全文获取类型
收费全文 | 300篇 |
免费 | 27篇 |
国内免费 | 56篇 |
专业分类
安全科学 | 15篇 |
废物处理 | 13篇 |
环保管理 | 33篇 |
综合类 | 247篇 |
基础理论 | 42篇 |
污染及防治 | 16篇 |
评价与监测 | 5篇 |
社会与环境 | 6篇 |
灾害及防治 | 6篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 13篇 |
2020年 | 6篇 |
2019年 | 7篇 |
2018年 | 3篇 |
2017年 | 8篇 |
2016年 | 12篇 |
2015年 | 17篇 |
2014年 | 16篇 |
2013年 | 13篇 |
2012年 | 18篇 |
2011年 | 20篇 |
2010年 | 10篇 |
2009年 | 15篇 |
2008年 | 15篇 |
2007年 | 18篇 |
2006年 | 19篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 24篇 |
2002年 | 15篇 |
2001年 | 21篇 |
2000年 | 13篇 |
1999年 | 20篇 |
1998年 | 13篇 |
1997年 | 8篇 |
1996年 | 4篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有383条查询结果,搜索用时 187 毫秒
51.
52.
以低温域(0~15 ℃)下黄菖蒲(Iris pseudacorus)、菖蒲(Acorus calamus)和香蒲(Typha orientalis)3种湿地植物为研究对象,分别取其根际土壤测定硝化强度,并采用FISH(荧光原位杂交)技术,考察植物根际AOB(氨氧化细菌)、AOA(氨氧化古菌)的数量变化规律. 结果表明:低温条件下,香蒲根际土壤的硝化强度最高,平均值为1.40 mg/(kg·h),黄菖蒲和菖蒲的平均值均为0.96 mg/(kg·h). 湿地植物根际土壤中的细菌数量(数量级为1010)远高于古菌(数量级为108),其中AOB为优势菌种,3种湿地植物的AOA数量分别约占总古菌数量的46.0%、47.9%和49.7%. 3种湿地植物根际AOB的数量(以湿土计,下同)排序为香蒲(2.57×109 g-1)>黄菖蒲(1.23×109 g-1)≈菖蒲(1.14×109 g-1),AOA的数量(以湿土计)排序为黄菖蒲(2.78×108 g-1)>香蒲(2.57×108 g-1)>菖蒲(1.15×108 g-1). 微生物分布特性和硝化作用效果均表明,不同植物根际氨氧化过程的主要作用微生物具有一定差异,AOA和AOB对于湿地土壤氮转化均具有不可忽视的作用,并与植物本体、土壤硝化过程微环境之间有一定的耦合关系. 相似文献
53.
CS2 removal was Obtained by coupling catalytic hyidation on bi-functional catalyst.On the hydrolysis active sites,CS2 is hydrolyzed to H2S,while on the oxidation active sites,H2S is oxidized to elemental S or sulfuric acid deposited on the porous support.The above process can be expressed as followsCS2→H2O COS →H2O H2S→O2 S/SO2- 4.H2S oxidation eliminates its prohibition on CS2 hydrolysis so that the rate of coupling removal CS2 is 5 times higher than that of CS2 hydrolysis.The same active energy of hydrolysis and coupling reaction also indicates that H2S oxidation does not change the reaction mechanism of CS2 hydrolysis.Temperature has obvious effect on the process while the mole ratio of O2 concentration to CS2 concentration (O/S) does not,especially in excess of 2.5.The formation of sulfuric acid on the catalyst surface poisons hydrolysis active sites and causes the decrease of left OH-1 concentration on the catalysts surface.Lower temperature is suggested for this bi-functional catalyst owing to the low yield ratio of S/SO4 2-. 相似文献
54.
应用南京逐日观测资料分析了南京低温、冰冻和积雪灾害的变化特征及其与区域气候变暖的联系,得到如下结论:①低温、冰冻、积雪事件都存在一定的年代际和年际的周期变化;冬季平均最低气温和极端最低气温具有相似的周期性特征;积雪深度的年代际尺度的周期特征明显,但是较小尺度的年际周期不明显;②近50年来南京的低温、冰冻、积雪事件呈现波动下降的趋势;③南京年均气温和低温、冰冻、积雪事件之间存在较强的相关性与区域气候变暖关系密切。 相似文献
55.
Transmissible spongiform encephalopathies (TSEs) are a group of fatal neurological conditions affecting a number of mammals,
including sheep and goats (scrapie), cows (BSE), and humans (Creutzfeldt-Jakob disease). The diseases are widely believed
to be caused by the misfolding of the normal prion protein to a pathological isoform, which is thought to act as an infectious
agent. Outbreaks of the disease are commonly attributed to contaminated feed and genetic susceptibility. However, the implication
of copper and manganese in the pathology of the disease, and its apparent geographical clustering, have prompted suggestions
of a link with trace elements in the environment. Nevertheless, studies of soils at regional scales have failed to provide
evidence of an environmental risk factor. This study uses geostatistical techniques to investigate the correlations between
the distribution of TSE prevalence and soil geochemical variables across the UK according to different spatial scales. A similar
spatial pattern in scrapie and BSE occurrence is identified, which may be linked with increasing pH and total organic carbon,
and decreasing iodine concentration. However, the pattern also resembles that of the density of dairy farming. Nevertheless,
despite the low spatial resolution of the TSE data available for this study, the fact that significant correlations are detected
indicates there is a possibility of a link between soil geochemistry, scrapie, and BSE. It is suggested that further investigations
of the prevalence of TSE and environmental exposure to trace metals should take into account the factors affecting their bioavailability. 相似文献
56.
W. C. Sidle D. L. Roose Paul Barndt 《Journal of the American Water Resources Association》2001,37(2):379-393
ABSTRACT: Environmental background levels of Pb were measured in ponds, river waters, sediments, suspended sediments, rocks, and air particulates within the Kankakee watershed during the period of 1995 to 1999. Stable isotopic Pb distinguished airborne Pb and its incorporation into riverine wetland sediments from geogenic Pb measured in river sediments. The provenance of the naturally‐occurring Pb is from carbonate bedrock and contributes comparable concentrations in riverbank sediments (25.9–30.4 mg kg?1) as Pb found in wetland sediments (18.6–24.8 mg kg?1). Estimates of anthropogenic Pb contributions from airfall into the Kankakee wetlands were found to be near 0.43–0.71 Bq cm?2 yr?1 during 1995 to 1999. While leachable Pb data suggests the uppermost layers of pond sediments were disturbed, 210Pb analyses from undisturbed sedimentation suggests Pb‐bearing sediments accumulate approximately 0.46–0.51 cm yr?1 in the ponds within the riparian zones. Transboundary Pb pollution from aerosols of industrial Pb across the Great Lakes occurs, but Pb isotopy indicates that the Pb concentrations are comparable to natural concentrations of Pb in both waters and sediments within the Kankakee watershed. 相似文献
57.
研究了4种成片分布的典型岩性(页岩、石灰岩、花岗岩、黄土)区域沉积物金属元素(Li、Na、K、Ca、Sr、Ba、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Al等共16种)总量与形态特征.结果表明:这4种岩性区域沉积物金属元素含量与形态均有显著的差别.与其它岩性相比,黄土地区易迁移元素含量高,而重金属含量显著较低;其金属元素残渣态含量高,而有机态、铁锰氧化物态和可交换态含量低.石灰岩地区重金属含量较高,而易迁移元素如Na,Sr等含量则较低;其重金属元素残渣态含量不偏低,表明经风化作用释放出来的重金属参与了次生矿物的形成过程而得以富集.花岗岩地区重金属含量居中,而Fe和Al含量较高;其金属元素残渣态含量不偏高则与风化作用较强有关.页岩地区元素含量与形态均居中,代表了各种岩性的平均水平. 相似文献
58.
江西华齐铜多金属矿区含矿硅质岩的地球化学特征及成因探讨 总被引:1,自引:0,他引:1
矿产远景地质调查过程中,在江西华齐铜多金属矿区发现含矿硅质岩.测试分析显示,区内硅质岩贫Al2O3、TiO2,Co、Cr等元素含量低,贫∑REE,δ(Eu)为负异常,δ(Ce)为弱正异常,HREE相对富集等热水沉积物的特征.在判别硅质岩形成的系列图解上,样品均指示热水沉积作用和大陆边缘环境,这与SiO2/Al2O3、SiO2/(K2O+Na2O)、SiO2/MgO、MnO/TiO2、K/Rb等特征值所指示的结果相一致.本区硅质岩地球化学特征及其对比结果说明该区域构造演化的复杂性.在元古代华南海槽构造演化中在华夏地块边缘发生断裂拉张,形成断陷盆地,并发生了热水喷流沉积成岩成矿作用.本区硅质岩与成矿关系密切,研究硅质岩对于认识区域构造演化及寻找矿化体具有重要意义. 相似文献
59.
60.
Fe203 particle catalysts were experimentally studied in the low temperature selective catalytic reduction (SCR) of NO with NH3. The effects of reaction temperature, oxygen concentration, [NH3]/[NO] molar ratio and residence time on SCR activity were studied. It was found that Fe203 catalysts had high activity for the SCR of NO with NH3 in a broad temperature range of 150-270℃, and more than 95% NO conversion was obtained at 180℃ when the molar ratio [NH3]/[NO] = 1, the residence time was 0.48 seconds and 02 volume fraction was 3%. In addition, the effect of SO2 on SCR catalytic activity was also investigated at the temperature of 180℃. The results showed that deactivation of the Fe2O3 particles occurred due to the presence of SO2 and the NO conversion decreased from 99.2% to 58% in 240 min, since SO2 gradually decreased the catalytic activity of the catalysts. In addition, X-ray diffraction, Thermogravimetric analysis and Fourier transform infrared spectroscopy were used to characterize the fresh and deactivated Fe2O3 catalysts. The results showed that the deactivation caused by SO2 was due to the formation of metal sulfates and ammonium sulfates on the catalyst surface during the de-NO reaction, which could cause pore plugging and result in suppression of the catalytic activity. 相似文献