H2O2/COD(weight ratio)=0.2-1.0, Fe2+ 0.6×10-3 mol, H2SO4 0.5mol, COD>1×104mg/L, the operating pressure is 0.1-0.6MPa and temperature is 104-165℃. This method suit to dispose the high-concentrated refractory wastewater, especially to the wastewater containing H2SO produced in the manufacture of pesticide, dyestuff and petrochemical works.     

湖泊水体中硫酸盐增高的环境效应研究

通过对高原３个硫酸盐浓度差异的湖泊沉积物水界面硫的形态分布、扩散通量和碎屑有机硫通量等估算，揭示了湖泊水体硫酸盐增加以后的环境效应和自然反馈机制．研究认为：水体向沉积物内部扩散和界面硫酸盐还原作用是高硫酸盐浓度水体硫酸盐的主要清除作用，随硫酸盐浓度的增加，它在水体清除硫酸盐作用的贡献逐渐增大，而低硫酸盐含量湖泊水体生物同化吸收作用是水体硫酸盐的主要清除机制，它在硫酸盐浓度不同的水体没有差异．     

Occurrence and congeners specific of poiychlorinated biphenyls in agricultural soils from Southern Jiangsu, China

A total of 198 agricultural soil samples were collected from Zhangjiagang and Changshu in Southern Jiangsu for analysis of 13 polychlorinated biphenyls (PCBs) in order to assess the levels of pollution, sources, area distribution, and potential risk for the environment. All methods were rigorously tested and an adequate quality control was ensured. Only one site had no PCBs residues, and the highest total PCBs concentration in the surface soils was 32.83 ng/g. The average concentration in all the soil samples was 4.13 ng/g, signaling low-level pollution. Tetra-, penta-, and hexa-chlorinated biphenyls were dominant species in soil samples, accounting for more than 75% ofΣPCBs in the soil samples. PCB118 was the most abundant congener in all the samples. The PCB118 was about 20% ofΣPCBs. The soil organic matter content showed only a weak correlation with the levels of all PCB congeners, in which a better correlation was noted for the more volatile lighter PCB congeners than for the heavier homologues. To a certain extent, the sources and land use seemed to influence the levels of PCBs.     

Quantitative structure - activity study on the reductivedehalogenation potency of the halogenated aromatics

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金属铁还原降解2,4-二硝基甲苯的实验研究

研究了金属铁对2,4-二硝基甲苯(2,4-DNT)的还原降解情况.实验结果表明,2,4-DNT的还原降解与溶液初始pH值、初始浓度和溶解氧等因素有关.氯离子能消除金属铁的钝化现象.金属铁表面附载的铜对2,4-DNT的还原降解具有催化作用.     

MBBR处理低浓度污水的工程应用

用 2座体积 12 0m3的移动床生物膜反应器处理抚顺乙烯有限公司厂区的低浓度 (CODCr6 0～ 80mg L)生活污水 ,停留时间 2 4h ,出水通过高效纤维球过滤罐 ,CODCr降至 2 0mg L ,BOD5降至 5mg L ,SS降至 5mg L ,氨氮降至 1mg L ,达到了循环冷却水的回用标准。进水浓度过低 ,对MBBR挂膜不利 ,工程中采用外加营养物质的措施后 ,3d内反应器成功挂膜启动。     

ASM1中废水和污泥组分浓度的测定方法研究

对呼吸计量法应用于校准ASM1作了简明的阐述。在呼吸速率与模型组分关系的基础上,介绍了ASM1中废水与污泥各组分浓度的测定方法,并指出模型组分细化的意义。