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941.
于都银坑贵多金属矿田有破碎岩蚀变型、层问破碎带型、岩体接触带型。硫锰矿型、铁锰帽型、黑土角砾型等六种矿化类型。主要控矿因素为地层、岩性、岩浆岩、构造和次火山岩体接触带构造四种。矿化带严格受破碎带控制,也受不同地层时代和岩浆热场的影响。矿带往往在主干断裂旁侧、多组裂隙交汇处及褶皱轴部横张裂隙发育部位定位;不同的地层时代有不同的有益元素组合,不同的岩性又对元素的富集成矿有特定的作用;岩浆岩的多期活动为矿床的形成提供了有利条件。本矿田成因类型属岩浆期后中低温热液充填交代矿床。通过矿床模式的建立,本区找矿方向的主要标志是:多组构造结点、特定的赋矿层位以及次火山构造周围。 相似文献
942.
燃煤电厂排放细微灰粒中痕量元素的分布与富集规律 总被引:19,自引:2,他引:19
本文测定了武汉市青山热电厂5^#锅炉在两种不同燃烧工况条件下,除尘器入口烟道灰的四种不同粒径灰粒中的Cu,Co,Ni,Pb,Cd,Cr和Be等七种痕量元素的含量。发现大部分元素有在细微粒子中富集的倾向,富集程度与颗粒物粒径大小、元素性质、元素存在形态及燃烧工况条件有密切关系。这种富集倾向可用痕量元素在燃烧过程中的蒸发-凝集作用来解释。 相似文献
943.
944.
采用天然锰矿和次氯酸钠在紫外光的照射下处理分散蓝2BLN废水,探讨了影响水溶液中分散蓝2BLN染料的光催化降解的各种影响因素。当通入氧气时,天然锰矿用量为20g/L、次氯酸钠的用量为20mL/L、光强2000W、光距10cm、反应时间为60min、pH值在7.5-9.5,废水的COD去除率达52%,脱色率达93%。 相似文献
945.
Burger J Campbell KR Campbell TS Shukla T Dixon C Gochfeld M 《Environmental monitoring and assessment》2005,110(1-3):171-184
We compared the levels of arsenic, cadmium, chromium, lead, manganese, mercury and selenium in a small species of fish (Central
stonerollers, Campostoma anomalum) collected from East Fork Poplar Creek (EFPC) and a reference site in eastern Tennessee. Stonerollers are minnows in the
Cyprinidae family that serve as prey for many carnivores in aquatic systems. Fish were collected from East Fork Poplar Creek
within the U.S. Department of Energy's Y-12 National Security Complex, part of the Oak Ridge Reservation, and from a reference
stretch of the Little River in East Tennessee. Whole fish were homogenized for analysis. Concentrations of all metals (except
arsenic) were significantly higher in stonerollers from EFPC compared to the reference site. Mercury levels in minnows from
EFPC averaged 0.4 ppm (μg/g), four times higher than the average for fish in the U.S. in general. This was higher than levels
in fish from the nearby Clinch River and higher than fillets of white bass (Morone chrysops) from the same creek. Most metal levels were inversely related to size and weight of the stonerollers, perhaps due to growth
dilution. 相似文献
946.
有机改性蒙脱土对萘的吸附机制和影响因子 总被引:1,自引:0,他引:1
我国场地土壤中多环芳烃(PAHs)污染或PAHs-重金属复合污染是常见的污染类型,对公众健康与环境构成巨大威胁.本研究利用耗散型石英晶体微天平(QCM-D)技术和批量吸附实验,探究实验室制备的2种有机改性黏土对萘的吸附机制,以及萘与Cu2+共存时黏土颗粒吸附情况.结果表明,25℃时,十六烷基三甲基溴化铵改性蒙脱土(CTAB-SMF)的吸附等温线符合Freundlich模型(R2>0.92,n>1),说明其对萘的吸附位点具有多样性,在较高萘平衡浓度(ce=1 mmol ·L-1)下吸附分配系数Kd为SMF的13.4倍;3-巯基丙基三甲氧基硅烷改性蒙脱土(TMSP-SMF)的吸附等温线符合Langmuir模型(R2>0.96),在较高萘平衡浓度(ce=1 mmol ·L-1)下吸附分配系数Kd为SMF的1.14倍.说明2种有机改性黏土对萘的吸附效果优于SMF颗粒.3种黏土颗粒对萘的吸附焓在-30~-10 kJ ·mol-1之间,均为自发物理吸附.溶液离子强度升高抑制了SMF吸附萘,但对改性黏土吸附萘无显著影响.萘平衡浓度较低(ce=0.1 mmol ·L-1)时,Cu2+的存在使TMSP-SMF对萘的吸附效果增加了3倍;同时萘能促进2种改性黏土对Cu2+的吸附.本研究通过原位在线QCM-D检测了黏土对萘的吸附机制,结果与批量吸附实验结果一致:CTAB-SMF对萘的吸附位点主要为黏土层间的改性剂基团,TMSP-SMF则位于黏土颗粒表面的改性剂基团.本项研究结果显示,QCM-D技术是一种有效的原位在线表征黏土膜吸附有机污染物的方法,2种有机改性的黏土颗粒可作为应用于PAHs或PAHs-重金属复合污染场地的修复材料. 相似文献
947.
ABSTRACT: Success in measuring turbulence in water has been achieved by replacing the hot-wire probe by the hot-film probe. Accordingly, these results have greatly increased knowledge and understanding of hydromechanics. However, there are few published measurements of turbulent properties of flow with suspended solid particles. With this in mind, the authors conducted measurements of turbulent properties of flow with suspended solid particles by using a quartz-coated, wedge-shaped hot-film probe. Turbulent intensities and macroscale of eddy change in the flow with suspended solid particles on a movable bed is discussed. 相似文献
948.
Variation of particle number and mass concentration in various size ranges of ambient aerosols in Eastern Germany 总被引:1,自引:0,他引:1
Th. Tuch P. Brand H.E. Wichmann J. Heyder 《Atmospheric environment (Oxford, England : 1994)》1997,31(24):4193-4197
There is an ongoing debate on the question which size fraction of particles in ambient air may be responsible for short-term responses of the respiratory system as observed in several epidemiological studies. However, the available data on ambient particle concentrations in various size ranges are not sufficient to answer this question.Therefore, on 180 days during the winter 1991/92 daily mean size distributions of ambient particles were determined in. Erfurt, a city in Eastern Germany. In the range 0.01–0.3 μm particles were classified by an electrical mobility analyzer and in the range 0.1–2.5 μm by an optical particle counter. From the derived size distributions, number and mass concentrations were calculated.The mean number concentration over this period of time was governed by particles smaller than 0.1 μm (72%), whereas the mean mass concentration was governed by particles in the size range 0.1–0.5 pm (83%). The contribution of particles larger than 0.5 μm to the overall number concentration was negligible and so was the contribution of particles smaller than 0.1 μm to the overall mass concentration. Furthermore, total number and mass concentrations in the range 0.01–2.5 μm were poorly correlated.The results suggest that particles larger than 2.5 μm (or even larger than 0.5 μm) are rare in the European urban environment so that the inhalation of these particles is probably not relevant for human health. Since particle number and mass concentrations can be considered poorly correlated variables, more insight into health-related aspects of particulate air pollution will be obtained by correlating respiratory responses with mass and number concentrations of ambient particles below 0.5 μm. 相似文献
949.
950.
本文研究了北京地区4种类型5个石灰性土壤样品对锰的吸附、及其与土壤各理化性质的关系。在每克土壤加入25ml10~200gMn/ml的剂量范围内,土壤对锰的吸附极好的遵从Freundrich等温方程,而是否符合Langmuir等温方程则与加入的锰溶液浓度有关,当其小于120 gMn/ml时,则能较好地符合Langmuir方程;这一现象说明,土壤具有两种或两种以上的吸附位。在土壤各理化性质中主要是粘粒含量和阳离于交换总量(CEC)影响到锰的吸附。但在锰溶液浓度较低时,各土壤理化性质均与土壤吸附锰量无显著相关。平衡溶液的pH强烈影响土壤吸附锰的能力,当pH由4上升至7左右时,土壤对锰的吸附急剧增加,pH值再上升,土壤吸附锰量的增加趋于平缓。 相似文献