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101.
研究了在二氧化锰催化引起的五氯酚的转化反应中,腐殖质前身化合物的加入对五氯酚去除率的影响,并以p-coumaricacid为代表研究了体系pH值、反应时间、二氧化锰的质量浓度以及腐殖质前生物的浓度和分子结构对去除率的影响。结果表明,反应的最佳pH值范围是4~4.70,去除率在80%左右。五氯酚在24h内去除速率较快,去除率达到75%左右;反应到168h,去除速率趋于0,去除率达到80%左右。相同条件下,无p-coumaricacid的对照体系中,对应的反应时间内去除率仅分别为20%和25%左右。五氯酚的去除率还随二氧化锰质量浓度和p-coumaricacid浓度的增加而增大。当二氧化锰的质量浓度由0增加到100g·L-1时,去除率由0增大为95%;而当p-coumaricacid的浓度由0增加到1mmol·L-1时,去除率由25%增大到100%左右。此外,不同腐殖质前身物的分子结构和浓度对去除率分别起到了提高、不明显改变和降低的作用。 相似文献
102.
通过在本课题组自行设计的中空水冷转式垃圾焚烧炉上的实验研究,论文从工艺流程和NOx生成特性方面探讨了该新型焚烧炉的稳定燃烧和低污染排放技术特点;并与固定床焚烧炉作了实验研究比较,可知中空水冷转式垃圾焚烧炉在降低NOx浓度与提高燃尽率方面具有良好的性能。 相似文献
103.
F.?L.?Toma G.?Bertrand D.?KleinEmail author C.?Coddet 《Environmental Chemistry Letters》2004,2(3):117-121
We studied the removal of nitrogen oxides pollutants via TiO2 Degussa P25 powder by photocatalysis. Parameters such as mass of catalyst, geometric irradiated surface, catalyst morphology, and thermal treatment were tested to explain the photocatalytic concentration decrease of nitrogen oxides. According to our working conditions, the conversion rates increased until an optimal value of the TiO2 weight, 35% of NO concentration and around 20% of NOx, was decomposed by the photocatalysis. The NOx removal increased proportionally with the irradiated geometric surface. The structural transformation of anatase to rutile performed by thermal treatment involved the decrease of the photocatalytic activity. 相似文献
104.
海底铁锰氧化还原过程的模拟研究 总被引:5,自引:0,他引:5
本文用室内海水-沉积物平衡箱研究了沉积物间隙水中铁、锰的垂直变化分布和随时间变化的分布,Fe~(2+)随深度、时间的变化幅度大,在六个月的实验期内均是如此,而Mn~(2+)在放置三个月后即趋于稳定;Fe~(2+),Mn~(2+)产生的宏观经验动力学表明:Fe~(2+)受pH影响远比Mn~(2+)大,且随着深度的增加更为明显,Fe~(2+)在较下层产生速率大,而Mn~(2+)反之;Fe~(2+)的扩散转移是上覆海水向沉积物中转移,扩散量为-60.7ug/m~2d,Nn~(2+)转移方向相反,扩散量为1746.2ug/m~2.d。 相似文献
105.
Ancillary benefits of reduced air pollution in the US from moderate greenhouse gas mitigation policies in the electricity sector 总被引:3,自引:0,他引:3
Dallas Burtraw Alan Krupnick Karen Palmer Anthony Paul Michael Toman Cary Bloyd 《Journal of Environmental Economics and Management》2003,45(3):650
Actions to slow atmospheric accumulation of greenhouse gases also would reduce conventional air pollutants yielding “ancillary” benefits that tend to accrue locally and in the near-term. Using a detailed electricity model linked to an integrated assessment framework to value changes in human health, we find a tax of $25 per metric ton of carbon emissions would yield NOx-related health benefits of about $8 per metric ton of carbon reduced in the year 2010 (1997 dollars). Additional savings of $4–$7 accrue from reduced investment in NOx and SO2 abatement in order to comply with emission caps. Total ancillary benefits of a $25 carbon tax are $12–$14, which appear to justify the costs of a $25 tax, although marginal benefits are less than marginal costs. At a tax of $75, greater total benefits are achieved but the value per ton of carbon reductions remains roughly constant at about $12. 相似文献
106.
The NO/H2/O2 reaction was studied under oxidizing conditions in the 100-400 °C range over 0.1 wt% Pt supported on various metal oxides such as MgO, CeO2, SiO2, La2O3, CaO, Y2O3 and TiO2. The Pt/MgO and Pt/CeO2 catalysts showed good catalytic behaviours. Here, we find that the Pt/Mg-Ce-O catalyst, prepared from MgO and CeO2 by the sol-gel method, is a very active and selective catalyst towards N2 formation in the whole 100–400 °C range. This catalyst appears to be the most active, selective and stable one ever reported in the literature for the NO/H2/O2 reaction, even in the presence of 5%v H2O or 20 ppmv of SO2 in the feed stream.Selected article from the Regional Symposium on Chemistry and Environment, Krusevac, Serbia, June 2003, organised by Dr. Branimir Jovancicevic. 相似文献
107.
108.
109.
介绍了络合吸收结合生物转化处理NOx 技术的基本原理和目前的研究进展情况 ,并分析了该技术处理氮氧化物存在的问题和未来发展方向 相似文献
110.
The current approach for modelling ion adsorption onto binary (hydr)oxides using homogeneous surface complexation models involves the assumption of either an ideal mixture of the two surfaces (i.e. two surface sites on one surface) or a patchwise surface (i.e. two surfaces with one surface site on each surface). As the physical truth should be between these two limiting cases, a model which assumes a patchwise surface constituted of three patches is proposed. Two patches represent the distinct (hydr)oxides, and the third one a mixture of these distinct (hydr)oxides. Using the diffuse layer model, the three approaches are applied to literature data for Cd adsorption onto binary mixtures of alumina-coated silica at total constant Cd concentration and varying amounts of alumina coatings. For Cd adsorption onto these binary (hydr)oxide systems, the new approach explains the observed potential effects. The proposed model, which contains two additional adjustable parameters in terms of site concentrations or one adjustable parameter in terms of specific surface area, is more successful than the two limiting cases. The new model is then validated by predicting Ca and Zn behaviour on the same binary (hydr)oxide system. 相似文献