贵阳市区大气降水中有机酸的研究

利用ICS-90常规离子色谱结合RFC-30型淋洗液在线发生器,对贵阳市区大气降水中的小分子有机酸进行了系统研究。测得贵阳市降水中的有机酸主要以甲酸[质量分数为(0.2-4.5)×10-6]、乙酸[质量分数为(0.6-5.3)×10-6]、草酸[质量分数为(0.1-4.9)×10-6]为主,其次是乳酸和丙酮酸,及少量丙酸和甲烷磺酸;有机酸对降水自由酸平均贡献为23.2%,占总阴离子的1.4%;通过比较贵阳市区有机酸前后二十年的变化,得出现阶段可能至少有近1/2乙酸和3/4甲酸来源于人类的活动,这说明有机酸人为源是其来源的重要组成部分。     

Synthesis of hydrogarnet from molten slag and its hydrogen chloride fixation performance at high temperature

Hydrogarnet was synthesized hydrothermally below 200°C using molten slag obtained from municipal solid waste. For comparison, it was also synthesized using pure-phase CaO–Al₂O₃–SiO₂–H₂O, as reported previously. The structural and textural properties of this material were investigated using various analytical and spectroscopic techniques such as X-ray diffraction, X-ray fluorescence spectrometry, atomic absorption spectrometry (AAS), thermogravimetry/differential thermal analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy. The Cl⁻ fixation ability of hydrogarnet was investigated in the temperature range 500–800°C in a fixed-bed flow reactor using a HCl concentration (1000 p.p.m.v.) similar to that of incinerator exhaust gas. Under these experimental conditions, the hydrogarnet was capable of reducing the HCl gas level to less than 1 p.p.m.v. Analysis of the spent catalyst revealed that the hydrogarnet was being transformed into wadalite and CaCl₂ at high temperatures. The elution test for chromium ions in hydrogarnet obtained from slag was also used, and it was found that chromium ions were not eluted from hydrogarnet. Received: January 27, 2001 / Accepted: October 11, 2001     

ACID PRECIPITATION AND WEATHERING BY ORGANIC ACIDS IN LABRAI)OR LAKE BASINS1

ABSTRACT: Thirty-five lakes in southern Labrador sampled in 1981 were resampled in 1989 and water chemistry values were compared between visits. Results showed higher pH, specific conductance, acid neutralization capacity, color, and base cations values in 1989, though sulfate, the ion most likely to reflect acid precipitation impacts, did not vary. The major ion changes measured were probably due to natural hydrological variations and not to changes in acid inputs. Results from the 1989 data showed a slight, but significant, decrease in water sulfate concentration trend from western to eastern Labrador, though most values, even in the western portion of the study area, fell close to the values considered “background” by Brakke et at. (1989). Base cation concentrations exceeded those which could be predicted from weathering by carbonic and bicarbonic acid. Assuming that little weathering is generated by acid precipitation in this region, the excess cations measured are probably a result of bedrock dissolution from organic acids generated by plant decomposition. Calculations showed that organic acid effect could be responsible for 9 to 52 percent of total weathering in the study basins.     

城市土地资产经营新思路探讨

自1996年上海市成立第一家土地收购储备机构——土地发展中心后，全国各大城市已纷纷效仿它的成功经验。截止2001年8月不完全统计，全国已有大小不同的土地收购储备机构669家。实践证明，土地收购储备机制在盘活城市存量土地，促进土地集约利用，保障城市土地资产的保值增值等方面成绩卓著。然而，实践过程中，土地收购储备机制的运作也暴露出不少问题。本文通过对这些问题的分析，提出了引进公司制度完善土地收购储备机制，合理运营城市土地资产的新思路。     

氯离子选择性电极法测定钻井废水氯离子含量

利用氯离子选择性电极测定钻井废水中的氯离子含量，分别用两种方法对钻井废水进行了预处理，氯离子在0-250mg/L的范围内线形关系良好，相关系数为0.9968,并且重现性和选择性良好、精密度与准确度较理想。     

重大事故应急处置基本原则与程序

提高重大事故的风险意识和应急处置能力,对坚持以人为本,建设和谐社会和保护人民群众生命财产安全有重要意义。本文论述了重大事故应急管理基本认识,应急处置过程应遵循的主要原则,论述了适用于各类突发公共事件的应急响应通用程序,并提出其应成为应急管理标准化的一个主要内容。     

浅析国内外重大危险源辨识中危险物质临界量的差异

通过分析国内外重大危险源辨识标准中危险物质临界量的差异,以汽油和液化石油气为例,分别选择池火灾和沸腾液体扩展蒸气云爆炸模型计算事故后果,并结合我国企业的安全管理状况,说明了修改我国《重大危险源辨识》中危险物质临界量的必要性。     

重大危险源动态监管与应急救援平台建设研究

由于缺乏相关的国家及行业标准规范,各地重大危险源监管与应急救援平台建设中主要存在如下问题:其一,只重视硬件建设,而忽视软件和信息建设;其二,重大危险源安全监管数据采集标准不统一,采用的相关软件和硬件技术不规范,难以在各级平台间实现数据共享。笔者参照重大危险源4级监管与应急救援体系,将国家科技攻关课题的相关研究成果同安全生产工作的实际需要有机地结合,提出重大危险源动态监管和事故应急救援平台建设方案。分析我国重大危险源监管及应急救援系统的建设现状及存在的主要问题;提出平台的设计原则、实现数据共享的主要思路;设计软件系统总体规划及各部分的功能。     

Biodegradability of Quaternized, Crosslinked Sugarcane Bagasse

Quaternized, crosslinked sugarcane bagasse can adsorb anionic dyes from textile wastewater. Disposal of dye-saturated adsorbent by composting or land application would require that modifications made to the bagasse do not interfere with its decomposition. The impact of quaternization and crosslinking on bagasse biodegradability was examined. Bagasse in varying states of modification was mixed with soil and monitored for carbon dioxide evolution for four weeks at 27°C. After subtracting the amount of carbon evolved from control soil samples, the net carbon evolved from the bagasse samples was determined and used as a measure of their extent of biodegradation. Biodegradability decreased in the order: bagasse (approx. 60% degraded after four weeks) > quaternized bagasse > quaternized, epichlorohydrin-crosslinked bagasse > quaternized, methylene-bis-acrylamide-crosslinked bagasse > epichlorohydrin-crosslinked bagasse (less than 5% degraded). Crosslinking severely impacted biodegration, probably by preventing the penetration of (hemi)cellulytic and lignolytic enzymes into the interior of the modified bagasse particles. It is concluded that the biodegradability of quaternized, crosslinked bagasse is too low for composting or land application.     

Adsorption behavior of ammonium by a bioadsorbent - Boston ivy leaf powder

The adsorption behaviors of ammonium ions from aqueous solution by a novel bioadsorbent,the Boston ivy (Parthenocissus tricuspidata) leaf powder (BPTL) were investigated.The SEM images and FT-IR spectra were used to characterize BPTL.The mathematical models were used to analyze the adsorption kinetics and isotherms.The optimum pH range for ammonium adsorption by BPTL was found to be 5-10.The adsorption reached equilibrium at 14 hr,and the kinetic data were well fitted by the Logistic model.The intraparticle diffusion was the main rate-controlling step of the adsorption process.The high temperature was favorableto the ammonium adsorption by BPTL,indicating that the adsorption was endothermic.The adsorption equilibrium fitted well to both the Langrnuir model and Freundlich model,and the maximum monolayer adsorption capacities calculated from Langmuir model were 3.37,5.28 and 6.59 mg N/g at 15,25 and 35℃,respectively,which were comparable to those by reported minerals.Both the separation factor (RL) from the Langmuir model and Freundlich exponent (n) suggested that the ammonium adsorption by BPTL was favorable.Therefore,the Boston ivy leaf powder could be considered a novel bioadsorbent for ammonium removal from aqueous solution.